WU Ming-bo, LI Ru-chun, HE Xiao-jun, ZHANG He-bao, SUI Wu-bin, TAN Ming-hui. Microwave-assisted preparation of peanut shell-based activated carbons and their use in electrochemical capacitors. New Carbon Mater., 2015, 30(1): 86-91. doi: 10.1016/S1872-5805(15)60178-0
Citation: WU Ming-bo, LI Ru-chun, HE Xiao-jun, ZHANG He-bao, SUI Wu-bin, TAN Ming-hui. Microwave-assisted preparation of peanut shell-based activated carbons and their use in electrochemical capacitors. New Carbon Mater., 2015, 30(1): 86-91. doi: 10.1016/S1872-5805(15)60178-0

Microwave-assisted preparation of peanut shell-based activated carbons and their use in electrochemical capacitors

doi: 10.1016/S1872-5805(15)60178-0
Funds:  Program for New Century Excellent Talents in U., China Ministry of Edn. (NCET-10-0768, NCET-13-0643); National Natural Science Foundation of China (U1361110, 51172285, 51372277).
  • Received Date: 2014-06-25
  • Accepted Date: 2015-02-13
  • Rev Recd Date: 2015-01-20
  • Publish Date: 2015-02-28
  • Activated carbons (ACs) were prepared from peanut shells by KOH activation under microwave heating and were used as electrode materials for electrochemical capacitors (ECs). The pore structure of the ACs was characterized by nitrogen adsorption andthe electrochemical performance by galvanostatic charge-discharge and cyclic voltammetry. Results show that the ACs' specific surface area, total pore volume, specific capacitance, as well as energy density are maximized using anactivation time from 6 to 10 min or KOH/peanut shell mass ratio from 0.6 to 2.0 under otherwise identical conditions. When the KOH/peanut shell mass ratio was 1.0, microwave power was 600 W and activation time was 8 min, the specific surface area of the resulting AC was 1 277 m2/g and its energy density was 8.38 Wh/kg after 1 000 cycles. The KOH activation of peanut shells with microwave heating is an efficient approach for the rapid preparation of low cost ACs for ECs.
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  • KANG Fei-yu , HE Yan-bing, LI Bao-hua , et al. Carbon for energy storage and conversion
    [J]. New Carbon Materials, 2011, 26(4): 246-254. (康飞宇, 贺艳兵, 李宝华, 等. 炭材料在能量储存与转化中的应用
    [J]. 新型炭材料, 2011, 26(4): 246-254.)
    Wilson K, Yang H, Seo C W, et al. Select metal adsorption by activated carbon made from peanut shells
    [J]. Bioresource Technology, 2006, 97(18): 2266-2270.
    Nabais J V, Carrott P, Ribeiro Carrott M M L, et al. Influence of preparation conditions in the textural and chemical properties of activated carbons from a novel biomass precursor: The coffee endocarp
    [J]. Bioresource Technology, 2008, 99(15): 7224-7231.
    He X J, Li R C, Qiu J S, et al. Synthesis of mesoporous carbons for supercapacitors from coal tar pitch by coupling microwave-assisted KOH activation with a MgO template
    [J]. Carbon, 2012, 50(13): 4911-4921.
    Zhang F, Ma H, Chen J, et al. Preparation and gas storage of high surface area microporous carbon derived from biomass source cornstalks
    [J]. Bioresource Technology, 2008, 99(11): 4803-4808.
    Wu M B, Zha Q F, Qiu J S, et al. Preparation and characterization of porous carbons from PAN-based preoxidized cloth by KOH activation
    [J]. Carbon, 2004, 42(1): 205-210.
    Li X, Xing W, Zhuo S P, et al. Preparation of capacitor's electrode from sunflower seed shell
    [J]. Bioresource Technology, 2011, 102(2): 1118-1123.
    He X J, Long S A, Zheng M D, et al. Optimization of activated carbon preparation by orthogonal Experimental design for electrochemical capacitors
    [J]. Science of Advanced Materials, 2010, 2(4): 545-551.
    Yuen F K and Hameed B H. Recent developments in the preparation and regeneration of activated carbons by microwaves
    [J]. Advances in Colloid and Interface Science, 2009, 149(1-2): 19-27.
    Ania C O, Parra J B, Menéndez J A, et al. Effect of microwave and conventional regeneration on the microporous and mesoporous network and on the adsorptive capacity of activated carbons
    [J]. Microporous and Mesoporous Materials, 2005, 85(1-2): 7-15.
    Ji Y B, Li T H, Zhu L, et al. Preparation of activated carbons by microwave heating KOH activation
    [J]. Applied Surface Science, 2007, 254(2): 506-512.
    Li W, Zhang L B, Peng J H, et al. Preparation of high surface area activated carbons from tobacco stems with K2CO3 activation using microwave radiation
    [J]. Industrial Crops and Products, 2008, 27(3): 341-347.
    Yagmur E, Ozmak M, Aktas Z. A novel method for production of activated carbon from waste tea by chemical activation with microwave energy
    [J]. Fuel, 2008, 87(15-16): 3278-3285.
    He X J, Geng Y J, Qiu J S, et al. Influence of KOH/Coke mass ratio on properties of activated carbons made by microwave-assisted activation for electric double-layer capacitors
    [J]. Energy & Fuels, 2010, 24(6): 3603-3609.
    Liu Q S, Zheng T, Wang P, et al. Preparation and characterization of activated carbon from bamboo by microwave-induced phosphoric acid activation
    [J]. Industrial Crops and Products, 2010, 31(2): 233-238.
    Valente Nabais J M, Teixeira J G, Almeida I. Development of easy made low cost bindless monolithic electrodes from biomass with controlled properties to be used as electrochemical capacitors
    [J]. Bioresource Technology, 2011, 102(3): 2781-2787.
    Yang K B, Peng J H, Srinivasakannan C, et al. Preparation of high surface area activated carbon from coconut shells using microwave heating
    [J]. Bioresource Technology, 2010, 101(15): 6163-6169.
    Ismanto A E, Wang S, Soetaredjo F E, et al. Preparation of capacitor's electrode from cassava peel waste
    [J]. Bioresource Technology, 2010, 101(10): 3534-3540.
    Chmiola J, Yushin G, Gogotsi Y, et al. Anomalous increase in carbon capacitance at pore sizes less than 1 nanometer
    [J]. Science, 2006, 313(5794): 1760-1763.
    Lee S G, Park K H, Shim W G, et al. Performance of electrochemical double layer capacitors using highly porous activated carbons prepared from beer lees
    [J]. Journal of Industrial and Engineering Chemistry, 2011, 17(3): 450-454.
    Ruiz V, Blanco C, Raymundo-Piero E, et al. Effects of thermal treatment of activated carbon on the electrochemical behaviour in supercapacitors
    [J]. Electrochimica Acta, 2007, 52(15): 4969-4973.
    SHANGGUAN Ju, LI Chun-hu, MIAO Mao-qian, et al. Surface characterization and SO2 removal activity of activated semi-coke with heat treatment
    [J]. New Carbon Materials, 2008, 23(1): 37-43. (上官炬, 李春虎, 苗茂谦, 等. 热处理活性半焦的表面性质和SO2脱除活性
    [J]. 新型炭材料, 2008, 23(1): 37-43.)
    ZHOU Ying, SONG Xiao-na, SHU Cheng, et al. The electrochemical properties of templated and activated mesoporous carbons produced from coal pitch
    [J]. New Carbon Materials, 2011, 26(3): 187-191. (周 颖, 宋晓娜, 舒 成, 等. 模板法煤沥青基中孔炭的制备及其电化学性能
    [J]. 新型炭材料, 2011, 26(3): 187-191.)
    Wang L L, Guo Y P, Zou B, et al. High surface area porous carbons prepared from hydrochars by phosphoric acid activation
    [J]. Bioresource Technology, 2011, 102(2): 1947-1950.
    Hall P J, Mirzaeian M, Fletcher S I, et al. Energy storage in electrochemical capacitors: designing functional materials to improve performance
    [J]. Energy & Environmental Science, 2010, 3(9): 1238-1251.
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