二维纳米材料的自上而下制备:可控液相剥离

邵姣婧; 郑德一; 李政杰; 杨全红

二维纳米材料的自上而下制备:可控液相剥离

1.
贵州大学材料与冶金学院, 贵州贵阳 550025;
2.
天津大学化工学院, 天津 300072

基金项目: 国家自然科学基金(51502046,21564002);贵州省科学技术基金(黔科合JZ字[2015]2004号);贵州省科技计划项目(黔科合LH字[2014]7602);贵州省留学人员科技创新项目(黔人项目资助合同[2015]11号);贵州大学引进人才科研项目(贵大人基合字[2014]45号).

详细信息

通讯作者:
邵姣婧,博士,教授.E-mail:shaojiao_jing@163.com

中图分类号: TQ127.1⁺1
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- 被引次数: 0
出版历程
- 收稿日期: 2016-02-25
- 录用日期: 2016-04-21
- 修回日期: 2016-03-28
- 刊出日期: 2016-04-28

Top-down fabrication of two-dimensional nanomaterials:Controllable liquid phase exfoliation

1.
School of Materials and Metallurgy, Guizhou University, Guiyang 550025, China;
2.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

Funds: National Natural Science Foundation of China(51502046, 21564002); Natural Science Foundation of Guizhou Province(JZ[2015]2004); Joint Capital Project of Science and Technology Department of Guizhou Province(LH[2014]7602); Science and Technology Innovation Project for Selected Overseas Chinese Scholar at Guizhou Province([2015]11); Talent Introduction and Scientific Research Project of Guizhou University, China([2014]45).

摘要

摘要: 二维纳米材料独特的结构特征赋予了其众多的优异性质,充分利用这些特性有利于实现新材料的制备和新产品的开发,而二维纳米材料的规模化可控制备是实现其广泛应用的必要前提。在众多制备二维纳米材料的各类方法中,基于层状前驱体的液相剥离法以其较高的效率和良好的操控性等优点受到了广泛关注。本文详细阐述了二维纳米材料的优异特性及其潜在应用,并以目前研究最为广泛的几种二维纳米材料为例,重点介绍了几种常见的基于三维层状晶体的液相剥离以制备二维纳米材料的方法,最后对各种液相剥离法的适用性进行总结,并对二维纳米材料的发展前景进行展望。
- 二维纳米材料 /
- 层状晶体 /
- 自上而下制备法 /
- 液相剥离 /
- 自组装
Abstract: Two-dimensional nanomaterials have unique structural characteristics and various extraordinary properties, which make them attractive for use in the preparation of advanced materials and new products. Large-scale fabrication of these nanomaterials in a controllable way is key for the realization of their applications. Liquid phase exfoliation has been given a great deal of attention in making two-dimensional nanomaterials owing to its high efficiency and excellent controllability. This review elaborates on the superior characteristics and potential applications of two-dimensional nanomaterials while focusing on liquid phase exfoliation methods, including ion-exchange, intercalation-exfoliation, oxidation-reduction, selective etching, direct sonication and shear exfoliation methods. The mechanisms and applicability of these methods are compared and the development prospects of two-dimensional nanomaterials are discussed.
- Two-dimensional nanomaterials /
- Layered crystals /
- Top-down fabrication /
- Liquid phase exfoliation /
- Self-assembly

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