氮掺杂稻壳基多孔炭的制备及其氧气还原反应的电催化性能

时军; 林楠; 林海波; 杨瑾; 张文礼

doi:10.1016/S1872-5805(20)60497-8

氮掺杂稻壳基多孔炭的制备及其氧气还原反应的电催化性能

doi: 10.1016/S1872-5805(20)60497-8

时军¹,
林楠²,
林海波^1,3,,
杨瑾¹,
张文礼⁴

1.
吉林大学无机合成与制备化学国家重点实验室, 吉林长春 130012;
2.
布伦瑞克工业大学能源与工艺系统工程学院, 德国法兰克福 38092;
3.
吉林大学珠海学院, 广东珠海 519041;
4.
阿卜杜拉国王科技大学物理科学与工程系, 沙特阿拉伯图瓦 23955-6900

基金项目: 国家重点研发计划项目（2017YFB0307500）；国家自然科学基金项目（21975101）；吉林大学科技创新团队项目（2017TD-31）；长春市"双十"重大科技专项工程（17SS018）.

详细信息

作者简介:
时军,博士研究生.E-mail:shijunhenu@163.com

通讯作者:
林海波,教授.E-mail:lhb910@jlu.edu.cn;张文礼,博士.E-mail:hiteur@163.com

中图分类号: TQ127.1⁺1
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- 被引次数: 0
出版历程
- 收稿日期: 2020-05-01
- 修回日期: 2020-07-02
- 刊出日期: 2020-08-28

A N-doped rice husk-based porous carbon as an electrocatalyst for the oxygen reduction reaction

1.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China;
2.
Institute of Energy and Process Systems Engineering, Technische Universitaet Braunschweig, Franz-Liszt-Str. 35, Braunschweig 38092, Germany;
3.
Zhuhai College of Jilin University, Zhuhai 519041, China;
4.
Materials Science and Engineering, Physical Science and Engineering Division, King Abdullah University of Science and Technology(KAUST), Thuwal 23955-6900, Saudi Arabia

Funds: National Key R&D Program of China (2017YFB0307500), National Natural Science Foundation of China (21975101), Science and Technology Innovation Team Project of Jilin University (2017TD-31), Major Science and Technology Research Project of "Shuangshi Project" in Changchun City (17SS018).

摘要

摘要: 本文发展了一种氮掺杂稻壳基多孔炭（N-RHPC）的制备方法，即将RHPC在氨气氛围下进行高温处理，操作简单，有利于大规模制备。结果表明，N-RHPC的介孔体积、石墨化程度明显提高，XPS N 1s谱证实了N原子在RHPC结构上的有效掺杂。N-RHPC作为ORR电催化剂具有与商用Pt/C接近的电催化活性，并具有较好的稳定性以及耐甲醇毒性，这主要是由于氨气氛围下对RHPC的高温处理使N原子进入RHPC中而引入了大量的催化位点所致。N-RHPC制备方法简单，性价比高，作为电催化剂具有很好的应用前景。
- 稻壳基多孔炭 /
- 氧气还原反应 /
- 氮掺杂稻壳基多孔炭 /
- 电催化剂
Abstract: A N-doped rice husk-based porous carbon (N-RHPC) was cost-effectively prepared by simply treating RHPC at high temperature in an ammonia atmosphere. Results show that the mesopore volume and degree of graphitization of N-RHPC are significantly increased by the treatment. N atoms are doped in the RHPC structure in the form of pyridinic N (398.5 ±0.1 eV), pyridonic N (399.3 ±0.1 eV), and graphitic N groups (401.1 ±0.1 eV) and N-oxide (401.8 ±0.1 eV). Compared with a commercial Pt/C catalyst, the N-RHPC as an oxygen reduction electrocatalyst has a similar electrocatalytic activity, and better stability and methanol toxicity resistance. This excellent performance is ascribed to the increased number of catalytic sites afforded by the nitrogen species, the improved degree of graphitization that increases electron transfer, and the unique pore structure with macropores, mesopores and micropores for fast ion transport.
- Rice husk-based porous carbon /
- Oxygen reduction reaction /
- N-doped porous carbon /
- Electrocatalysts

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