LI Fang-Fei, Lv Wei, NIU Shu-Zhang, LI Bao-Hua. Preparation and electrochemical performance of a graphene-wrapped carbon / sulphur composite cathode. New Carbon Mater., 2014, 29(4): 309-315. doi: 10.1016/S1872-5805(14)60140-2
Citation:
LI Fang-Fei, Lv Wei, NIU Shu-Zhang, LI Bao-Hua. Preparation and electrochemical performance of a graphene-wrapped carbon / sulphur composite cathode. New Carbon Mater., 2014, 29(4): 309-315. doi: 10.1016/S1872-5805(14)60140-2
LI Fang-Fei, Lv Wei, NIU Shu-Zhang, LI Bao-Hua. Preparation and electrochemical performance of a graphene-wrapped carbon / sulphur composite cathode. New Carbon Mater., 2014, 29(4): 309-315. doi: 10.1016/S1872-5805(14)60140-2
Citation:
LI Fang-Fei, Lv Wei, NIU Shu-Zhang, LI Bao-Hua. Preparation and electrochemical performance of a graphene-wrapped carbon / sulphur composite cathode. New Carbon Mater., 2014, 29(4): 309-315. doi: 10.1016/S1872-5805(14)60140-2
Engineering Laboratory for Next Generation Power and Energy Storage Batteries, Engineering Laboratory for Functionalized Carbon Materials, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China|
Funds:
National Key Basic Research Program of China (2014CB932400);National Natural Science Foundation of China ( 51202121, 51232005 ); NSAF ( U1330123 ); Shenzhen Technical Plan Project ( JC201005310705A, JCYJ20120619152808478, JCYJ20130402145002382); Guangdong Province Innovation R&D Team Plan for En鄄 ergy and Environmental Materials (2009010025).
Graphene is used as a barrier film to suppress the “shuttle effect ”and to improve the performance of activated carbon-sulphur hybrid cathode materials in a lithium-sulphur battery by forming a core-shell structure. Graphene wraps around the activated carbon-sulphur hybrid to form a core-shell structure, in which the porous carbon framework stores most of the sulphur and the graphene layer suppresses the movement of the soluble polysulfide in the electrolyte during charge-discharge, resulting in an improvement of capacity and cyclic stability during long-term cycling. Such a core-shell structure is formed by changing the hydrophilicity of graphene oxide during reduction, in which the hydrophobic graphene closely wraps around the hydrophobic carbon surface.