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氮掺杂稻壳基多孔炭的制备及其氧气还原反应的电催化性能

时军 林楠 林海波 杨瑾 张文礼

时军, 林楠, 林海波, 杨瑾, 张文礼. 氮掺杂稻壳基多孔炭的制备及其氧气还原反应的电催化性能[J]. 新型炭材料, 2020, 35(4): 401-409. doi: 10.1016/S1872-5805(20)60497-8
引用本文: 时军, 林楠, 林海波, 杨瑾, 张文礼. 氮掺杂稻壳基多孔炭的制备及其氧气还原反应的电催化性能[J]. 新型炭材料, 2020, 35(4): 401-409. doi: 10.1016/S1872-5805(20)60497-8
SHI Jun, LIN Nan, LIN Hai-bo, YANG Jin, ZHANG Wen-li. A N-doped rice husk-based porous carbon as an electrocatalyst for the oxygen reduction reaction[J]. NEW CARBON MATERIALS, 2020, 35(4): 401-409. doi: 10.1016/S1872-5805(20)60497-8
Citation: SHI Jun, LIN Nan, LIN Hai-bo, YANG Jin, ZHANG Wen-li. A N-doped rice husk-based porous carbon as an electrocatalyst for the oxygen reduction reaction[J]. NEW CARBON MATERIALS, 2020, 35(4): 401-409. doi: 10.1016/S1872-5805(20)60497-8

氮掺杂稻壳基多孔炭的制备及其氧气还原反应的电催化性能

doi: 10.1016/S1872-5805(20)60497-8
基金项目: 国家重点研发计划项目(2017YFB0307500);国家自然科学基金项目(21975101);吉林大学科技创新团队项目(2017TD-31);长春市"双十"重大科技专项工程(17SS018).
详细信息
    作者简介:

    时军,博士研究生.E-mail:shijunhenu@163.com

    通讯作者:

    林海波,教授.E-mail:lhb910@jlu.edu.cn;张文礼,博士.E-mail:hiteur@163.com

  • 中图分类号: TQ127.1+1

A N-doped rice husk-based porous carbon as an electrocatalyst for the oxygen reduction reaction

Funds: National Key R&D Program of China (2017YFB0307500), National Natural Science Foundation of China (21975101), Science and Technology Innovation Team Project of Jilin University (2017TD-31), Major Science and Technology Research Project of "Shuangshi Project" in Changchun City (17SS018).
  • 摘要: 本文发展了一种氮掺杂稻壳基多孔炭(N-RHPC)的制备方法,即将RHPC在氨气氛围下进行高温处理,操作简单,有利于大规模制备。结果表明,N-RHPC的介孔体积、石墨化程度明显提高,XPS N 1s谱证实了N原子在RHPC结构上的有效掺杂。N-RHPC作为ORR电催化剂具有与商用Pt/C接近的电催化活性,并具有较好的稳定性以及耐甲醇毒性,这主要是由于氨气氛围下对RHPC的高温处理使N原子进入RHPC中而引入了大量的催化位点所致。N-RHPC制备方法简单,性价比高,作为电催化剂具有很好的应用前景。
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出版历程
  • 收稿日期:  2020-05-01
  • 修回日期:  2020-07-02
  • 刊出日期:  2020-08-28

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