Preparation of porous graphitic carbon and its dual-ion capacitance energy storage mechanism

ZHAN Chang-zhen; ZENG Xiao-jie; LV Rui-tao; SHEN Yang; HUANG Zheng-hong; KANG Fei-yu

doi:10.1016/S1872-5805(23)60727-9

Volume 38 Issue 3

Jun. 2023

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Article Navigation > New Carbon Mater. > 2023 > 38(3): 576-582

ZHAN Chang-zhen, ZENG Xiao-jie, LV Rui-tao, SHEN Yang, HUANG Zheng-hong, KANG Fei-yu. Preparation of porous graphitic carbon and its dual-ion capacitance energy storage mechanism. New Carbon Mater., 2023, 38(3): 576-582. doi: 10.1016/S1872-5805(23)60727-9

Citation:

ZHAN Chang-zhen, ZENG Xiao-jie, LV Rui-tao, SHEN Yang, HUANG Zheng-hong, KANG Fei-yu. Preparation of porous graphitic carbon and its dual-ion capacitance energy storage mechanism. New Carbon Mater., 2023, 38(3): 576-582. doi: 10.1016/S1872-5805(23)60727-9

Citation:

ZHAN Chang-zhen, ZENG Xiao-jie, LV Rui-tao, SHEN Yang, HUANG Zheng-hong, KANG Fei-yu. Preparation of porous graphitic carbon and its dual-ion capacitance energy storage mechanism. New Carbon Mater., 2023, 38(3): 576-582. doi: 10.1016/S1872-5805(23)60727-9

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Preparation of porous graphitic carbon and its dual-ion capacitance energy storage mechanism

doi: 10.1016/S1872-5805(23)60727-9

ZHAN Chang-zhen^{1, 3
,},
ZENG Xiao-jie²,
LV Rui-tao^{1, 2},
SHEN Yang¹,
HUANG Zheng-hong^{1, 2
,
,},
KANG Fei-yu^{1, 2}

1.
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
2.
Key Lab of Advanced Materials, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
3.
Mengjing Advanced Graphite Institute, Beijing 101318, China

More Information

Author Bio:
ZHAN Chang-zhen, Ph.D. E-mail: zhanchangzhen@sina.com
Corresponding author: HUANG Zheng-hong, Ph.D, Professor. E-mail: zhhuang@tsinghua.edu.cn
Received Date: 2019-04-26
Rev Recd Date: 2022-10-25

Available Online: 2023-03-01

Publish Date: 2023-06-01

Abstract

Abstract

A lithium-ion capacitor, a combination of a lithium-ion batteries and a supercapacitor, is expected to have the advantages of both a batteries and a capacitor and has attracted worldwide attention in recent years. However, its energy storage is limited due to the electric double-layer capacitance mechanism of the positive electrode. Consequently, to fundamentally improve the performance of the positive electrode material, a novel dual-ion hybrid capacitance energy storage mechanism is proposed. Porous graphitic carbon with a partially graphitized structure and hierarchical porous structure was synthesized by a one-step heat treatment method using potassium/magnesium/iron citrate as precursors. When used as the positive electrode material, the porous graphitic carbon has a dual-ion hybrid capacitance mechanism in an electrolyte produced using a mixture of Li-TFSI (bis(trifluoromethylsulfonyl) amine lithium salt) and BMIm-TFSI (1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide), which combines electric double-layer capacitance behavior in a lithium-ion capacitor and anion intercalation/de-intercalation behavior in a dual-ion batteries. Two mechanisms were observed in the electrochemical characterization process, and the performance of the porous graphitic carbon was compared to porous carbon and artificial graphite, which indicate that its energy storage performance is significantly better due to the additional plateau capacity contributed by anion intercalation at a high potential and the improved conductivity through the local graphitic regions.
- Dual-ion hybrid capacitor,
- Porous graphitic carbon,
- Lithium-ion battery,
- Dual-ion battery,
- Citrate

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References(25)

References

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