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氮杂炭催化剂催化5-羟甲基糠醛选择性氧化制备2,5-呋喃二甲醛

滕娜 李金龙 路博琼 王玉琪 贾时宇 王英雄 侯相林

滕娜, 李金龙, 路博琼, 王玉琪, 贾时宇, 王英雄, 侯相林. 氮杂炭催化剂催化5-羟甲基糠醛选择性氧化制备2,5-呋喃二甲醛. 新型炭材料, 2019, 34(6): 593-599. doi: 10.1016/S1872-5805(19)60034-X
引用本文: 滕娜, 李金龙, 路博琼, 王玉琪, 贾时宇, 王英雄, 侯相林. 氮杂炭催化剂催化5-羟甲基糠醛选择性氧化制备2,5-呋喃二甲醛. 新型炭材料, 2019, 34(6): 593-599. doi: 10.1016/S1872-5805(19)60034-X
TENG Na, LI Jin-long, LU Bo-qiong, WANG Yu-qi, JIA Shi-yu, WANG Ying-xiong, HOU Xiang-lin. The selective aerobic oxidation of 5-hydroxymethylfurfural to produce 2,5-diformylfuran using nitrogen-doped porous carbons as catalysts. New Carbon Mater., 2019, 34(6): 593-599. doi: 10.1016/S1872-5805(19)60034-X
Citation: TENG Na, LI Jin-long, LU Bo-qiong, WANG Yu-qi, JIA Shi-yu, WANG Ying-xiong, HOU Xiang-lin. The selective aerobic oxidation of 5-hydroxymethylfurfural to produce 2,5-diformylfuran using nitrogen-doped porous carbons as catalysts. New Carbon Mater., 2019, 34(6): 593-599. doi: 10.1016/S1872-5805(19)60034-X

氮杂炭催化剂催化5-羟甲基糠醛选择性氧化制备2,5-呋喃二甲醛

doi: 10.1016/S1872-5805(19)60034-X
基金项目: 国家自然科学基金(U1710252,51703237);山西省应用基础研究项目(201701D221053).
详细信息
    作者简介:

    滕娜,高级工程师.E-mail:tengna@sxicc.ac.cn

    通讯作者:

    侯相林,研究员.E-mail:houxianglin@sxicc.ac.cn;王玉琪,助理研究员.E-mail:wangyuqi@sxicc.ac.cn

  • 中图分类号: TQ127.1+1

The selective aerobic oxidation of 5-hydroxymethylfurfural to produce 2,5-diformylfuran using nitrogen-doped porous carbons as catalysts

Funds: National Natural Science Foundation of China (U1710252, 51703237); Applied Fundamental Research Project of Shanxi Province (201701D221053).
  • 摘要: 利用氮杂炭材料作为催化剂,实现了5-羟甲基糠醛(5-HMF)选择性氧化制备2,5-呋喃二甲醛(2,5-DFF)。该氮杂炭催化剂通过壳聚糖热解制得,且壳聚糖是该催化剂的碳源和氮源,在热解过程中使用K2CO3作为活化剂。在不外加添加剂的情况下,该催化剂对5-HMF制备2,5-DFF展现出较高的催化活性。在120℃、7.5 h和2.0 MPa氧气条件下,5-HMF的转化率可达95.3%,2,5-DFF的选择性可达94.6%。氮杂炭催化剂表面的石墨型氮对分子氧的活化展现出高效的催化性能。同时,氧自由基的形成有利于5-HMF的氧化脱氢。氮杂炭催化剂表面的石墨型氮是5-HMF选择性氧化制备2,5-DFF的活性位点。本研究为无金属催化5-HMF选择性氧化制备2,5-DFF提供了一条新思路。
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出版历程
  • 收稿日期:  2019-11-10
  • 录用日期:  2020-01-03
  • 修回日期:  2019-12-05
  • 刊出日期:  2019-12-28

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