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基于电化学阳极氧化的多壁碳纳米管表面改性

张巍松 刘玉婷 吴刚平

张巍松, 刘玉婷, 吴刚平. 基于电化学阳极氧化的多壁碳纳米管表面改性. 新型炭材料, 2020, 35(2): 155-164. doi: 10.1016/S1872-5805(20)60481-4
引用本文: 张巍松, 刘玉婷, 吴刚平. 基于电化学阳极氧化的多壁碳纳米管表面改性. 新型炭材料, 2020, 35(2): 155-164. doi: 10.1016/S1872-5805(20)60481-4
ZHANG Wei-song, LIU Yu-ting, WU Gang-ping. Surface modification of multiwall carbon nanotubes by electrochemical anodic oxidation. New Carbon Mater., 2020, 35(2): 155-164. doi: 10.1016/S1872-5805(20)60481-4
Citation: ZHANG Wei-song, LIU Yu-ting, WU Gang-ping. Surface modification of multiwall carbon nanotubes by electrochemical anodic oxidation. New Carbon Mater., 2020, 35(2): 155-164. doi: 10.1016/S1872-5805(20)60481-4

基于电化学阳极氧化的多壁碳纳米管表面改性

doi: 10.1016/S1872-5805(20)60481-4
基金项目: 国家自然科学基金委员会-中国石油天然气集团有限公司石油化工联合基金(U1362107);国家自然科学基金委-山西煤基低碳联合基金(U1810116);山西省科技重大专项项目(20181101020).
详细信息
    作者简介:

    张巍松,硕士研究生.E-mail:zhangweisong@sxicc.ac.cn

    通讯作者:

    吴刚平,博士,研究员.E-mail:wgp@sxicc.ac.cn

  • 中图分类号: TQ127.1+1

Surface modification of multiwall carbon nanotubes by electrochemical anodic oxidation

Funds: National Natural Science Foundation of China & China National Petroleum Corporation Joint Fund(U1362107); National Natural Science Foundation of China-Shanxi Coal-based Low Carbon Joint Fund (U1810116); Major science and technology projects of Shanxi Provence (20181101020).
  • 摘要: 分别以硫酸和氢氧化钠溶液为电解液,用阳极氧化方法对多壁碳纳米管进行表面改性处理。采用了扫描电子显微镜,透射电子显微镜,Zeta电位仪,红外光谱仪,X-射线光电子能谱仪和拉曼光谱仪等表征手段对多壁碳纳米管的形貌、分散性、功能化程度及缺陷程度等方面进行了表征。多壁碳纳米管经阳极氧化后,表面含氧官能团数量增加,这提高了其在水溶液中的分散性。但是在不同的电解液中阳极氧化后,纳米管的分散性、官能团种类和表面缺陷情况不同。在氢氧化钠溶液中阳极氧化会在纳米管表面引入更多含氧官能团,而在硫酸溶液中阳极氧化会在纳米管表面引入更多缺陷。
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出版历程
  • 收稿日期:  2020-01-27
  • 录用日期:  2020-04-28
  • 修回日期:  2020-03-10
  • 刊出日期:  2020-04-28

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