三维石墨烯网络在超级电容器中的应用

李晨; 张熊; 王凯; 张海涛; 孙现众; 马衍伟

doi:10.1016/S1872-5805(15)60185-8

三维石墨烯网络在超级电容器中的应用

doi: 10.1016/S1872-5805(15)60185-8

中国科学院电工研究所, 北京 100190

基金项目: 国家自然科学基金(51472238, 51025726).

详细信息

通讯作者:
马衍伟,研究员. E-mail: ywma@mail.iee.ac.cn

中图分类号: TQ127. 1⁺1
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- 被引次数: 0
出版历程
- 收稿日期: 2015-01-29
- 录用日期: 2015-09-07
- 修回日期: 2015-04-12
- 刊出日期: 2015-06-28

Three dimensional graphene networks for supercapacitor electrode materials

Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China

Funds: National Natural Science Foundation of China(51472238, 51025726).

摘要

摘要: 三维石墨烯网络(3DGNs)能够缩短电解质离子的扩散距离,提供快速电子输运通道,并能充当骨架以与赝电容材料进行复合,因而在超级电容器中得到了广泛应用。本文主要综述近年来三维石墨烯网络及其复合材料在超级电容器电极材料方面的的进展,论述提升三维石墨烯基超级电容器性能的途径,最后展望了未来三维石墨烯网络的前景。
- 三维 /
- 石墨烯 /
- 超级电容器 /
- 纳米结构 /
- 能量存储
Abstract: Three dimensional graphene networks (3DGNs) are promising electrode materials in electrochemical applications because they provide short diffusion pathways for electrolyte ions and fast transport channels for electrons, and act as an ideal scaffold for forming composites with pseudocapacitive materials to obtain a synergistic effect. This review offers an overview of recent advances in the synthesis of 3DGNs and their composites as electrodes in supercapacitors. In particular, methods to enhance the capacitive performance of 3DGN-based supercapacitors are summarized. Prospects for the future development of 3DGNs are presented at the end.
- Three dimensional /
- Graphene /
- Supercapacitor /
- Nanostructure /
- Energy storage

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参考文献(65)

Winter M, Brodd R J. What are batteries, fuel cells, and supercapacitors
[J]. Chem Rev, 2004, 104(10): 4245-4269.

Novoselov K S, Geim A K, Morozov S V, et al. Electric field effect in atomically thin carbon films
[J]. Science, 2004, 306(5696): 666-669.

Li Y F, Liu Y Z, Zhang W K, et al. Green synthesis of reduced graphene oxide paper using Zn powder for supercapacitors
[J]. Mater Lett, 2015,157: 273-276.

王旭珍, 刘宁, 胡涵, 等. 3D二硫化钼/石墨烯组装体的制备及其催化脱硫性能
[J]. 新型炭材料, 2014, 29(2): 81-88. (Wang Xu-zhen, Liu Ning, Hu Han, et al. Fabrication of three dimensional MoS₂-graphene hybrid monoliths and their catalytic performance for hydrodesulfurization
[J]. New Carbon Materials, 2014, 29(2): 81-88.)

Stoller M D, Park S J, Zhu Y W, et al. Graphene-based ultracapacitors
[J]. Nano Lett, 2008, 8(10): 3498-3502.

Zhang X, Zhang H, Li C, et al. Recent advances in porous graphene materials for supercapacitor applications
[J]. RSC Adv, 2014, 4(86): 45862-45884.

Xu Y, Huang X, Lin Z, et al. One-step strategy to graphene/Ni(OH)₂ composite hydrogels as advanced three-dimensional supercapacitor electrode materials
[J]. Nano Res, 2012, 6(1): 65-76.

Sun Y Q, Wu Q O, Shi G Q. Graphene based new energy materials
[J]. Energ Environ Sci, 2011, 4(4): 1113-1132.

Chabot V, Higgins D, Yu A P, et al. A review of graphene and graphene oxide sponge: material synthesis and applications to energy and the environment
[J]. Energ Environ Sci, 2014, 7(5): 1564-1596.

Cao X H, Yin Z Y, Zhang H. Three-dimensional graphene materials: preparation, structures and application in supercapacitors
[J]. Energ Environ Sci, 2014, 7(6): 1850-1865.

Li C, Shi G Q. Three-dimensional graphene architectures
[J]. Nanoscale, 2012, 4(18): 5549-5563.

Liu Y Z, Chen C M, Li Y F, et al. Crumpled reduced graphene oxide by flame-induced reduction of graphite oxide for supercapacitive energy storage
[J]. J Mater Chem A, 2014, 2(16): 5730-5737.

Xu Y, Sheng K, Li C, et al. Self-assembled graphene hydrogel via a one-step hydrothermal process
[J]. ACS Nano, 2010, 4(7): 4324-4330.

Zhang L, Shi G Q. Preparation of highly conductive graphene hydrogels for fabricating supercapacitors with high rate capability
[J]. J Phys Chem C, 2011, 115(34): 17206-17212.

Shi J L, Du W C, Yin Y X, et al. Hydrothermal reduction of three-dimensional graphene oxide for binder-free flexible supercapacitors
[J]. J Mater Chem A, 2014, 2(28): 10830-10834.

Xu Y, Lin Z, Huang X, et al. Flexible solid-state supercapacitors based on three-dimensional graphene hydrogel films
[J]. ACS Nano, 2013, 7(5): 4042-4049.

Jiang L, Fan Z. Design of advanced porous graphene materials: from graphene nanomesh to 3D architectures
[J]. Nanoscale, 2014, 6(4): 1922-1945.

盛凯旋, 徐宇曦, 李春, 等. 化学还原氧化石墨烯制备高性能石墨烯自组装水凝胶
[J]. 新型炭材料, 2011, 26(1): 9-15. (Sheng Kai-xuan, Xu Yu-xi, Li Chuen, et al. High-performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide
[J]. New Carbon Materials, 2011, 26(1): 9-15.)

Zhang X T, Sui Z Y, Xu B, et al. Mechanically strong and highly conductive graphene aerogel and its use as electrodes for electrochemical power sources
[J]. J Mater Chem, 2011, 21(18): 6494-6497.

Luan V H, Tien H N, Hoa L T, et al. Synthesis of a highly conductive and large surface area graphene oxide hydrogel and its use in a supercapacitor
[J]. J Mater Chem A, 2013, 1(2): 208-211.

Wu Q, Sun Y, Bai H, et al. High-performance supercapacitor electrodes based on graphene hydrogels modified with 2-aminoanthraquinone moieties
[J]. Phys Chem Chem Phys, 2011, 13(23): 11193-11198.

Chen Z, Ren W, Gao L, et al. Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition
[J]. Nat Mater, 2011, 10(6): 424-428.

Huang H, Xu L, Tang Y, et al. Facile synthesis of nickel network supported three-dimensional graphene gel as a light weight and binder-free electrode for high rate performance supercapacitor application
[J]. Nanoscale, 2014, 6(4): 2426-2433.

Huang H, Tang Y, Xu L, et al. Direct formation of reduced graphene oxide and 3D light weight nickel network composite foam by hydrohalic acids and its application for high-performance supercapacitors
[J]. ACS Appl Mater Interfaces, 2014, 6(13): 10248-10257.

He Y M, Chen W J, Li X D, et al. Freestanding three-dimensional graphene/MnO₂ composite networks as ultra light and flexible supercapacitor electrodes
[J]. ACS Nano, 2013, 7(1): 174-182.

Wang X, Zhang Y, Zhi C, et al. Three-dimensional strutted graphene grown by substrate-free sugar blowing for high-power-density supercapacitors
[J]. Nat Commun, 2013, 4: 2905.

Niu Z, Chen J, Hng H H, et al. A leavening strategy to prepare reduced graphene oxide foams
[J]. Adv Mater, 2012, 24(30): 4144-4150.

Chen M, Wang H, Li L, et al. Novel and facile method, dynamic self-assemble, to prepare SnO₂/rGO droplet aerogel with complex morphologies and their application in supercapacitors
[J]. Acs Appl Mater Inter, 2014, 6(16): 14327-14337.

Wang H, Xu Z, Yi H, et al. One-step preparation of single-crystalline Fe₂O₃particles/graphene composite hydrogels as high performance anode materials for supercapacitors
[J]. Nano Energy, 2014, 786-96.

Wang H W, Yi H, Chen X, et al. One-step strategy to three-dimensional graphene/VO₂ nanobelt composite hydrogels for high performance supercapacitors
[J]. J Mater Chem A, 2014, 2(4): 1165-1173.

Ge J, Yao H B, Hu W, et al. Facile dip coating processed graphene/MnO₂ nanostructured sponges as high performance supercapacitor electrodes
[J]. Nano Energy, 2013, 2(4): 505-513.

Wang C C, Chen H C, Lu S Y. Manganese oxide/graphene aerogel composites as an outstanding supercapacitor electrode material
[J]. Chem Eur J, 2014, 20(2): 517-523.

Wu S, Chen W, Yan L. Fabrication of a 3D MnO₂/graphene hydrogel for high-performance asymmetric supercapacitors
[J]. J Mater Chem A, 2014, 2(8): 2765.

Zhai T, Wang F, Yu M, et al. 3D MnO₂-graphene composites with large areal capacitance for high-performance asymmetric supercapacitors
[J]. Nanoscale, 2013, 5(15): 6790.

Ji C C, Xu M W, Bao S J, et al. Self-assembled three-dimensional interpenetrating porous graphene aerogels with MnO₂ coating and their application as high-performance supercapacitors
[J]. New J Chem, 2013, 37(12): 4199-4205.

Wang W, Guo S, Lee I, et al. Hydrous ruthenium oxide nanoparticles anchored to graphene and carbon nanotube hybrid foam for supercapacitors
[J]. Sci Rep, 2014, 44452.

Dong X C, Xu H, Wang X W, et al. 3D graphene-cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection
[J]. ACS Nano, 2012, 6(4): 3206-3213.

Yuan J, Zhu J, Bi H, et al. Graphene-based 3D composite hydrogel by anchoring Co₃O₄ nanoparticles with enhanced electrochemical properties
[J]. Phys Chem Chem Phys, 2013, 15(31): 12940-12945.

Liu J J, Lv W, Wei W, et al. A three-dimensional graphene skeleton as a fast electron and ion transport network for electrochemical applications
[J]. J Mater Chem A, 2014, 2(9): 3031-3037.

Patil U M, Lee S C, Sohn J S, et al. Enhanced symmetric supercapacitive performance of Co(OH)₂ nanorods decorated conducting porous graphene foam electrodes
[J]. Electrochim Acta, 2014, 129334-342.

Ji J, Zhang L L, Ji H, et al. Nanoporous Ni(OH)₂ thin film on 3D Ultrathin-graphite foam for asymmetric supercapacitor
[J]. ACS Nano, 2013, 7(7): 6237-6243.

Chen S, Duan J, Tang Y, et al. Hybrid hydrogels of porous graphene and nickel hydroxide as advanced supercapacitor materials
[J]. Chem Eur J, 2013, 19(22): 7118-7124.

Zhu G, He Z, Chen J, et al. Highly conductive three-dimensional MnO₂-carbon nanotube-graphene-Ni hybrid foam as a binder-free supercapacitor electrode
[J]. Nanoscale, 2014, 6(2): 1079-1085.

Patil U M, Sohn J S, Kulkarni S B, et al. Enhanced supercapacitive performance of chemically grown cobalt-nickel hydroxides on three-dimensional graphene foam electrodes
[J]. ACS Appl Mater Interfaces, 2014, 6(4): 2450-2458.

Cao X, Shi Y, Shi W, et al. Preparation of novel 3D graphene networks for supercapacitor applications
[J]. Small, 2011, 7(22): 3163-3168.

Wang G, Zhang L, Zhang J. A review of electrode materials for electrochemical supercapacitors
[J]. Chem Soc Rev, 2012, 41(2): 797-828.

Zhao Y, Liu J, Hu Y, et al. Highly compression-tolerant supercapacitor based on polypyrrole-mediated graphene foam electrodes
[J]. Adv Mater, 2013, 25(4): 591-595.

Sun R, Chen H, Li Q, et al. Spontaneous assembly of strong and conductive graphene/polypyrrole hybrid aerogels for energy storage
[J]. Nanoscale, 2014, 6(21): 12912-12920.

Ye S, Feng J. Self-assembled three-dimensional hierarchical graphene/polypyrrole nanotube hybrid aerogel and its application for supercapacitors
[J]. ACS Appl Mater Interfaces, 2014, 6(12): 9671-9679.

Tai Z, Yan X, Xue Q. Three-dimensional graphene/polyaniline composite hydrogel as supercapacitor electrode
[J]. J Electrochem Soc, 2012, 159(10): A1702-A1709.

Yang F, Xu M, Bao S-J, et al. Self-assembled hierarchical graphene/polyaniline hybrid aerogels for electrochemical capacitive energy storage
[J]. Electrochim Acta, 2014, 137: 381-387.

Kulkarni S B, Patil U M, Shackery I, et al. High-performance supercapacitor electrode based on a polyaniline nanofibers/3D graphene framework as an efficient charge transporter
[J]. J Mater Chem A, 2014, 2(14): 4989-4998.

Zhang J, Wang J, Yang J, et al. Three-dimensional macroporous graphene foam filled with mesoporous polyaniline network for high areal capacitance
[J]. ACS Sustainable Chem Eng, 2014, 2(10): 2291-2296.

Yu P P, Zhao X, Huang Z L, et al. Free-standing three-dimensional graphene and polyaniline nanowire arrays hybrid foams for high-performance flexible and lightweight supercapacitors
[J]. J Mater Chem A, 2014, 2(35): 14413-14420.

Rao C N R, Gopalakrishnan K, Govindaraj A. Synthesis, properties and applications of graphene doped with boron, nitrogen and other elements
[J]. Nano Today, 2014, 9(3): 324-343.

Sun L, Wang L, Tian C G, et al. Nitrogen-doped graphene with high nitrogen level via a one-step hydrothermal reaction of graphene oxide with urea for superior capacitive energy storage
[J]. Rsc Adv, 2012, 2(10): 4498-4506.

Zhao Y, Hu C, Hu Y, et al. A versatile, ultralight, nitrogen-doped graphene framework
[J]. Angew Chem Int Ed, 2012, 51(45): 11371-11375.

Guo H L, Su P, Kang X F, et al. Synthesis and characterization of nitrogen-doped graphene hydrogels by hydrothermal route with urea as reducing-doping agents
[J]. J Mater Chem A, 2013, 1(6): 2248-2255.

Chen P, Yang J J, Li S S, et al. Hydrothermal synthesis of macroscopic nitrogen-doped graphene hydrogels for ultrafast supercapacitor
[J]. Nano Energy, 2013, 2(2): 249-256.

Zuo Z C, Jiang Z Q, Manthiram A. Porous B-doped graphene inspired by fried-ice for supercapacitors and metal-free catalysts
[J]. J Mater Chem A, 2013, 1(43): 13476-13483.

Wu Z S, Winter A, Chen L, et al. Three-dimensional nitrogen and boron co-doped graphene for high-performance all-solid-state supercapacitors
[J]. Adv Mater, 2012, 24(37): 5130-5135.

Zhang L, Zhang F, Yang X, et al. Porous 3D graphene-based bulk materials with exceptional high surface area and excellent conductivity for supercapacitors
[J]. Sci Rep, 2013, 31408.

Yun S, Kang S O, Park S, et al. CO₂-activated, hierarchical trimodal porous graphene frameworks for ultrahigh and ultrafast capacitive behavior
[J]. Nanoscale, 2014, 6(10): 5296-5302.

Ju H F, Song W L, Fan L Z. Rational design of graphene/porous carbon aerogels for high-performance flexible all-solid-state supercapacitors
[J]. J Mater Chem A, 2014, 2(28): 10895-10903.

Xu Y, Lin Z, Zhong X, et al. Holey graphene frameworks for highly efficient capacitive energy storage
[J]. Nat Commun, 2014, 5: 4554.

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