The selective aerobic oxidation of 5-hydroxymethylfurfural to produce 2,5-diformylfuran using nitrogen-doped porous carbons as catalysts

TENG Na; LI Jin-long; LU Bo-qiong; WANG Yu-qi; JIA Shi-yu; WANG Ying-xiong; HOU Xiang-lin

doi:10.1016/S1872-5805(19)60034-X

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TENG Na, LI Jin-long, LU Bo-qiong, WANG Yu-qi, JIA Shi-yu, WANG Ying-xiong, HOU Xiang-lin. The selective aerobic oxidation of 5-hydroxymethylfurfural to produce 2,5-diformylfuran using nitrogen-doped porous carbons as catalysts. New Carbon Mater., 2019, 34(6): 593-599. doi: 10.1016/S1872-5805(19)60034-X

Citation:

TENG Na, LI Jin-long, LU Bo-qiong, WANG Yu-qi, JIA Shi-yu, WANG Ying-xiong, HOU Xiang-lin. The selective aerobic oxidation of 5-hydroxymethylfurfural to produce 2,5-diformylfuran using nitrogen-doped porous carbons as catalysts. New Carbon Mater., 2019, 34(6): 593-599. doi: 10.1016/S1872-5805(19)60034-X

Citation:

TENG Na, LI Jin-long, LU Bo-qiong, WANG Yu-qi, JIA Shi-yu, WANG Ying-xiong, HOU Xiang-lin. The selective aerobic oxidation of 5-hydroxymethylfurfural to produce 2,5-diformylfuran using nitrogen-doped porous carbons as catalysts. New Carbon Mater., 2019, 34(6): 593-599. doi: 10.1016/S1872-5805(19)60034-X

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The selective aerobic oxidation of 5-hydroxymethylfurfural to produce 2,5-diformylfuran using nitrogen-doped porous carbons as catalysts

doi: 10.1016/S1872-5805(19)60034-X

TENG Na^1,2,3,
LI Jin-long^1,2,3,
LU Bo-qiong^1,2,3,
WANG Yu-qi^{1,2,3
,},
JIA Shi-yu^1,2,3,
WANG Ying-xiong^1,2,3,
HOU Xiang-lin^1,2,3

1.
Shanxi Engineering Research Center of Biorefinery, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China;
2.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China;
3.
CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

Funds: National Natural Science Foundation of China (U1710252, 51703237); Applied Fundamental Research Project of Shanxi Province (201701D221053).

Received Date: 2019-11-10
Accepted Date: 2020-01-03
Rev Recd Date: 2019-12-05
Publish Date: 2019-12-28

Abstract

Abstract

The selective aerobic oxidation of 5-hydroxymehtylfurfural (HMF) to synthesize 2,5-diformylfuran (DFF) using nitrogen-doped porous carbons as catalysts was achieved. The N-doped carbon materials were prepared by pyrolysis of chitosan with K₂CO₃ as an activator at 600 to 900℃. The N-doped porous carbon activated at 700℃ showed the highest catalytic activity in the conversion from HMF to DFF without any co-catalyst, i.e., the 95.3% HMF conversion and 94.6% selectivity of DFF under optimum reaction conditions (120℃, 7.5 h and 2.0 MPa O₂). According to the XPS results graphitic nitrogen on the surface of the catalysts played a critical role in the activation of O₂ to form oxygen radicals that facilitated the oxidative dehydrogenation of HMF.
- 5-Hydroxymethylfurfural,
- 2,5-Diformylfuran,
- Chitosan,
- Nitrogen-doped carbon,
- Oxidative dehydrogenation

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References

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