CHEN Hui, GUO Yan-chuan, WANG Fu, WANG Gang, QI Pei-rong, GUO Xu-hong, DAI Bin, YU Feng. An activated carbon derived from tobacco waste for use as a supercapacitor electrode material. New Carbon Mater., 2017, 32(6): 592-599. doi: 10.1016/S1872-5805(17)60140-9
Citation: CHEN Hui, GUO Yan-chuan, WANG Fu, WANG Gang, QI Pei-rong, GUO Xu-hong, DAI Bin, YU Feng. An activated carbon derived from tobacco waste for use as a supercapacitor electrode material. New Carbon Mater., 2017, 32(6): 592-599. doi: 10.1016/S1872-5805(17)60140-9

An activated carbon derived from tobacco waste for use as a supercapacitor electrode material

doi: 10.1016/S1872-5805(17)60140-9
Funds:  Doctor Foundation of Bingtuan (2014BB004);Program of Science and Technology Innovation Team in Bingtuan (2015BD003);Program for Changjiang Scholars,Innovative Research Team in University (IRT_15R46).
  • Received Date: 2017-06-12
  • Accepted Date: 2017-12-28
  • Rev Recd Date: 2017-12-08
  • Publish Date: 2017-12-28
  • A tobacco-derived activated carbon (TAC) was prepared from tobacco waste using KOH activation with a KOH/tobacco carbon mass ratio of 3 at 800℃ for 1 h, and was used as an electrode material for a supercapacitor. The tobacco waste was hydrothermally treated in a 10%(v/v) HCl solution to remove metallic impurities and carbonized before activation. The carbonized tobacco has a low Brunauer-Emmett-Teller (BET) surface area of 111.25 m2·g-1, a pore volume of 0.11 cm3·g-1, an average pore diameter of 1.77 nm and a specific capacitance of 37 F·g-1 at a current density of 0.5 A·g-1. The TAC has a high BET surface area of 1 297.6 m2·g-1, a large pore volume of 0.52 cm3·g-1, and a pore size distribution with a median pore size of 0.52 nm. It has a specific capacitance of 148 F·g-1 at a current density of 0.5 A·g-1 in a 6 M KOH electrolyte, and an excellent cycling stability with no capacitance fade after 9 000 cycles at a current density of 1 A·g-1.
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