Fluorinated graphene as a cathode material for high performance primary lithium ion batteries

XU Yao; ZHAN Liang; WANG Yun; WANG Yan-li; SHI Yun-hai

doi:10.1016/S1872-5805(15)60177-9

Volume 30 Issue 1

Turn off MathJax

Article Contents

Article Navigation > New Carbon Mater. > 2015 > 30(1): 79-85

XU Yao, ZHAN Liang, WANG Yun, WANG Yan-li, SHI Yun-hai. Fluorinated graphene as a cathode material for high performance primary lithium ion batteries. New Carbon Mater., 2015, 30(1): 79-85. doi: 10.1016/S1872-5805(15)60177-9

Citation:

XU Yao, ZHAN Liang, WANG Yun, WANG Yan-li, SHI Yun-hai. Fluorinated graphene as a cathode material for high performance primary lithium ion batteries. New Carbon Mater., 2015, 30(1): 79-85. doi: 10.1016/S1872-5805(15)60177-9

Citation:

PDF( 2637 KB)

Fluorinated graphene as a cathode material for high performance primary lithium ion batteries

doi: 10.1016/S1872-5805(15)60177-9

State Key Laboratory of Chemical Engineering, Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), East China University of Science and Technology, Shanghai 200237, China

Funds: National Science Foundation of China (51472086,51002051); Natural Science Foundation of Shanghai City (12ZR1407200).

Received Date: 2014-07-13
Accepted Date: 2015-02-13
Rev Recd Date: 2015-01-17
Publish Date: 2015-02-28

Abstract

Abstract

A free-standing fluorinated graphene (F-graphene) was fabricated by the simple liquid exfoliation of a fluorinated graphite (F-graphite) in a 2-propanol/water mixture, and was used as the cathode material of primary lithium ion batteries. As-prepared F-grapheneh as a very high fluorine content (49.7 at%), and an amorphous-like two-dimensional nanostructure. These features facilitate the rapid diffusion of lithium ions during discharging. The F-graphene exhibits better electrochemical performance, especially, a higher specific power density than the F-graphite.
- Fluorinated graphene nanosheets,
- Two-dimensional nanostructure,
- Fluorinated graphite,
- Pprimary lithium batteries

FullText(HTML)

References(21)

References

Yoshio M, Wang H Y, Fukuda K J. Spherical carbon-coated natural graphite as a lithium-ion battery-anode material
[J]. Angewandte Chemie, 2003, 115(35): 4335-4338.

Sahin H, Topsakal M, Ciraci S. Structures of fluorinated graphene and their signatures
[J]. Physical Review B, 2011, 83(11): 115432-115440.

Robinson J T, Burgess J S, Junkermeier C E, et al. Properties of fluorinated graphene films
[J]. Nano Letters, 2010, 10(8): 3001-3005.

Rüdorff W, Rüdorff G. Zur Konstitution des kohlenstoff-monofluorids
[J]. Zeitschrift Für Anorganische Chemie, 1947, 253(5-6): 281-296.

Krawietz T R, Haw J F. Characterization of poly (carbon monofluoride) by 19F and 19F to 13C cross polarization MAS NMR spectroscopy
[J]. Chemical Communications, 1998, 19: 2151-2152.

Hamwi A. Fluorine reactivity with graphite and fullerenes. Fluoride derivatives and some practical electrochemical applications
[J]. Journal of Physics and Chemistry of Solids, 1996, 57(6): 677-688.

Hany P, Yazami R, Hamwi A. Low-temperature carbon fluoride for high power density lithium primary batteries
[J]. Journal of Power Sources, 1997, 68(2): 708-710.

Delabarre C, Dubois M, Giraudet J, et al. Comparative electrochemical study of low temperature fluorinated graphites used as cathode in primary lithium batteries
[J]. ECS Transactions, 2007, 3(36): 153-163.

Guérin K, Pinheiro J P, Dubois M, et al. Synthesis and characterization of highly fluorinated graphite containing sp² and sp³ carbon
[J]. Chemistry of Materials, 2004, 16(9): 1786-1792.

Giraudet J, Delabarre C, Guérin K, et al. Comparative performances for primary lithium batteries of some covalent and semi-covalent graphite fluorides
[J]. Journal of Power Sources, 2006, 158(2): 1365-1372.

Yazami R, Hamwi A, Guérin K, et al. Fluorinated carbon nanofibres for high energy and high power densities primary lithium batteries
[J]. Electrochemistry Communications, 2007, 9(7): 1850-1855.

Ueta A, Tanimura Y, Prezhdo O V. Infrared spectral signatures of surface-fluorinated graphene: A molecular dynamics study
[J]. The Journal of Physical Chemistry Letters, 2012, 3(2): 246-250.

Yazami R, Ozawa Y, Miao S, et al. The kinetics of sub-fluorinated carbon fluoride cathodes for lithium batteries
[J]. ECS Transactions, 2007, 3(36): 199-211.

Yazami R, Hamwi A, Guérin K, et al. Fluorinated carbon nanofibres for high energy and high power densities primary lithium batteries
[J]. Electrochemistry Communications, 2007, 9(7): 1850-1855.

Coleman J N, Lotya M, O'Neill A, et al. Two-dimensional nanosheets produced by liquid exfoliation of layered materials
[J]. Science, 2011, 331(6017): 568-571.

Zhan L, Yang S, Wang Y, et al. Fabrication of fully fluorinated graphene nanosheets towards high-performance lithium storage
[J]. Advanced Materials Interfaces, 2014. DOI: 10.1002/admi.201300149.

Zhang Q, D'Astorg S, Xiao P, et al. Carbon-coated fluorinated graphite for high energy and high power densities primary lithium batteries
[J]. Journal of Power Sources, 2010, 195(9): 2914-2917.

Nakajima T, Gupta V, Ohzawa Y, et al. Electrochemical behavior of plasma-fluorinated graphite for lithium ion batteries
[J]. Journal of Power Sources, 2002, 104(1): 108-114.

Groult H, Nakajima T, Perrigaud L, et al. Surface-fluorinated graphite anode materials for Li-ion batteries
[J]. Journal of Fluorine Chemistry, 2005, 126(7): 1111-1116.

Dubois M, Guérin K, Zhang W, et al. Tuning the discharge potential of fluorinated carbon used as electrode in primary lithium battery
[J]. Electrochimica Acta, 2012, 59: 485-491.

Delabarre C, Dubois M, Giraudet J, et al. Electrochemical performance of low temperature fluorinated graphites used as cathode in primary lithium batteries
[J]. Carbon, 2006, 44(12): 2543-2548.

Relative Articles

Supplements(0)

Cited By

Proportional views