泡沫炭的成核机理及其复合增强机制

霍云霞; 何自国; 詹亮; 刘想; 王艳莉

泡沫炭的成核机理及其复合增强机制

华东理工大学, 化学工程联合国家重点实验室, 特殊功能高分子材料及其相关技术教育部重点实验室, 上海 200237

基金项目: 国家自然科学基金(51472086, 51002051); 上海市自然科学基金(12ZR1407200).

详细信息

作者简介:
霍云霞,硕士研究生.E-mail:huoyunxiagogo@163.com

通讯作者:
詹亮,教授.E-mail:zhanliang@ecust.edu.cn

中图分类号: TQ127.1⁺1
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- 文章访问数: 860
- HTML全文浏览量: 219
- PDF下载量: 535
- 被引次数: 0
出版历程
- 收稿日期: 2015-04-20
- 录用日期: 2015-09-07
- 修回日期: 2015-07-22
- 刊出日期: 2015-08-28

Preparation of reinforced carbon foams with different fillers

State Key Laboratory of Chemical Engineering, Key Laboratory for Specially Functional Polymers and Related Technology of Ministry of Education, East China University of Science and Technology, Shanghai 200237, China

Funds: Natural National Science Foundation of China (51472086, 51002051); Natural Science Foundation of Shanghai City (12ER 1407200).

摘要

摘要: 以中间相炭微球(MCMB)、聚丙烯腈基炭纤维(PAN-CF)和纳米氧化锆(ZrO₂)为增强体,采用自发泡法制备出泡沫炭复合材料,并研究不同增强材料对中间相沥青基泡沫炭的发泡行为和压缩强度的影响。结果表明,中间相沥青在发泡过程中遵循热点成核机制;较PAN-CF、MCMB而言,ZrO₂纳米颗粒(~100 nm)对泡沫炭具有更佳的增强效果。当在中间相沥青原料中添加30%的纳米ZrO₂后,泡沫炭的压缩强度可由7.57 MPa提高到31.4 MPa。
- 泡沫炭 /
- 复合增强 /
- 中间相炭微球 /
- 纳米氧化锆 /
- 炭纤维
Abstract: Carbon foam composites were prepared by a self-foaming method from mesophase pitch using mesocarbon microbeads (MCMBs), PAN based carbon fibers (PAN-CFs) and ZrO₂ nanoparticles were used as the fillers for reinforcement. The effects of the fillers on the foaming behavior and the compressive strength were investigated. Results show that ZrO₂ nanoparticles produce a larger increase in the compressive strength of the carbon foam than do MCMBs and PAN-CFs. The compressive strength of the carbon foam increases from 7.57 to 31.4 MPa when 30% of the ZrO₂ nanoparticles is added to the mesophase pitch. The foam formation obeys the hot-point nucleation mechanism, in which gaseous products released from light hydrocarbons are heated to generate nuclei by localized condensation reaction heat.
- Carbon foam /
- Composite enhancement /
- Mesocarbon microbeads /
- ZrO₂ /
- Carbon fibers

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