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简便的碳浴法制备N,S共掺杂类石墨烯炭提高氧还原反应性能

冶小文 胡立兵 刘民聪 王刚 于锋

冶小文, 胡立兵, 刘民聪, 王刚, 于锋. 简便的碳浴法制备N,S共掺杂类石墨烯炭提高氧还原反应性能[J]. 新型炭材料, 2020, 35(5): 531-539. doi: 10.1016/S1872-5805(20)60506-6
引用本文: 冶小文, 胡立兵, 刘民聪, 王刚, 于锋. 简便的碳浴法制备N,S共掺杂类石墨烯炭提高氧还原反应性能[J]. 新型炭材料, 2020, 35(5): 531-539. doi: 10.1016/S1872-5805(20)60506-6
YE Xiao-wen, HU Li-bing, LIU Min-cong, WANG Gang, YU Feng. Improved oxygen reduction performance of a N, S co-doped graphene-like carbon prepared by a simple carbon bath method[J]. NEW CARBON MATERIALS, 2020, 35(5): 531-539. doi: 10.1016/S1872-5805(20)60506-6
Citation: YE Xiao-wen, HU Li-bing, LIU Min-cong, WANG Gang, YU Feng. Improved oxygen reduction performance of a N, S co-doped graphene-like carbon prepared by a simple carbon bath method[J]. NEW CARBON MATERIALS, 2020, 35(5): 531-539. doi: 10.1016/S1872-5805(20)60506-6

简便的碳浴法制备N,S共掺杂类石墨烯炭提高氧还原反应性能

doi: 10.1016/S1872-5805(20)60506-6
基金项目: 国家自然科学基金(21865025).
详细信息
    通讯作者:

    于锋.E-mail:yufeng05@mails.ucas.ac.cn

  • 中图分类号: TQ127.1+1

Improved oxygen reduction performance of a N, S co-doped graphene-like carbon prepared by a simple carbon bath method

Funds: National Natural Science Foundation of China (21865025).
  • 摘要: 合理设计和优化氧还原反应(ORR)非金属电催化剂对于燃料电池和金属空气电池非常重要。然而,这现在仍然是一个巨大的挑战。本工作通过简单的碳浴法成功制备了N,S共掺杂的类石墨烯炭材料(GLC),并将其用于电催化氧还原反应。经高温热解和模板分解后,得到的GLC-11具有较高的比表面积(583.68 cm2/g)和孔体积(0.63 cm3/g)。其中,微孔表面积占总表面积的29.39%,微孔体积占总孔体积的12.70%。同时,通过XPS结果计算得到,GLC-11的吡啶氮和石墨氮含量总和高达92.2%。因此,GLC-11在碱性电解液中显示出了高电催化ORR性能,其中波电位(E1/2)为0.82 VRHE,优于Pt/C(E1/2=0.80 VRHE)。此外,GLC-11催化剂与商业Pt/C(20 wt%)催化剂相比表现出更好的稳定性和优异的甲醇耐受性。
  • Wenhui H, Chunhuan J, Jiabo W, et al. High-rate oxygen electroreduction over graphitic-N species exposed on 3D hierarchically porous nitrogen-doped carbons[J]. Angewandte Chemie International Edition-Englishi, 2015, 53:9503-9507.
    Wu M, Tang Q, Dong F, et al. Fe/N/S-composited hierarchically porous carbons with optimized surface functionality, composition and nanoarchitecture as electrocatalysts for oxygen reduction reaction[J]. Journal of Catalysis, 2017, 352:208-217.
    Tan H, Tang J, Henzie J, et al. Assembly of hollow carbon nanospheres on graphene nanosheets and creation of iron-nitrogen-doped porous carbon for oxygen reduction[J]. ACS Nano, 2018, 12:5674-5683
    Zhao K, Gu W, Zhao L, et al. MoS2/nitrogen-doped graphene as efficient electrocatalyst for oxygen reduction reaction[J]. Electrochimica Acta, 2015, 169:142-149.
    Wang Y, Yu F, Zhu M, et al. N-doping of plasma exfoliated graphene oxide via dielectric barrier discharge plasma treatment for the oxygen reduction reaction[J]. Journal of Materials Chemistry A, 2017, 6:2011-2017.
    Hu L, Yu F, Yuan H, et al. Improved oxygen reduction reaction via a partially oxidized co-coo catalyst on N-doped carbon synthesized by a facile sand-bath method[J]. Chinese Chemical Letters, 2018, 30:624-629.
    Liu M, Guo X, Hu L, et al. Fe3O4/Fe3C@nitrogen-doped carbon for enhancing oxygen reduction reaction[J]. ChemNanoMat, 2019, 5:187-193.
    Wassner M, Eckardt M, Gebauer C, et al. Synthesis and electrocatalytic performance of spherical core-shell tantalum (oxy)nitride@nitrided carbon composites in the oxygen reduction reaction[J]. Electrochimica Acta, 2016, 227:367-381.
    Zhao L, Sui X, Zhou Q, et al. 1D N-doped hierarchically porous hollow carbon tubes derived from a supramolecular template as metal-free electrocatalysts for a highly efficient oxygen reduction reaction[J]. Journal of Materials Chemistry A, 2018, 6:6212-6219.
    Shi J, Zhou X, Xu P, et al. Nitrogen and sulfur co-doped mesoporous carbon materials as highly efficient electrocatalysts for oxygen reduction reaction[J]. Electrochimica Acta, 2014, 145:259-269.
    Wang Y, Zhu M, Li Y, et al. Heteroatom-doped porous carbon from methyl orange dye wastewater for oxygen reduction[J]. Green Energy & Environment, 2018, 3:172-178.
    Chen X, Chen X, Xu X, et al. Sulfur-doped porous reduced graphene oxide hollow nanospheres framework as metal-free electrocatalysts for oxygen reduction reaction and supercapacitor electrode materials[J]. Nanoscale, 2014, 6:13740-13747.
    Cheng T, Wang H, Xiang C, et al. Topological defects in metal-free nanocarbon for oxygen electrocatalysis[J]. Advanced Materials, 2016, 6845-6851.
    Li Q, Cao R, Cho J, et al. Nanocarbon electrocatalysts for oxygen reduction in alkaline media for advanced energy conversion and storage[J]. Advanced Energy Materials, 2014, 4:1301415.
    Hao P, Zhao Z, Leng Y, et al. Graphene-based nitrogen self-doped hierarchical porous carbon aerogels derived from chitosan for high performance supercapacitors[J]. Nano Energy, 2015, 15:9-23
    Liu X, Amiinu I S, Liu S, et al. Transition metal/nitrogen dual-doped mesoporous graphene-like carbon nanosheets for the oxygen reduction and evolution reactions[J]. Nanoscale, 2016, 8:13311.
    Zhang J, Li Q, Wu H, et al. Nitrogen-self-doped carbon with a porous graphene-like structure as a highly efficient catalyst for oxygen reduction[J]. Journal of Materials Chemistry A, 2015, 3:10851-10857.
    Qu K, Zheng Y, Dai S, et al. Graphene oxide-polydopamine derived n, s-codoped carbon nanosheets as superior bifunctional electrocatalysts for oxygen reduction and evolution[J]. Nano Energy, 2016, 19:373-381.
    Fan H, Wang Y, Gao F, et al. Hierarchical sulfur and nitrogen co-doped carbon nanocages as efficient bifunctional oxygen electrocatalysts for rechargeable zn-air battery[J]. Journal of Energy Chemistry, 2019, 34:64-71.
    Ruili L, Dongqing W, Xinliang F, et al. Nitrogen-doped ordered mesoporous graphitic arrays with high electrocatalytic activity for oxygen reduction[J]. Angewandte Chemie International Edition, 2010, 49:2565-2569.
    Zheng P, Zhou W, Wang Y B, et al. N-doped graphene-wrapped TiO2 nanotubes with stable surface Ti3+ for visible-light photocatalysis[J]. Applied Surface Science, 2020, 512:144549.
    Liang J, Zhou R F, Chen X M, et al. Fe-N decorated hybrids of cnts grown on hierarchically porous carbon for high-performance oxygen reduction[J]. Advanced Materials, 2014, 26:6074-6079.
    Yu H, Shang L, Bian T, et al. Nitrogen-doped porous carbon nanosheets templated from g-C3N4 as metal-free electrocatalysts for efficient oxygen reduction reaction[J]. Advanced Materials, 2016, 28:5080-5086.
    Tian W, Zhang H, Sun H, et al. Heteroatom (N or N-S)-doping induced layered and honeycomb microstructures of porous carbons for CO2 capture and energy applications[J]. Advanced Functional Materials, 2016, 26:8651-8661.
    Yi L, Li K, Ge B, et al. Influence of micropore and mesoporous in activated carbon air-cathode catalysts on coxygen reduction reaction in microbial fuel cells[J]. Electrochimica Acta, 2016, 214:110-118.
    Yang HB, Miao J, Hung SF, et al. Identification of catalytic sites for oxygen reduction and oxygen evolution in n-doped graphene materials:Development of highly efficient metal-free bifunctional electrocatalyst[J]. Science Advances, 2016, 2:e1501122.
    Guo S, Deng Z, Li M, et al. Phosphorus-doped carbon nitride tubes with a layered micro-nanostructure for enhanced visible-light photocatalytic hydrogen evolution[J]. Angewandte Chemie, 2016, 55:1830-1834
    Shalom M, Inal S, Fettkenhauer C, et al. Improving carbon nitride photocatalysis by supramolecular preorganization of monomers[J]. Journal of the American Chemical Society, 2013, 135:7118-7121.
    Seo D H, Han Z J, Kumar S, et al. Supercapacitors:Structure-controlled, vertical graphene-based, binder-free electrodes from plasma-reformed butter enhance supercapacitor performance[J]. Advanced Energy Materials, 2013, 3:1316-1323.
    Zhu J, Li K, Xiao M, et al. Significantly enhanced oxygen reduction reaction performance of n-doped carbon by heterogeneous sulfur incorporation:Synergistic effect between the two dopants in metal-free catalysts[J]. Journal of Materials Chemistry A, 2016, 4:7422-7429.
    Guo D, Shibuya R, Akiba C, et al. Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts[J]. Science, 2016, 351:361-365.
    Lai L, Potts J, Zhan D, et al. Exploration of the active center structure of nitrogen-doped graphene-based catalysts for oxygen reduction reaction[J]. Energy & Environmental Science, 2012, 5:7936-7942.
    Ahn S, Yu X, Manthiram A. "Wiring" Fe-Nx-embedded porous carbon framework onto 1D nanotubes for efficient oxygen reduction reaction in alkaline and acidic media[J]. Advanced Materials, 2017, 29:1606534.
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出版历程
  • 收稿日期:  2019-06-25
  • 修回日期:  2020-04-28
  • 刊出日期:  2020-10-28

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