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Co/N-doped carbon catalyst derived from metal-organic framework (ZIF-8@ZIF-67) for efficient oxygen reduction reaction (ORR)

ZHANG Ya-ting LI Si-yi ZHANG Na-na LIN Gang WANG Rui-qi YANG Meng-nan LI Ke-ke

张亚婷, 李思祎, 张娜娜, 林港, 王瑞琪, 杨梦囡, 李可可. 金属有机骨架(ZIF-8@ZIF-67)衍生的Co/N共掺杂碳基催化剂在氧还原反应(ORR)中的应用研究. 新型炭材料. doi: 10.1016/S1872-5805(22)60609-7
引用本文: 张亚婷, 李思祎, 张娜娜, 林港, 王瑞琪, 杨梦囡, 李可可. 金属有机骨架(ZIF-8@ZIF-67)衍生的Co/N共掺杂碳基催化剂在氧还原反应(ORR)中的应用研究. 新型炭材料. doi: 10.1016/S1872-5805(22)60609-7
ZHANG Ya-ting, LI Si-yi, ZHANG Na-na, LIN Gang, WANG Rui-qi, YANG Meng-nan, LI Ke-ke. Co/N-doped carbon catalyst derived from metal-organic framework (ZIF-8@ZIF-67) for efficient oxygen reduction reaction (ORR). New Carbon Mater.. doi: 10.1016/S1872-5805(22)60609-7
Citation: ZHANG Ya-ting, LI Si-yi, ZHANG Na-na, LIN Gang, WANG Rui-qi, YANG Meng-nan, LI Ke-ke. Co/N-doped carbon catalyst derived from metal-organic framework (ZIF-8@ZIF-67) for efficient oxygen reduction reaction (ORR). New Carbon Mater.. doi: 10.1016/S1872-5805(22)60609-7

金属有机骨架(ZIF-8@ZIF-67)衍生的Co/N共掺杂碳基催化剂在氧还原反应(ORR)中的应用研究

doi: 10.1016/S1872-5805(22)60609-7
基金项目: 国家自然科学基金项目(No. U1810113, U1703251);陕西省自然科学基金项目(No. 2019JLP-12),陕西省创新能力支持计划项目(No. 2019TD-021).
详细信息
    通讯作者:

    张亚婷,教授. E-mail:isyating@163.com

Co/N-doped carbon catalyst derived from metal-organic framework (ZIF-8@ZIF-67) for efficient oxygen reduction reaction (ORR)

Funds: This work was supported by the National Natural Science Foundation of China (Nos. U1810113 and U1703251); Natural Science Foundation of Shaanxi(No. 2019JLP-12), Shaanxi Provincial Innovation Capability Support Program (No. 2019TD-021)
More Information
    Corresponding author: ZHANG Ya-ting, Ph. D, Professor. E-mail: isyating@163.com
  • 摘要: 在燃料电池中,碳基氧还原反应 (ORR) 催化剂被认为是昂贵的铂基催化剂的潜在替代品。近年来,由过渡金属和氮原子共掺杂的碳基材料 (M-N-C) 以其低成本和优异的活性而受到研究人员的广泛关注。在此,我们通过精心设计的杨桃状MOF (ZIF-8@ZIF-67) 为前驱体,采用简单的一步热解法制备钴、氮共掺杂多孔碳材料 (命名为Co-N@CNT-C800)。Co-N@CNT-C800产生了大量碳纳米管 (CNT),独特的三维结构保证了较高的比表面积和孔隙率,有利于ORR的传质和电子传递。同时,Co-N@CNT-C800在碱性介质中表现出优异的半波电位和极限电流密度,分别为0.841 V和5.07 mA·cm−2。此外,与商用Pt/C材料相比,Co-N@CNT-C800还表现出优异的电化学稳定性和耐甲醇毒性。该策略为制备低成本、高活性的能量转换电催化剂提供了一种有效的方法。
  • Figure  1.  Schematic illustration of the preparation of the Co-N@CNT-C800

    Figure  2.  (a) ZIF-8 SEM image, (b) ZIF-8@ZIF-67 SEM image, (c) Co-N@CNT-C800 high-magnification SEM image, (d, e) TEM images of Co-N@CNT-C800, (f) HRTEM image of Co-N@CNT-C800, (g) Co-N@CNT-C800 SAED patterns, (h) Co-N@CNT-C800 elemental mapping image (C, (bule); Co, (red); N,(cyan); ).

    Figure  3.  (a) XRD patterns of Co-N@CNT-C800, C-ZIF-67800, and C-ZIF-8800, (b) Raman spectra of Co-N@CNT-C800, C-ZIF-67800, and C-ZIF-8800, (c) N2 sorption isotherms of Co-N@CNT-C800, C-ZIF-67800, and C-ZIF-8800, (d) The pore size distribution of the Co-N@CNT-C800, C-ZIF-67800, and C-ZIF-8800.

    Figure  4.  XPS spectra of Co-N@CNT-C800. (a) survey, (b) C 1s, (c) N 1s and (d) Co 2p.

    Figure  5.  (a) CVs of Co-N@CNT-C800, C-ZIF-8800, and C-ZIF-67800 in 0.1 M O2/N2-saturated KOH electrolyte, (b) LSV curves of C-ZIF-8800, C-ZIF-67800, Co-N@CNT-C700, Co-N@CNT-C800, Co-N@CNT-C900, and commercially available Pt/C in O2-saturated 0.1 M KOH solution, (c) E1/2 of different samples, (d) Limiting current density for different samples.

    Figure  6.  (a) LSV curves of Co-N@CNT-C800 in 0.1 M O2-saturated KOH electrolyte at different rotational speeds (from 400 to 2500 rpm) (scanning rate: 10 mV s−1), (b) Koutecky-Levich profiles of Co-N@CNT-C800 catalyst obtained from Fig. 6 (a) at 0.2-0.5V, (c) The number of transferred electrons of Co-N@CNT-C800 at 0.2-0.5 V, (d) Tafel profiles of Co-N@CNT-C800, C-ZIF-8800, C-ZIF-67800, and commercially available Pt/C.

    Figure  7.  (a) RRDE tests (1600 rpm) of Co-N@CNT-C800 for ORR in O2-saturated 0.1 M KOH electrolyte at a scan rate of 10 mV s−1, (b) the number of transferred electrons and yield of H2O2 calculated from the RRDE results, (c) Chronoamperometric measurement of Co-N@CNT-C800 and the commercial Pt/C by injecting 2 wt % of methanol at 300 s, (d) Chronoamperometric measurement Co-N@CNT-C800 and the commercial Pt/C obtained at a fixed potential of 0.60 V in O2-saturated 0.1 M KOH electrolyte at 1600 rpm.

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  • 收稿日期:  2021-01-01
  • 网络出版日期:  2022-04-22

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