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A carbon catalyst doped with Co and N derived from the metal-organic framework hybrid (ZIF-8@ZIF-67) for efficient oxygen reduction reaction

ZHANG Ya-ting LI Si-yi ZHANG Na-na LIN Gang WANG Rui-qi YANG Meng-nan LI Ke-ke

张亚婷, 李思祎, 张娜娜, 林港, 王瑞琪, 杨梦囡, 李可可. 金属有机骨架(ZIF-8@ZIF-67)衍生的Co/N共掺杂碳基催化剂在氧还原反应(ORR)中的应用. 新型炭材料(中英文), 2023, 38(1): 200-210. doi: 10.1016/S1872-5805(22)60609-7
引用本文: 张亚婷, 李思祎, 张娜娜, 林港, 王瑞琪, 杨梦囡, 李可可. 金属有机骨架(ZIF-8@ZIF-67)衍生的Co/N共掺杂碳基催化剂在氧还原反应(ORR)中的应用. 新型炭材料(中英文), 2023, 38(1): 200-210. doi: 10.1016/S1872-5805(22)60609-7
ZHANG Ya-ting, LI Si-yi, ZHANG Na-na, LIN Gang, WANG Rui-qi, YANG Meng-nan, LI Ke-ke. A carbon catalyst doped with Co and N derived from the metal-organic framework hybrid (ZIF-8@ZIF-67) for efficient oxygen reduction reaction. New Carbon Mater., 2023, 38(1): 200-210. doi: 10.1016/S1872-5805(22)60609-7
Citation: ZHANG Ya-ting, LI Si-yi, ZHANG Na-na, LIN Gang, WANG Rui-qi, YANG Meng-nan, LI Ke-ke. A carbon catalyst doped with Co and N derived from the metal-organic framework hybrid (ZIF-8@ZIF-67) for efficient oxygen reduction reaction. New Carbon Mater., 2023, 38(1): 200-210. doi: 10.1016/S1872-5805(22)60609-7

金属有机骨架(ZIF-8@ZIF-67)衍生的Co/N共掺杂碳基催化剂在氧还原反应(ORR)中的应用

doi: 10.1016/S1872-5805(22)60609-7
基金项目: 国家自然科学基金项目(U1810113, U1703251);陕西省自然科学基金项目(2019JLP-12),陕西省创新能力支持计划项目(2019TD-021)
详细信息
    通讯作者:

    张亚婷,教授. E-mail:isyating@163.com

  • 中图分类号: TB33

A carbon catalyst doped with Co and N derived from the metal-organic framework hybrid (ZIF-8@ZIF-67) for efficient oxygen reduction reaction

Funds: This work was supported by the National Natural Science Foundation of China (U1810113 and U1703251); Natural Science Foundation of Shaanxi (2019JLP-12), Shaanxi Provincial Innovation Capability Support Program (2019TD-021)
More Information
    Corresponding author: ZHANG Ya-ting, Ph. D, Professor. E-mail: isyating@163.com
  • 摘要: 在燃料电池中,碳基氧还原反应 (ORR) 催化剂被认为是昂贵的铂基催化剂的潜在替代品。近年来,由过渡金属和氮原子共掺杂的碳基材料 (M-N-C) 以其低成本和优异的活性而受到研究人员的广泛关注。在此,通过精心设计的杨桃状MOF (ZIF-8@ZIF-67) 为前驱体,采用简单的一步热解法制备钴、氮共掺杂多孔炭材料 (命名为Co-N@CNT-C800)。Co-N@CNT-C800产生了大量碳纳米管 (CNT),独特的三维结构保证了较高的比表面积和孔隙率,有利于ORR的传质和电子传递。同时,Co-N@CNT-C800在碱性介质中表现出优异的半波电位和极限电流密度,分别为0.841 V和5.07 mA·cm−2。此外,与商用Pt/C材料相比,Co-N@CNT-C800还表现出优异的电化学稳定性和耐甲醇毒性。该策略为制备低成本、高活性的能量转换电催化剂提供了一种有效的方法。
  • FIG. 2072.  FIG. 2072.

    FIG. 2072..  FIG. 2072.

    Figure  1.  Schematic illustration of the preparation of the Co-N@CNT-C800

    Figure  2.  (a) SEM image of ZIF-8. (b) SEM image of ZIF-8@ZIF-67. (c) High-magnification SEM image of Co-N@CNT-C800. (d, e) TEM images of Co-N@CNT-C800. (f) HRTEM image of Co-N@CNT-C800. (g) SAED patterns of Co-N@CNT-C800. (h) Elemental mapping image of C (bule), Co (red) and N (cyan) in Co-N@CNT-C800

    Figure  3.  (a) XRD patterns of Co-N@CNT-C800, C-ZIF-67800 and C-ZIF-8800. (b) Raman spectra of Co-N@CNT-C800, C-ZIF-67800 and C-ZIF-8800. (c) N2 sorption isotherms of Co-N@CNT-C800, C-ZIF-67800 and C-ZIF-8800. (d) The pore size distributions of the Co-N@CNT-C800, C-ZIF-67800 and C-ZIF-8800

    Figure  4.  XPS spectra of Co-N@CNT-C800: (a) survey, (b) C1s, (c) N1s and (d) Co2p

    Figure  5.  (a) CVs of Co-N@CNT-C800, C-ZIF-8800, and C-ZIF-67800 in 0.1 mol L−1 O2/N2-saturated KOH electrolyte. (b) LSV curves of C-ZIF-8800, C-ZIF-67800, Co-N@CNT-C700, Co-N@CNT-C800, Co-N@CNT-C900 and commercially available Pt/C in O2-saturated 0.1 mol L−1 KOH solution. (c) E1/2 values of different samples. (d) Limiting current densities for different samples

    Figure  6.  (a) LSV curves of Co-N@CNT-C800 in 0.1 mol L−1 O2-saturated KOH electrolyte at different rotational speeds (from 400 to 2500 r min−1) (scanning rate: 10 mV s−1). (b) Koutecky-Levich profiles of Co-N@CNT-C800 catalyst obtained from Fig. 6 (a) at 0.2-0.5V. (c) The number of transferred electrons of Co-N@CNT-C800 at 0.2-0.5 V. (d) Tafel profiles of Co-N@CNT-C800, C-ZIF-8800, C-ZIF-67800 and commercially available Pt/C

    Figure  7.  (a) RRDE tests (1600 r min−1) of Co-N@CNT-C800 for ORR in O2-saturated 0.1 mol L−1 KOH electrolyte at a scan rate of 10 mV s−1. (b) The number of transferred electrons and yield of H2O2 calculated from the RRDE results. (c) Chronoamperometric measurement of Co-N@CNT-C800 and the commercial Pt/C by injecting 2 wt % of methanol at 300 s. (d) Chronoamperometric measurement of Co-N@CNT-C800 and the commercial Pt/C obtained at a fixed potential of 0.60 V in O2-saturated 0.1 mol L−1 KOH electrolyte at 1600 r min−1

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出版历程
  • 收稿日期:  2021-01-13
  • 修回日期:  2022-03-25
  • 网络出版日期:  2022-04-22
  • 刊出日期:  2023-01-06

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