Synthesis of a novel CNT/polyamide composite containing phosphine oxide groups and its flame retardancy and thermal properties

Meisam Shabanian; Mohsen Hajibeygi; Mehdi Roohani

doi:10.1016/S1872-5805(15)60199-8

Volume 30 Issue 5

Turn off MathJax

Article Contents

Article Navigation > New Carbon Mater. > 2015 > 30(5): 397-403

Meisam Shabanian, Mohsen Hajibeygi, Mehdi Roohani. Synthesis of a novel CNT/polyamide composite containing phosphine oxide groups and its flame retardancy and thermal properties. New Carbon Mater., 2015, 30(5): 397-403. doi: 10.1016/S1872-5805(15)60199-8

Citation:

Meisam Shabanian, Mohsen Hajibeygi, Mehdi Roohani. Synthesis of a novel CNT/polyamide composite containing phosphine oxide groups and its flame retardancy and thermal properties. New Carbon Mater., 2015, 30(5): 397-403. doi: 10.1016/S1872-5805(15)60199-8

Citation:

Meisam Shabanian, Mohsen Hajibeygi, Mehdi Roohani. Synthesis of a novel CNT/polyamide composite containing phosphine oxide groups and its flame retardancy and thermal properties. New Carbon Mater., 2015, 30(5): 397-403. doi: 10.1016/S1872-5805(15)60199-8

PDF( 1506 KB)

Synthesis of a novel CNT/polyamide composite containing phosphine oxide groups and its flame retardancy and thermal properties

doi: 10.1016/S1872-5805(15)60199-8

1.
Faculty of Chemistry and Petrochemical Engineering, Standard Research Institute (SRI), Karaj P.O. Box 31745-139, Iran;
2.
Faculty of Chemistry, Kharazmi University 15719-14911 Tehran, Iran

Received Date: 2015-07-03
Accepted Date: 2015-11-10
Rev Recd Date: 2015-10-10
Publish Date: 2015-10-28

Abstract

Abstract

A novel composite based on a semi-aromatic polyamide (PA) reinforced by multiwall carbon nanotubes (CNTs) was prepared by a solution mixing method. PA was synthesized through a direct polycondensation between azelaic acid and bis (3-amino phenyl) phenyl phosphine oxide. The effect of the CNT addition on the thermal and flammability properties of the composite were studied by thermogravimetric analysis, differential scanning calorimetry and microscale combustion calorimetry. The temperature at which 5% weight loss occurs is increased by over 70℃ by incorporating CNTs into the PA matrix. CNTs improve the flame retardancy of PA, which is manifested by a decrease of the heat release rate and the total heat release of the composite compared with pure PA.
- Multiwalled carbon nanotube,
- Nanocomposite,
- Polyamide,
- Flame Retardancy.

FullText(HTML)

References(38)

References

Song W L, Wang W, L Monica Veca, et al. Polymer/carbon nanocomposites for enhanced thermal transport properties-Carbon nanotubes versus graphene sheets as nanoscale fillers[J]. Journal of Materials Chemistry, 2012, 22(33):17133-17139.

Al-Saleh M H, U Sundararaj. Microstructure, electrical, and electromagnetic interference shielding properties of carbon nanotube/acrylonitrile-butadiene-styrene nanocomposites[J]. Journal of Polymer Science, Part B:Polymer Physics, 2012, 50(19):1356-1362.

Ghasemi I, A T Farsheh, Z Masoomi. Effects of multi-walled carbon nanotube functionalization on the morphological and mechanical properties of nanocomposite foams based on poly(vinyl chloride)/(wood flour)/(multi-walled carbon nanotubes)[J]. Journal of Vinyl and Additive Technology, 2012, 18(3):161-167.

Díez-Pascual A M, Mohammed N, Carlos M, et al. High-performance nanocomposites based on polyetherketones[J]. Progress in Materials Science, 2012, 57(7):1106-1190.

Ma P C, Siddiqui Naveed A, Gad Marom, et al. Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites:A review[J]. Composites Part A:Applied Science and Manufacturing, 2010, 41(10):1345-1367.

Shabanian M, Nian-Jun Kang, De-Yi Wang, et al. Synthesis, characterization and properties of novel aliphatic-aromatic polyamide/functional carbon nanotube nanocomposites via in situ polymerization[J]. RSC Advances, 2013, 3(43):20738-20745.

Hapuarachchi T D , T Peijs. Multiwalled carbon nanotubes and sepiolite nanoclays as flame retardants for polylactide and its natural fibre reinforced composites[J]. Composites Part A:Applied Science and Manufacturing, 2010, 41(8):954-963.

Abbaszadeh S, Allec N, Karim K S. Characterization of low dark-current lateral amorphous-selenium metal-semiconductor-metal photodetector[J]. IEEE Electron Device Letters, 2011, 32(9):1263-1265.

Cassidy P E. Thermally stable polymers:syntheses and properties[M]. 1980, Marcel Dekker Inc.

García J M, Félix C, García, Felipe Serna, et al. High-performance aromatic polyamides[J]. Progress in Polymer Science, 2010, 35(5):623-686.

Mallakpour S, M Kolahdoozan. Synthesis and properties of novel soluble aromatic polyamides derived from 5-(2-phthalimidyl-3-methyl butanoylamino) isophthalic acid and aromatic diamines[J]. Reactive and Functional Polymers, 2008, 68(1):91-96.

Bazzar M, M Ghaemy, R Alizadeh. Novel fluorescent light-emitting polymer composites bearing 1,2,4-triazole and quinoxaline moieties:Reinforcement and thermal stabilization with silicon carbide nanoparticles by epoxide functionalization[J]. Polymer Degradation and Stability, 2012, 97(9):1690-1703.

Song R, D Yang, L He. Preparation of semi-aromatic polyamide(PA)/multi-wall carbon nanotube(MWCNT) composites and its dynamic mechanical properties[J]. Journal of Materials Science, 2008, 43(4):1205-1213.

Shabanian M, M Hajibeygi. Magnetic heat resistant poly(amide-imide) nanocomposite derived from bisphenol A:Synthesis and properties[J]. Polymer Composites, 2013, 34(10):1682-1689.

Faghihi K, M Hajibeygi, M Shabanian. Novel thermally stable poly(amide-imide)s containing dibenzalacetone moiety in the main chain:Synthesis and characterization[J]. Macromolecular Research, 2010, 18(5):421-428.

Faghihi K, Shabanian M, Hajibeygi M , et al. Synthesis and characterization of new poly(ether-ester-imide)s as a generation of soluble and thermally stable polymers[J]. Polymer Bulletin, 2010, 66(1):37-49.

Shabanian M, D Ghanbari. Synthesis of magnesium hydroxide nanofiller and its use for improving thermal properties of new poly(ether-amide)[J]. Journal of Applied Polymer Science, 2013, 127(3):2004-2009.

Shabbir S, et al. Synthesis, characterization and functionalization of thermally stable hyperbranched polyamide-ethers based on 6-hydroxy-2,4-bis(4'-nitrobenzamide)pyrimidine[J]. Polymer Degradation and Stability, 2010, 95(4):500-507.

Shabanian M, Nian-Jun Kang, De-Yi Wang,et al. Synthesis of aromatic-aliphatic polyamide acting as adjuvant in polylactic acid(PLA)/ammonium polyphosphate(APP) system[J]. Polymer Degradation and Stability, 2013, 98(5):1036-1042.

Zulfiqar S, M Ishaq, M Ilyas Sarwar. Synthesis and characterization of soluble aromatic-aliphatic polyamide[J]. Advances in Polymer Technology, 2010, 29(4):300-308.

Zulfiqar S, Zahoor Ahmad, Muhammad Ishaq, et al. Aromatic-aliphatic polyamide/montmorillonite clay nanocomposite materials:Synthesis, nanostructure and properties[J]. Materials Science and Engineering:A, 2009, 525(1-2):30-36.

Sarwar M I, S Zulfiqar, Z Ahmad. Properties of polyamide-zirconia nanocomposites prepared from sol-gel technique[J]. Polymer Composites, 2009, 30(1):95-100.

Zulfiqar S, Ayesha K, Muhammad R, et al. Probing the role of surface treated montmorillonite on the properties of semi-aromatic polyamide/clay nanocomposites[J]. Applied Surface Science, 2008, 255(5):2080-2086.

Shabanian M, Basaki N. New photosensitive semi aramid/organoclay nanocomposite containing cinnamoyl groups:Synthesis and characterization[J]. Composites Part B:Engineering, 2013, 52:224-232.

Zulfiqar, S, Ishaq M, Sarwar M I. Effect of surface modification of montmorillonite on the properties of aromatic polyamide/clay nanocomposites[J]. Surface and Interface Analysis, 2008, 40(8):1195-1201.

Zhao H, et al. Improving the performance of polyamide reverse osmosis membrane by incorporation of modified multi-walled carbon nanotubes[J]. Journal of Membrane Science, 2014. 450(0):249-256.

Mallakpour S, Hatami M. Production and evaluation of the surface properties of chiral poly(amide-imide)/TiO₂ nanocomposites containing L-phenylalanine units[J]. Progress in Organic Coatings, 2012,74(3):564-571.

Pardal F, Slim Salhi, Brigitte Rousseau, et al. Unsaturated polyamides from bio-Based z-octadec-9-enedioic acid[J]. Macromolecular Chemistry and Physics, 2008, 209(1):64-74.

Galià M, Lucas Montero de Espinosa, Joan Carles Ronda,? et al. Vegetable oil-based thermosetting polymers[J]. European Journal of Lipid Science and Technology, 2010, 112(1):87-96.

Zuo J, Shaojun Li, Laziz Bouzidi, et al. Thermoplastic polyester amides derived from oleic acid[J]. Polymer, 2011, 52(20):4503-4516.

Roumanet P J, Lafleche F, Jarroux N, et al. Novel aliphatic polyesters from an oleic acid based monomer. Synthesis, epoxidation, cross-linking and biodegradation[J]. European Polymer Journal, 2013, 49(4):813-822.

Xia Y, R C Larock. Vegetable oil-based polymeric materials:synthesis, properties, and applications[J]. Green Chemistry, 2010, 12(11):1893-1909.

McEwen, J H a W. Azelaic acid[J]. Organic Synthese, 1943, 2:53-54.

Faghihi K, Zamani K. Synthesis and properties of novel flame-retardant poly(amide-imide)s containing phosphine oxide moieties in main chain by microwave irradiation[J]. Journal of Applied Polymer Science, 2006, 101(6):4263-4269.

Shi Y, Takashi Kashiwag, Richard N Walters, et al. Ethylene vinyl acetate/layered silicate nanocomposites prepared by a surfactant-free method:Enhanced flame retardant and mechanical properties[J]. Polymer, 2009, 50(15):3478-3487.

Kiliaris P, Papaspyrides C D. Polymer/layered silicate(clay) nanocomposites:An overview of flame retardancy[J]. Progress in Polymer Science, 2010, 35(7):902-958.

Yu G, Gong J L , Wang S, et al. Etching effects of ethanol on multi-walled carbon nanotubes[J]. Carbon, 2006, 44(7):1218-1224.

Kashiwagi T, Grulke Eric A , Jenny Hilding, et al. Thermal and flammability properties of polypropylene/carbon nanotube nanocomposites[J]. Polymer, 2004, 45(12):4227-4239.

Relative Articles

Supplements(0)

Cited By

Proportional views