Synthesis and photoluminescence of graphdiyne

ZHENG Yong-ping; FENG Qian; TANG Nu-jiang; DU You-wei

doi:10.1016/S1872-5805(18)60354-3

Volume 33 Issue 6

Turn off MathJax

Article Contents

Article Navigation > New Carbon Mater. > 2018 > 33(6): 516-521

ZHENG Yong-ping, FENG Qian, TANG Nu-jiang, DU You-wei. Synthesis and photoluminescence of graphdiyne. New Carbon Mater., 2018, 33(6): 516-521. doi: 10.1016/S1872-5805(18)60354-3

Citation:

ZHENG Yong-ping, FENG Qian, TANG Nu-jiang, DU You-wei. Synthesis and photoluminescence of graphdiyne. New Carbon Mater., 2018, 33(6): 516-521. doi: 10.1016/S1872-5805(18)60354-3

ZHENG Yong-ping, FENG Qian, TANG Nu-jiang, DU You-wei. Synthesis and photoluminescence of graphdiyne. New Carbon Mater., 2018, 33(6): 516-521. doi: 10.1016/S1872-5805(18)60354-3

Citation:

ZHENG Yong-ping, FENG Qian, TANG Nu-jiang, DU You-wei. Synthesis and photoluminescence of graphdiyne. New Carbon Mater., 2018, 33(6): 516-521. doi: 10.1016/S1872-5805(18)60354-3

PDF( 1771 KB)

Synthesis and photoluminescence of graphdiyne

doi: 10.1016/S1872-5805(18)60354-3

1.
Fujian Provincial Key Laboratory of Quantum Manipulation & New Energy Materials, Fujian Normal University, Fuzhou 350117, China;
2.
National Laboratory of Solid State Microstructures & Jiangsu Provincial Key Laboratory for Nanotechnology, Nanjing University, Nanjing 210093, China

Funds: State Key Program for Basic Research (2014CB921102); National Natural Science Foundation of China (51572122); Natural Science Foundation of Fujian Province (2016J01291, 2017J01476).

Received Date: 2018-10-18
Accepted Date: 2018-12-27
Rev Recd Date: 2018-12-03
Publish Date: 2018-12-28

Abstract

Abstract

Graphdiyne was prepared by a cross coupling reaction and characterized by SEM, TEM, XRD, Raman spectroscopy and XPS. Its photoluminescence (PL) properties were investigated. It was found that the graphdiyne has a thickness of ca. 1 μm, a O/C atomic ratio of ca. 0.174 1 and many oxygen-containing functional groups. It exhibits strong ultraviolet (UV) PL at 397 nm and optical absorption at ca. 280 nm. It is proposed that the oxygen-containing functional groups in the graphdiyne induce charge transfer, leading to the PL properties. As a new kind of artificially synthesized carbon allotrope, graphdiyne with UV PL have many applications.
- Cross coupling reaction,
- Graphdiyne,
- Photoluminescence

FullText(HTML)

References(27)

References

Nurunnabi M, Khatun Z, Huh K M, et al. In vivo biodistribution and toxicology of carboxylated graphene quantum dots[J]. ACS Nano, 2013, 7:6858-6867.

Wen J, Xu Y Q, Li H J, et al. Recent applications of carbon nanomaterials in fluorescence biosensing and bioimaging[J]. Chemical Communications, 2015, 51:11346-11358.

Eda G, Lin Y Y, Mattevi C, et al. Blue photoluminescence from chemically derived graphene oxide[J]. Advanced Materials, 2010, 22:505-509.

Sun X, Liu Z, Welsher K, et al. Nano-graphene oxide for cellular imaging and drug delivery[J]. Nano Research, 2008, 1:203-212.

Malko D, Neiss C, Viñes F, et al. Competition for graphene:Graphynes with direction-dependent Dirac cones[J]. Physical Review Letters, 2012, 108:086804.

Narita N, Nagai S, Suzuki S, et al. Electronic structure of three-dimensional graphyne[J]. Physical Review B, 2000, 62:11146.

Narita N, Nagai S, Suzuki S, et al. Optimized geometries and electronic structures of graphyne and its family[J]. Physical Review B, 1998, 58:11009.

Malko D, Neiss C, GÖrling A. Two-dimensional materials with Dirac cones:Graphynes containing heteroatoms[J]. Physical Review B, 2012, 86:045443.

Kim B G, Choi H J. Graphyne:Hexagonal network of carbon with versatile Dirac cones[J]. Physical Review B, 2012, 86:115435.

Li G X, Li Y L, Liu H B, et al. Architecture of graphdiyne nanoscale films[J]. Chemical Communications, 2010, 46:3256-3258.

Li Y J, Xu L, Liu H B, et al. Graphdiyne and graphyne:from theoretical predictions to practical construction[J]. Chemical Society Reviews, 2014, 43:2572-2586.

Chen Y H, Liu H B, Li Y L, et al. Progress and prospect of two dimension carbon graphdiyne[J]. Chinese Science Bulletin, 2016, 61:2901-2912.

Qian X M, Ning Z Y, Li Y L, et al. Construction of graphdiyne nanowires with high-conductivity and mobility[J]. Dalton Transactions, 2012, 41:730-733.

Chen J M, Xi J Y, Wang D, et al. Carrier mobility in graphyne should be even larger than that in graphene:A theoretical prediction[J]. The Journal of Physical Chemistry Letters, 2013, 4:1443-1448.

Huang C S, Zhang S L, Liu H B, et al. Graphdiyne for high capacity and long-life lithium storage[J]. Nano Energy, 2015, 11:481-489.

Zhang S L, Liu H B, Huang C S, et al. Bulk graphdiyne powder applied for highly efficient lithium storage[J]. Chemical Communications, 2015, 51:1834-1837.

Qi H T, Yu P, Wang Y X, et al. Graphdiyne oxides as excellent substrate for electroless deposition of Pd clusters with high catalytic activity[J]. Journal of the American Chemical Society, 2015, 137:5260-5263.

Kuang C Y, Tang G, Jiu T G, et al. Highly efficient electron transport obtained by doping PCBM with graphdiyne in planar-heterojunction perovskite solar cells[J]. Nano Letters, 2015, 15:2756-2762.

Xue Z, Yang H, Gao J, et al. Controlling the interface areas of organic/inorganic semiconductor heterojunction nanowires for high-performance diodes[J]. ACS Applied Materials & Interfaces, 2016, 8:21563-21569.

Jin Z W, Zhou Q, Chen Y Y, et al. Graphdiyne:ZnO nanocomposites for high-performance UV photodetectors[J]. Advanced Materials, 2016, 28:3697-3702.

Luo G F, Zheng Q Y, Mei W N, et al. Structural, electronic, and optical properties of bulk graphdiyne[J]. The Journal of Physical Chemistry C, 2013, 117:13072-13079.

Liu R J, Liu H B, Li Y L, et al. Nitrogen-doped graphdiyne as a metal-free catalyst for high-performance oxygen reduction reactions[J]. Nanoscale, 2014, 6:11336-11343.

Luo G F, Qian X M, Liu H B, et al. Quasiparticle energies and excitonic effects of the two-dimensional carbon allotrope graphdiyne:Theory and experiment[J]. Physical Review B, 2011, 84:075439.

Li M, Wu W B, Ren W C, et al. Synthesis and upconversion luminescence of N-doped graphene quantum dots[J]. Applied Physics Letters, 2012, 101:103107.

Jin S H, Kim D H, Jun G H, et al. Tuning the photoluminescence of graphene quantum dots through the charge transfer effect of functional groups[J]. ACS Nano, 2013, 7:1239-1245.

Kang B T, Liu H G, Lee J Y. Oxygen adsorption on single layer graphyne:A DFT study[J]. Physical Chemistry Chemical Physics, 2014, 16:974-980.

Sun J, Yang S W, Wang Z Y, et al. Ultra-high quantum yield of graphene quantum dots:Aromatic-nitrogen doping and photoluminescence mechanism[J]. Particle & Particle Systems Characterization, 2015, 32:434-440.

Relative Articles

Supplements(0)

Cited By

Proportional views