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多孔掺磷碳纳米管:磷酸水热合成及其在氧还原和锂硫电池中的应用

郭梦清 黄佳琦 孔祥屹 彭翃杰 税晗 钱方圆 朱林 朱万诚 张强

郭梦清, 黄佳琦, 孔祥屹, 彭翃杰, 税晗, 钱方圆, 朱林, 朱万诚, 张强. 多孔掺磷碳纳米管:磷酸水热合成及其在氧还原和锂硫电池中的应用[J]. 新型炭材料, 2016, 31(3): 352-362.
引用本文: 郭梦清, 黄佳琦, 孔祥屹, 彭翃杰, 税晗, 钱方圆, 朱林, 朱万诚, 张强. 多孔掺磷碳纳米管:磷酸水热合成及其在氧还原和锂硫电池中的应用[J]. 新型炭材料, 2016, 31(3): 352-362.
GUO Meng-qing, HUANG Jia-qi, KONG Xiang-yi, PENG Hong-jie, SHUI Han, QIAN Fang-yuan, ZHU Lin, ZHU Wan-cheng, ZHANG Qiang. Hydrothermal synthesis of porous phosphorus-doped carbon nanotubes and their use in the oxygen reduction reaction and lithium-sulfur batteries[J]. NEW CARBOM MATERIALS, 2016, 31(3): 352-362.
Citation: GUO Meng-qing, HUANG Jia-qi, KONG Xiang-yi, PENG Hong-jie, SHUI Han, QIAN Fang-yuan, ZHU Lin, ZHU Wan-cheng, ZHANG Qiang. Hydrothermal synthesis of porous phosphorus-doped carbon nanotubes and their use in the oxygen reduction reaction and lithium-sulfur batteries[J]. NEW CARBOM MATERIALS, 2016, 31(3): 352-362.

多孔掺磷碳纳米管:磷酸水热合成及其在氧还原和锂硫电池中的应用

基金项目: 国家自然科学基金(21306103,21422604);国家重大科学研究计划(2015CB932500).
详细信息
    作者简介:

    郭梦清,博士生.E-mail:guo.761@osu.edu

    通讯作者:

    黄佳琦,博士,副研究员.E-mail:jqhuang@tsinghua.edu.cn;张强,博士,副教授.E-mail:zhang-qiang@mails.tsinghua.edu.cn

  • 中图分类号: TB332

Hydrothermal synthesis of porous phosphorus-doped carbon nanotubes and their use in the oxygen reduction reaction and lithium-sulfur batteries

Funds: National Natural Scientific Foundation of China (21306103, 21422604);National Basic Research Program of China (2015CB932500).
  • 摘要: 碳纳米管优异的物理性质和可调的化学组成使其拥有广泛的应用前景。采用低温过程在碳骨架中引入磷原子预期带来可调的化学特性。本研究采用170℃下水热处理碳纳米管-磷酸混合物获得磷掺杂的碳纳米管。磷掺杂的碳管的磷含量为1.66%,比表面积为132 m2/g,热失重峰在纯氧环境下提升至694℃。当掺磷碳纳米管用于氧还原反应时,其起始电位为-0.20 V,电子转移数为2.60,反应电流显著高于无掺杂的碳纳米管。当其用作锂硫电池正极导电材料时,电极的起始容量为1106 mAh/g,电流密度从0.1 C提升至1 C时容量保留率为80%,100次循环的衰减率为每圈0.25%。
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出版历程
  • 收稿日期:  2016-05-10
  • 录用日期:  2016-06-28
  • 修回日期:  2016-06-09
  • 刊出日期:  2016-06-28

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