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功能化纳米碳管对水溶液中Pb2+吸附的动力学、平衡与等温线

Hamzeh Eyni,  Hasan Tahermansouri,  Farhoush Kiani,  Mansour Jahangiri

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文章导航 > 新型炭材料  > 2019 >  34(6): 512-523
Hamzeh Eyni, Hasan Tahermansouri, Farhoush Kiani, Mansour Jahangiri. 功能化纳米碳管对水溶液中Pb2+吸附的动力学、平衡与等温线. 新型炭材料, 2019, 34(6): 512-523. doi: 10.1016/S1872-5805(19)60027-2
引用本文: Hamzeh Eyni, Hasan Tahermansouri, Farhoush Kiani, Mansour Jahangiri. 功能化纳米碳管对水溶液中Pb2+吸附的动力学、平衡与等温线. 新型炭材料, 2019, 34(6): 512-523. doi: 10.1016/S1872-5805(19)60027-2
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Hamzeh Eyni, Hasan Tahermansouri, Farhoush Kiani, Mansour Jahangiri. Kinetics, equilibrium and isotherms of Pb2+ adsorption from aqueous solutions on carbon nanotubes functionalized with 3-amino-5a,10a-dihydroxybenzo indeno furan-10-one. New Carbon Mater., 2019, 34(6): 512-523. doi: 10.1016/S1872-5805(19)60027-2
Citation: Hamzeh Eyni, Hasan Tahermansouri, Farhoush Kiani, Mansour Jahangiri. Kinetics, equilibrium and isotherms of Pb2+ adsorption from aqueous solutions on carbon nanotubes functionalized with 3-amino-5a,10a-dihydroxybenzo indeno furan-10-one. New Carbon Mater., 2019, 34(6): 512-523. doi: 10.1016/S1872-5805(19)60027-2
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功能化纳米碳管对水溶液中Pb2+吸附的动力学、平衡与等温线

doi: 10.1016/S1872-5805(19)60027-2
  • 1.

    Faculty of Nanotechnology, Semnan University, Semnan, Iran;

  • 2.

    Department of Chemistry, Ayatollah Amoli Branch, Islamic Azad University, Amol, Iran;

  • 3.

    Faculty of Chemical & Petroleum and Gas Engineering, Semnan University, Semnan, Iran

详细信息
    通讯作者:

    Hasan Tahermansouri,Ph.D,Associate Professor.E-mail:h.tahermansuri@iauamol.ac.ir,tahermansuri@yahoo.com

  • 中图分类号: TQ127.1+1

Kinetics, equilibrium and isotherms of Pb2+ adsorption from aqueous solutions on carbon nanotubes functionalized with 3-amino-5a,10a-dihydroxybenzo indeno furan-10-one

  • 1.

    Faculty of Nanotechnology, Semnan University, Semnan, Iran;

  • 2.

    Department of Chemistry, Ayatollah Amoli Branch, Islamic Azad University, Amol, Iran;

  • 3.

    Faculty of Chemical & Petroleum and Gas Engineering, Semnan University, Semnan, Iran

More Information
    Corresponding author: Hasan Tahermansouri,Ph.D,Associate Professor.E-mail:h.tahermansuri@iauamol.ac.ir,tahermansuri@yahoo.com

    摘要
  • 摘要: 以3-Amino-5a，10a-dihydroxybenzo indeno furan-10-one（ADIF）功能化改性的纳米碳管（MWCNT-ADIF）为吸附剂，除去水溶液中的Pb2+。采用FT-IR，SEM，TGA及DTG对MWCNT-ADIF样品进行表征。探讨了pH值、Pb2+初始浓度、吸附量和接触时间对吸附动力学与平衡的影响。采用4种二参数模型（Langmuir、Freundlich、Tempkin与Dubinin-Radushkevich）和6种三参数模型（Redlich-Peterson，Khan，Sips，Radke-Prausnitz，Toth，Hil）研究Pb2+吸附等温线。通过伪一阶动力学模型、伪二阶动力学模型和粒子内扩散模型分析吸附动力学。采用3种误差分析方法、相关系数、卡方值和平均相对误差来确定最佳拟合等温线和动力学模型。结果表明，吸附动力学与伪二阶动力学模型相吻合。误差分析表明，三参数模型比二参数模型更适合描述Pb2+吸附数据。等温线数据与Langmuir、Hill和Sips models相符。MWCNT-ADIF在pH=3溶液中能脱除92%的Pb2+，并且回收后的MWCNT-ADIF能重复使用5个再生周期。
    Abstract: Multi-wall carbon nanotubes functionalized with 3-Amino-5a, 10a-dihydroxybenzo indeno furan-10-one (ADIF), (MWCNT-ADIF), were used as the adsorbent to remove lead ions (Pb2+) from aqueous solutions. The samples were characterized by FT-IR, SEM, TGA and DTG. Effects of pH, initial Pb2+ concentration, adsorbent dosage and contact time on adsorption kinetics and equilibrium were investigated in a batch mode. Adsorption isotherms of Pb2+ ions were investigated using four two-parameter models (Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich) and six three-parameter models (Redlich-Peterson, Khan, Sips, Radke-Prausnitz, Toth, Hill). Adsorption kinetics were investigated by the pseudo first-order kinetic model, the pseudo second-order kinetic model and the intra-particle diffusion model. Three error analysis methods, correlation coefficient, chi-square test and average relative errors, were used to determine the best fitted isotherm. Results indicated that adsorption kinetics was best described by the pseudo second-order kinetic model. Error analysis indicated that three-parameter models described the Pb2+ sorption data better than the two-parameter models. The isotherm data were best fitted by the Langmuir, Hill and Sips models. Pb2+ ions could be desorbed from MWCNT-ADIF up to 92% at pH=3 and the recycled MWCNT-ADIF could be reused for 5 regeneration cycles.
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  • 收稿日期:  2019-08-02
  • 录用日期:  2020-01-03
  • 修回日期:  2019-11-30
  • 刊出日期:  2019-12-28

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