LIAN Peng-fei, SONG Jin-liang, LEI Shi-wen, TAO Ze-chao, ZHAO Hong-chao, ZHANG Jun-peng, LIU Zhan-jun. Microstructure and thermophysical properties of graphite foam/Sn-Bi alloy composites for use as a thermal sink for electronics. New Carbon Mater., 2018, 33(4): 351-356. doi: 10.1016/S1872-5805(18)60344-0
Citation: LIAN Peng-fei, SONG Jin-liang, LEI Shi-wen, TAO Ze-chao, ZHAO Hong-chao, ZHANG Jun-peng, LIU Zhan-jun. Microstructure and thermophysical properties of graphite foam/Sn-Bi alloy composites for use as a thermal sink for electronics. New Carbon Mater., 2018, 33(4): 351-356. doi: 10.1016/S1872-5805(18)60344-0

Microstructure and thermophysical properties of graphite foam/Sn-Bi alloy composites for use as a thermal sink for electronics

doi: 10.1016/S1872-5805(18)60344-0
Funds:  Natural Science Foundation of Shanghai (16ZR1443400); National Natural Science Foundation of China (51602336, 21576277, 51602335); Youth Innovation Promotion Association CAS (2017205).
  • Received Date: 2018-06-03
  • Accepted Date: 2018-08-30
  • Rev Recd Date: 2018-07-28
  • Publish Date: 2018-08-28
  • Two mesophase pitch-based graphite foams with densities of 0.62±0.01 (GF1) and 0.84±0.01 g/cm3 (GF2) were prepared by foaming the pitch in an autoclave at 723 K, 6.0 MPa and 763 K, 13.4 MPa, respectively, followed by carbonization at 1273 K for 2 h and graphitization at 2973 K for 0.5 h. The GFs were infiltrated by a Sn-Bi liquid to prepare GF/Sn-Bi alloy composites for use as thermal sinks for electronics. The microstructures and thermophysical properties of the composites were investigated. Results indicated that GF1 had a larger cells and thinner cell walls than GF2. The Sn-Bi liquid was well infiltrated into cells of the GFs, resulting in composites with densities of 5.60±0.01 and 3.83±0.01 g/cm3 for GF1 and GF2, respectively. The thermal diffusivity and coefficient of thermal expansion (CTE) of the GF1/Sn-Bi composite were 51.6±2 mm2/s and 16.6±0.02 ppm/K, respectively. The corresponding values for the GF2/Sn-Bi were 163.1±3 mm2/s and 8.08±0.02 ppm/K. The GF2/Sn-Bi composite had a high thermal diffusivity and a low CTE value matching that of semiconductor chips and packaging materials.
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