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不粘煤基活性炭作超级电容器电极材料:硼、氮掺杂对其电化学性能的影响

陆倩 徐园园 木沙江 李文翠

陆倩, 徐园园, 木沙江, 李文翠. 不粘煤基活性炭作超级电容器电极材料:硼、氮掺杂对其电化学性能的影响[J]. 新型炭材料, 2017, 32(5): 442-450. doi: 10.1016/S1872-5805(17)60133-1
引用本文: 陆倩, 徐园园, 木沙江, 李文翠. 不粘煤基活性炭作超级电容器电极材料:硼、氮掺杂对其电化学性能的影响[J]. 新型炭材料, 2017, 32(5): 442-450. doi: 10.1016/S1872-5805(17)60133-1
LU Qian, XU Yuan-yuan, MU Sha-jiang, LI Wen-cui. The effect of nitrogen and/or boron doping on the electrochemical performance of non-caking coal-derived activated carbons for use as supercapacitor electrodes[J]. NEW CARBON MATERIALS, 2017, 32(5): 442-450. doi: 10.1016/S1872-5805(17)60133-1
Citation: LU Qian, XU Yuan-yuan, MU Sha-jiang, LI Wen-cui. The effect of nitrogen and/or boron doping on the electrochemical performance of non-caking coal-derived activated carbons for use as supercapacitor electrodes[J]. NEW CARBON MATERIALS, 2017, 32(5): 442-450. doi: 10.1016/S1872-5805(17)60133-1

不粘煤基活性炭作超级电容器电极材料:硼、氮掺杂对其电化学性能的影响

doi: 10.1016/S1872-5805(17)60133-1
基金项目: 国家自然科学基金(NSNF,U1303192);新疆维吾尔族自治区自然科学基金项目(2012211A108).
详细信息
    作者简介:

    陆倩,硕士研究生.

    通讯作者:

    李文翠,教授.E-mail:wencuili@dlut.edu.cn

  • 中图分类号: TQ127.1+1

The effect of nitrogen and/or boron doping on the electrochemical performance of non-caking coal-derived activated carbons for use as supercapacitor electrodes

Funds: National Natural Science Foundation of China (NSNF,U1303192); Natural Science Fund Project of Xinjiang uighur autonomous region (2012211A108).
  • 摘要: 以新疆不粘煤为原料,三聚氰胺为氮源,硼酸为硼源,通过球磨和后续活化过程合成硼,氮掺杂及硼氮共掺杂煤基活性炭。氮吸附结果显示杂原子掺杂可提高活性炭中介孔的含量。红外和X光电子能谱结果显示,硼、氮原子存在于炭骨架中。循环伏安,恒流充放电及电化学阻抗分析说明硼、氮掺杂活性炭的电化学性能优于非掺杂活性炭。其中,硼氮共掺杂活性炭具有176 F·g-1的高比容量。循环20 000次容量保持率为96%。共掺杂活性炭优异的电化学性能归因于硼氮的协同作用。
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出版历程
  • 收稿日期:  2017-04-25
  • 录用日期:  2017-11-13
  • 修回日期:  2017-08-01
  • 刊出日期:  2017-10-28

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