GUO Meng-qing, HUANG Jia-qi, KONG Xiang-yi, PENG Hong-jie, SHUI Han, QIAN Fang-yuan, ZHU Lin, ZHU Wan-cheng, ZHANG Qiang. Hydrothermal synthesis of porous phosphorus-doped carbon nanotubes and their use in the oxygen reduction reaction and lithium-sulfur batteries[J]. NEW CARBOM MATERIALS, 2016, 31(3): 352-362.
Citation: GUO Meng-qing, HUANG Jia-qi, KONG Xiang-yi, PENG Hong-jie, SHUI Han, QIAN Fang-yuan, ZHU Lin, ZHU Wan-cheng, ZHANG Qiang. Hydrothermal synthesis of porous phosphorus-doped carbon nanotubes and their use in the oxygen reduction reaction and lithium-sulfur batteries[J]. NEW CARBOM MATERIALS, 2016, 31(3): 352-362.

Hydrothermal synthesis of porous phosphorus-doped carbon nanotubes and their use in the oxygen reduction reaction and lithium-sulfur batteries

Funds:  National Natural Scientific Foundation of China (21306103, 21422604);National Basic Research Program of China (2015CB932500).
  • Received Date: 2016-05-10
  • Accepted Date: 2016-06-28
  • Rev Recd Date: 2016-06-09
  • Publish Date: 2016-06-28
  • The many uses of carbon nanotubes (CNTs) depend not only on their intrinsic physical properties, but also on their tunable chemical components. Exploring a low-temperature method for the incorporation of phosphorus atoms in the carbon framework is expected to change the chemical properties of CNTs. Here, phosphorus-functionalized CNTs (PCNTs) were prepared by the direct hydrothermal treatment of a CNT-H3PO4 mixture at 170℃. The PCNTs had a high phosphorus content of 1.66 at%, a specific surface area of 132 m2·g-1, and an improved thermal stability with a weight loss peak at 694℃ during oxidation in pure oxygen. They showed good electrocatalytic activity for the oxygen reduction reaction with an onset potential of 0.20 V vs Hg/Hg2Cl2, an electron transfer number of 2.60, and a larger current density as well as improved cyclic stability compared with pristine CNTs. PCNTs were also used as conductive scaffolds for the cathode in lithium-sulfur batteries. The cathode delivered an initial discharge capacity of 1 106 mAh·g-1, a capacity retention of 80% from 0.1 to 1.0 C, and a low decay rate of 0.25% per cycle during 100 cycles.
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