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亚微米级单分散的密胺树脂微球及其氮掺杂炭微球的制备

马灿良 王再然 胡振慧 王艺华 赵云 师晶

马灿良, 王再然, 胡振慧, 王艺华, 赵云, 师晶. 亚微米级单分散的密胺树脂微球及其氮掺杂炭微球的制备. 新型炭材料, 2020, 35(3): 269-285. doi: 10.1016/S1872-5805(20)60489-9
引用本文: 马灿良, 王再然, 胡振慧, 王艺华, 赵云, 师晶. 亚微米级单分散的密胺树脂微球及其氮掺杂炭微球的制备. 新型炭材料, 2020, 35(3): 269-285. doi: 10.1016/S1872-5805(20)60489-9
MA Can-liang, WANG Zai-ran, HU Zhen-hui, WANG Yi-hua, ZHAO Yun, SHI Jing. Preparation of submicron monodisperse melamine resin microspheres and nitrogen-doped carbon microspheres derived from them. New Carbon Mater., 2020, 35(3): 269-285. doi: 10.1016/S1872-5805(20)60489-9
Citation: MA Can-liang, WANG Zai-ran, HU Zhen-hui, WANG Yi-hua, ZHAO Yun, SHI Jing. Preparation of submicron monodisperse melamine resin microspheres and nitrogen-doped carbon microspheres derived from them. New Carbon Mater., 2020, 35(3): 269-285. doi: 10.1016/S1872-5805(20)60489-9

亚微米级单分散的密胺树脂微球及其氮掺杂炭微球的制备

doi: 10.1016/S1872-5805(20)60489-9
基金项目: 国家自然科学基金(U1510134,51702191);山西省科技厅2019面上自然基金项目(201901D111037);山西省教育厅2019科技创新项目(2019L0012);山西省"1331工程"重点创新研究团队支持.
详细信息
    通讯作者:

    马灿良,博士,副教授.E-mail:macanliang008@163.com

  • 中图分类号: TQ127.1+1

Preparation of submicron monodisperse melamine resin microspheres and nitrogen-doped carbon microspheres derived from them

Funds: National Scientific Research Funding of China (U1510134, 51702191), Natural Science Foundation of Shanxi Province (201901D111037), Science and Technology Innovation Planning Project in Universities and Colleges of Shanxi Province of China (2019L0012), and the Shanxi "1331 Project" Key Innovative Research Team.
  • 摘要: 亚微米单分散三聚氰胺树脂微球和氮掺杂碳微球的可控制备仍是当今材料领域的一个重要课题。在不添加任何表面活性剂的情况下,仅使用适量的乙酸作为催化剂制备了最小粒径为200纳米的单分散MF微球,这比已报道的强酸制备的MF微球都要小。此外,随着搅拌时间的增加(0~48 h),MF微球的D50并不是简单地增加然后保持稳定,而是进一步下降,再次稳定,最后稳定后的粒径相比最大粒径发生明显收缩,收缩率约40%。在适当的热处理条件下,尤其是将物料均匀地薄薄地铺开,可以得到相应的单分散氮掺杂碳微球,其在800℃下的收缩率为81%~65%,收缩率与搅拌时间有关。最后,从分子形成的角度讨论了MF树脂微球和氮掺杂碳微球形成过程中的上述现象和规律。
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出版历程
  • 收稿日期:  2020-03-20
  • 修回日期:  2020-05-10
  • 刊出日期:  2020-06-28

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