Recycled silicon powder coated on carbon paper used as the anode of lithium ion batteries

SHEN Chin-Wei; KO Tse-Hao; CHIU Kuo-Feng; LEU Hoang-Jyh; LIAO Ting-Chia; LIU Ching-Han

doi:10.1016/S1872-5805(19)60007-7

Volume 34 Issue 2

Turn off MathJax

Article Contents

Article Navigation > New Carbon Mater. > 2019 > 34(2): 140-145

SHEN Chin-Wei, KO Tse-Hao, CHIU Kuo-Feng, LEU Hoang-Jyh, LIAO Ting-Chia, LIU Ching-Han. Recycled silicon powder coated on carbon paper used as the anode of lithium ion batteries. New Carbon Mater., 2019, 34(2): 140-145. doi: 10.1016/S1872-5805(19)60007-7

Citation:

SHEN Chin-Wei, KO Tse-Hao, CHIU Kuo-Feng, LEU Hoang-Jyh, LIAO Ting-Chia, LIU Ching-Han. Recycled silicon powder coated on carbon paper used as the anode of lithium ion batteries. New Carbon Mater., 2019, 34(2): 140-145. doi: 10.1016/S1872-5805(19)60007-7

Citation:

SHEN Chin-Wei, KO Tse-Hao, CHIU Kuo-Feng, LEU Hoang-Jyh, LIAO Ting-Chia, LIU Ching-Han. Recycled silicon powder coated on carbon paper used as the anode of lithium ion batteries. New Carbon Mater., 2019, 34(2): 140-145. doi: 10.1016/S1872-5805(19)60007-7

PDF( 5004 KB)

Recycled silicon powder coated on carbon paper used as the anode of lithium ion batteries

doi: 10.1016/S1872-5805(19)60007-7

Carbon Laboratory for Department of Materials Science and Engineering, Feng Chia University, Taichung 40724, China

Funds: Ministry of Science and Technology, China (MOST 104-2221-E-035-010).

Received Date: 2018-12-03
Accepted Date: 2019-04-30
Rev Recd Date: 2019-02-28
Publish Date: 2019-04-28

Abstract

Abstract

High-capacity electrode materials are critical for portable electronic equipment that requires a high-energy density from lithium ion batteries (LIBs). Many different materials and fabrication methods for such electrodes have been developed for this purpose. Carbon paper coated with recycled silicon powder (CP-RSP) was prepared by coating silicon and pitch powder on the carbon paper, followed by stabilization at 250℃ in air and carbonization at 1 000℃ in N₂. The CP-RSP acted as both the current-collector and the active material for the anodes of LIBs. Electrodes with 2.5, 5, and 10 wt.% silicon exhibited capacity increases of 94, 129 and 41%, respectively, compared with the silicon-free electrode. The electrode for the CP-RSP with 5 wt.% silicon exhibited an optimal balance between discharge capacity and stability in long-cycle tests under various charging rates.
- High-capacity electrode materials,
- Lithium-ion batteries,
- Carbon composite paper,
- Silicon-containing electrodes

FullText(HTML)

References(15)

References

Castro L, Dedryvère R, Ledeuil J B, et al. Aging mechanisms of LiFePO₄//graphite cells studied by XPS:Redox reaction and electrode/electrolyte interfaces[J]. The Electrochemical Society, 2012, 159(4):A357-363.

Koltypin M, Aurbach D, Nazar L, et al. More on the performance of LiFePO₄electrodes-The effect of synthesis route, solution composition, aging, and temperature[J]. Power Sources, 2007, 174:1241-1250.

Striebel K, Shim J, Sierra A, et al. The development of low cost LiFePO₄-based high power lithium-ion batteries[J]. Power Sources, 2005, 146:33-38.

Liu D J, Chen L C, Liu T J, et al. An effective mixing for lithium ion battery slurries[J]. Advances in Chemical Engineering and Science, 2014, 4(4):515-528.

Poizot P, Laruelle S, Grugeon S, et al. Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries[J], Nature, 2000, 407:496-499.

Winter M, Besenhard J O, Spahr M E, et al. Insertion electrode materials for rechargeable lithium batteries[J], Adv Mater, 1998, 10:725-763.

Szczech Jeannine R, Jin Song, et al. Nanostructured silicon for high capacity lithium battery anodes[J]. Energy Environ Sci, 2011, 4:56-72.

Zhao X Y, Xia D G, Gu L, et al. High-performance self-organized Si nanocomposite anode for lithium-ion batteries[J]. Energy Chemistry, 2014, 23:291-300.

Kasavajjula U, Wang C S, John A A, et al. Nano-and bulk-silicon-based insertion anodes for lithium-ion secondary cells[J]. Power Sources, 2007, 163:1003-1039.

Ding Z Y, Li X C, Wei T G, et al. Improved compatibility of graphite anode for lithium ion battery using sulfuric esters[J]. Electrochimica Acta, 2016, 196:622-628.

Zhou Y, Guo H, Yang Y, et al. Facile synthesis of silicon/carbon nanospheres composite anode materials for lithium-ion batteries[J]. Materials Letters, 2016, 168:138-142.

Liu X H, Huang J Y, et al. In situ TEM electrochemistry of anode materials in lithium ion batteries[J]. Energy Environ. Sci., 2011, 4:3844-3860.

Li M, Hou X H, Sha Y J, et al. Facile spray-drying/pyrolysis synthesis of coreeshell structure graphite/silicon-porous carbon composite as a superior anode for Li-ion batteries[J]. Power Sources, 2014, 248:721-728.

Mukherjee R, Krishnan R, Lu T M, et al. Nanostructured electrodes for high-power lithium ion batteries[J]. Nano Energy, 2012, 1(4):518-533.

Jawhari T, Roidb A, Casado J, et al. Raman spectroscopic characterization of some commercially available carbon black materials[J]. Carbon, 1995, 33(11):1561-1565.

Relative Articles

Supplements(0)

Cited By

Proportional views