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摘要: 研究了商用活性炭作为电极的双电层电容器在水系和有机系电解液中的电容和活性炭孔结构的关系。水系电解液采用1mol/L的H2SO4溶液、有机系电解液采用1mol/L 的TEMA/PC溶液。结果表明:水系和有机系电解液中的电容存在线性关系。电容由活性炭微孔表面和其他大孔构成的表面两部分提供(分别称为Cmicro.和Cext.)。其中Cmicro.较小并对电流有依赖性、而Cext.近似为一个常数、不随电流改変。Abstract: The dependence of electric double layer capacitance on the pore structure of commercially available activated carbons in both nonaqueous and aqueous electrolytes was studied. Capacitance in the nonaqueous electrolyte (propylene carbonate solution of 1mol/L triethylmethylammonium tetrafluoroborate) was linearly related to that in the aqueous electrolyte (1mol/L H2SO4 solution). The contributions of the microporous surface area, Cmicro., and the surface formed on account of other large pores, Cext., were separately evaluated, the former being small and depending strongly on current density and the latter being almost constant.
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Key words:
- Capacitance /
- Nonaqueous electrolyte /
- Aqueous electrolyte /
- Pore surface areas
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