氧化石墨烯/聚合物基复合膜对水,氨水与二氯甲烷的渗透性

Ali Asghar Zomorodkia; Saeed Bazgir; Davood Zaarei; Mohsen Gorji; Mehdi Ardjmand

doi:10.1016/S1872-5805(20)60514-5

氧化石墨烯/聚合物基复合膜对水,氨水与二氯甲烷的渗透性

doi: 10.1016/S1872-5805(20)60514-5

1.
Department of Chemical Engineering, Science and Research Branch, Islamic Azad University, Tehran, Postal code:1477893855, Iran;
2.
Department of Polymer Engineering, Science and Research Branch, Islamic Azad University, Tehran, Postal code:1477893855 Iran;
3.
Department of Polymer Engineering, South Tehran Branch, Islamic Azad University, Tehran, Postal code:1584743311, Iran;
4.
New Technologies Research Center (NTRC) Amirkabir University of Technology, Tehran, Postal code:159163-4311, Iran;
5.
Department of Chemical Engineering, South Tehran Branch, Islamic Azad University, Tehran, Postal code:1584743311, Iran.

详细信息

通讯作者:
Saeed Bazgir.E-mail:bazgir@srbiau.ac.ir

中图分类号: TB33
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- 文章访问数: 430
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- 被引次数: 0
出版历程
- 收稿日期: 2020-02-02
- 修回日期: 2020-03-13
- 刊出日期: 2020-12-31

Permeation of water, ammonia and dichloromethane through graphene oxide/polymeric matrix composite membranes

1.
Department of Chemical Engineering, Science and Research Branch, Islamic Azad University, Tehran, Postal code:1477893855, Iran;
2.
Department of Polymer Engineering, Science and Research Branch, Islamic Azad University, Tehran, Postal code:1477893855 Iran;
3.
Department of Polymer Engineering, South Tehran Branch, Islamic Azad University, Tehran, Postal code:1584743311, Iran;
4.
New Technologies Research Center(NTRC) Amirkabir University of Technology, Tehran, Postal code:159163-4311, Iran;
5.
Department of Chemical Engineering, South Tehran Branch, Islamic Azad University, Tehran, Postal code:1584743311, Iran

摘要

摘要: 以氧化石墨烯（GO）、聚氨酯（PU）和亲水性聚2-丙烯酰胺-2-甲基丙烷磺酸（PAMPS）为原料，制备出无支撑的PU基复合膜和PAMPS基复合膜。研究氧化石墨烯聚合物基膜用于含极性材料废液如水、氨水、以及含非极性二氯甲烷和氨-二氯甲烷混合废液的渗透行为。采用不同表征方法如X射线衍射仪（XRD）、接触角、场发射扫描电子显微镜（FESEM）、红外光谱仪（FT-IR）和力学性能测试仪来评价所制复合膜的综合性能。采用ASTM E96/96-M14设备进行复合膜的渗透测试。结果表明，PAMPS基复合膜因较高的亲水性，具有最佳的水和氨渗透性能，而PU基复合膜具有最佳的二氯甲烷渗透性，最差的水和氨的渗透性。
- 聚氨酯 /
- 聚2-丙烯酰胺-2-甲基丙烷磺酸 /
- 氧化石墨烯 /
- 渗透性 /
- 疏水性 /
- 亲水性
Abstract: The permeation of polar molecules (water and ammonia), non-polar dichloromethane and a mixture of ammonia and dichloromethane through graphene oxide (GO)/polymer matrix composite membranes was investigated. Results indicated that a hydrophilic poly(2-acrylamido -2 -methyl propane sulfonic acid) (PAMPS) based membrane had the highest permeability for water and ammonia due to the high hydrophilicity of the polymer matrix while a hydrophobic polyurethane (PU)-based membrane had the best permeation performance for dichloromethane and the worst performance for water and ammonia. Adding the GO to PU or PAMPS polymers increases the negative charge due to the negatively charged nature of GO caused by its oxygen-containing functional groups, which increases the amounts of absorbed water and ammonia due to the positive charge of the hydrogen atoms in these two molecules.
- PU /
- PAMPS /
- Graphene oxide /
- Permeability /
- Hydrophobic /
- Hydrophilic

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