Barium (Ⅱ)-doped zinc ferrite-reduced graphene oxide nanohybrids for superior adsorption and magnetic properties

FEI Peng; QIAO Jun; HUO Jin-xian; LIU Jian-hong; ZHONG Ming; SU Bi-tao

doi:10.1016/S1872-5805(17)60131-8

Volume 32 Issue 5

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FEI Peng, QIAO Jun, HUO Jin-xian, LIU Jian-hong, ZHONG Ming, SU Bi-tao. Barium (Ⅱ)-doped zinc ferrite-reduced graphene oxide nanohybrids for superior adsorption and magnetic properties. New Carbon Mater., 2017, 32(5): 402-410. doi: 10.1016/S1872-5805(17)60131-8

Citation:

FEI Peng, QIAO Jun, HUO Jin-xian, LIU Jian-hong, ZHONG Ming, SU Bi-tao. Barium (Ⅱ)-doped zinc ferrite-reduced graphene oxide nanohybrids for superior adsorption and magnetic properties. New Carbon Mater., 2017, 32(5): 402-410. doi: 10.1016/S1872-5805(17)60131-8

Citation:

FEI Peng, QIAO Jun, HUO Jin-xian, LIU Jian-hong, ZHONG Ming, SU Bi-tao. Barium (Ⅱ)-doped zinc ferrite-reduced graphene oxide nanohybrids for superior adsorption and magnetic properties. New Carbon Mater., 2017, 32(5): 402-410. doi: 10.1016/S1872-5805(17)60131-8

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Barium (Ⅱ)-doped zinc ferrite-reduced graphene oxide nanohybrids for superior adsorption and magnetic properties

doi: 10.1016/S1872-5805(17)60131-8

1.
School of Chemistry and Environmental Engineering, Shanxi Datong University, Datong 037009, China;
2.
Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;
3.
School of Materials Science and Engineering, National Institute for Advanced Materials, TKL of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China

Funds: Doctoral Scientific Research Foundation of Shanxi Datong University (2014-B-11); National Natural Science Foundation of China (21174114); Program for Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China (IRT1177); Scientific and Technical plan project of Gansu province (1204GKCA006); National Natural Science Foundation of China (21363021); Scientific and Technical Innovation Project of Northwest Normal University (nwnu-kjcxgc-03-63).

Received Date: 2017-07-15
Accepted Date: 2017-11-13
Rev Recd Date: 2017-10-07
Publish Date: 2017-10-28

Abstract

Abstract

A one-step solvothermal method was used to prepare barium (Ⅱ)-doped zinc ferrite/reduced graphene oxide (Ba²⁺-ZF/rGO) magnetic nanohybrid adsorbents. During the solvothermal treatment, Ba²⁺-ZF nanoparticles were formed from Ba²⁺, Fe³⁺ and Zn²⁺ chlorides, which were anchored on the surface of rGO obtained from the reduction of GO with ethylene glycol. TEM and SEM results show that the Ba²⁺-ZF nanoparticles are uniformly distributed on the rGO sheets without any agglomeration. When used as adsorbents, the Ba²⁺-ZF/rGO nanohybrid with an rGO content of 35% possesses excellent adsorption capacities for methylene blue at different initial concentrations and the adsorption kinetics can be well-described by the pseudo-second-order kinetic model. The formation of Fe²⁺ from FeCl₃·6H₂O and the doping of Ba²⁺ into the spinel structure dramatically improve the magnetism of the zinc ferrite, which makes the magnetic separability of the nanohybrid outstanding. The Ba²⁺-ZF/rGO nanohybrid could be used as an efficient, magnetically separable adsorbent for removing organic dyes.
- Barium ion doped zinc ferrite/reduced graphene oxide,
- One-pot solvothermal method,
- Magnetic property,
- Adsorption activity

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References(37)

References

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