HUA Ping, YU Hong-mei, LI Jian-hua, FANG Lue-tao, DAI Bao-jiang, ZHANG Hai-bin, ZHU Guo-hua. Catalytic activity of carbon-based solid acids in the esterification synthesis of 1,4-butanediol disuccinate diisooctyl. New Carbon Mater., 2016, 31(5): 539-544.
Citation: HUA Ping, YU Hong-mei, LI Jian-hua, FANG Lue-tao, DAI Bao-jiang, ZHANG Hai-bin, ZHU Guo-hua. Catalytic activity of carbon-based solid acids in the esterification synthesis of 1,4-butanediol disuccinate diisooctyl. New Carbon Mater., 2016, 31(5): 539-544.

Catalytic activity of carbon-based solid acids in the esterification synthesis of 1,4-butanediol disuccinate diisooctyl

Funds:  Major projects of "Twelve Five" National Science and Technology Support Program (2011BAE06A06); Natural Science Research Project of the Education Department of Jiangsu Province (13KJB150032).
  • Received Date: 2016-07-26
  • Accepted Date: 2016-10-28
  • Rev Recd Date: 2016-09-29
  • Publish Date: 2016-10-28
  • Carbon-based solid acids were prepared by coking mixtures of p-toluene sulfonic acid and soluble starch with different ratios at different temperatures. The effects of the p-toluene sulfonic acid/soluble starch mass ratio, coking temperature and time on their catalytic activities in the esterification reaction of maleic anhydride with ethylene glycol were investigated. Results indicated that the activity of the acid was the highest when amixture with the mass ratio of 0.5 was coked at 200℃ for 8 h. The activity remained high after the solid acid had been used 5 times.
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