RONG Ju, ZHU Yuan-yuan, FAN Zhen, FENG Zhi-hai, HE Lian-long. Investigation of defects in a mesophase pitch-based graphite at the atomic scale. New Carbon Mater., 2017, 32(2): 168-173.
Citation: RONG Ju, ZHU Yuan-yuan, FAN Zhen, FENG Zhi-hai, HE Lian-long. Investigation of defects in a mesophase pitch-based graphite at the atomic scale. New Carbon Mater., 2017, 32(2): 168-173.

Investigation of defects in a mesophase pitch-based graphite at the atomic scale

Funds:  National Program on Key Basic Research Project (973 Program) (2011CB605800).
  • Received Date: 2017-01-13
  • Accepted Date: 2017-04-26
  • Rev Recd Date: 2017-04-02
  • Publish Date: 2017-04-28
  • A C/C composite as a thermal conducting material was prepared by the impregnation of unidirectional mesophase pitch-based carbon fibers with mesophase pitch and graphitization at 3 000℃. It was thinned to around 10 nm in the direction parallel to the fiber axis by cutting, grinding and ion beam bombardment. Results indicate that mesophase pitch is transformed into hexagonal graphite (HG). However, there is rhombohedral graphite (RG) tens of nanometer thick mingled with the HG. Defects include the glide and rotation structures and grain boundaries.
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  • Manocha L M, Warrier A, Manocha S, et al. Thermophysical properties of densified pitch based carbon/carbon materials-II. Bidirectional composites[J]. Carbon, 2006, 44(3):488-495.
    Shim H B, Seo M K, Park S J. Thermal conductivity and mechanical properties of various cross-section types carbon fiber-reinforced composites[J]. Journal of Materials Science, 2002, 37(9):1881-1885.
    Kundu S, Naskar A K, Ogale A A, et al. Observations on a low-angle X-ray diffraction peak for AR-HP mesophase pitch[J]. Carbon, 2008, 46(8):1166-1169.
    Singer L S. Carbon fibres from mesophase pitch[J]. Fuel, 1981, 60(9):839-847.
    Matsumoto T. Mesophase pitch and its carbon fibers[J]. Pure and Applied Chemistry, 1985, 57(11):1553-1562.
    Lu S, Blanco C, Appleyard S, et al. Texture studies of carbon and graphite tapes by XRD texture goniometry[J]. Journal of Materials Science, 2002, 37(24):5283-5290.
    Fitzer E. The future of carbon-carbon composites[J]. Carbon, 1987, 25(2):163-190.
    Sheehan J E, Buesking K W, Sullivan B J. Carbon-carbon composites[J]. Annual Review of Materials Science, 1994, 24(1):19-44.
    Manocha L M, Warrier A, Manocha S, et al. Thermophysical properties of densified pitch based carbon/carbon materials-I. Unidirectional composites[J]. Carbon, 2006, 44(3):480-487.
    奚同庚. 无机材料热物性学[M]. 上海:上海科学技术出版社, 1981:18. (Xi Tong-geng. Thermophysical Properties of Inorgaani Materials[M]. Shanghai:Shanghai Science and Technology Press, 1981:18.)
    Pradère C, Batsale J C, Goyhénèche J M, et al. Thermal properties of carbon fibers at very high temperature[J]. Carbon, 2009, 47(3):737-743.
    Yuan G, Li X, Dong Z, et al. Pitch-based ribbon-shaped carbon-fiber-reinforced one-dimensional carbon/carbon composites with ultrahigh thermal conductivity[J]. Carbon, 2014, 68:413-425.
    Yuan G, Li X, Dong Z, et al. The structure and properties of ribbon-shaped carbon fibers with high orientation[J]. Carbon, 2014, 68:426-439.
    Takaku A, Shioya M. X-ray measurements and the structure of polyacrylonitrile-and pitch-based carbon fibres[J]. Journal of Materials Science, 1990, 25(11):4873-4879.
    Ozcan S, Tezcan J, Filip P. Microstructure and elastic properties of individual components of C/C composites[J]. Carbon, 2009, 47(15):3403-3414.
    Lin Q, Feng Z, Li T, et al. The effect of pyrocarbon deposition on the microstructure of graphitic foam[J]. Carbon, 2013, 56:18-26.
    Liu Y, He L, Lu X, X et al. Transmission electron microscopy study of the microstructure of unidirectional C/C composites fabricated by catalytic chemical vapor infiltration[J]. Carbon, 2013, 51:381-389.
    Endo M, Oshida K, Kobori K, T et al. Evidence for glide and rotation defects observed in well-ordered graphite fibers[J]. Journal of Materials Research, 1995, 10(6):1461-1468.
    Feng Z H, Fan Z, Kong Q, et al. Effect of high temperature treatment on the structure and thermal conductivity of 2D carbon/carbon composites with a high thermal conductivity[J]. New Carbon Materials, 2014, 29(5):357-362.
    Telling R H, Heggie M I. Stacking fault and dislocation glide on the basal plane of graphite[J]. Philosophical Magazine Letters, 2003, 83(7):411-421.
    Freise E J, Kelly A. The deformation of graphite crystals and the production of the rhombohedral form[J]. Philosophical Magazine, 1963, 8(93):1519-1533.
    林青云. 两种石墨类炭材料的显微结构研究[D]. 沈阳:中国科学院金属研究所, 2012:52. (Lin Qing-yun. TEM studies on two kinds of graphitic carbon materials[D]. Shenyang:Institute of Metal Research, Chinese Academy of Sciences, 2012:52.)
    Inagaki M, Kang F. Carbon Material Science and Engineering, From foundamentals to Applications[M]. Beijing:Tsinghua University Press, 2006:391-413.
    Lin Q Y, Li T Q, Liu Z J, et al. High-resolution TEM observations of isolated rhombohedral crystallites in graphite blocks[J]. Carbon, 2012, 50(6):2369-2371.
    Hull A W. A new method of X-ray crystal analysis[J]. Physical Review, 1917, 10(6):661-696.
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