Citation: | YAN Rui, WANG Kai, WANG Cong-wei, GUO Quan-gui, WANG Jun-zhong. A review of graphene-based catalysts for oxygen reduction reaction. New Carbon Mater., 2020, 35(5): 508-521. doi: 10.19869/j.ncm.1007-8827.20170141 |
Zhou M, Wang H L, Guo S, et al. Towards high-efficiency nanoelectrocatalysts for oxygen reduction through engineering advanced carbon nanomaterials[J]. Chemical Society Reviews, 2016, 45:1273-1307.
|
Maldonado S, Stevenson K J, et al. Direct preparation of carbon nanofiber electrodes via pyrolysis of Iron(Ⅱ) phthalocyanine:electrocatalytic aspects for oxygen reduction[J]. Journal of Physics Chemical B, 2004, 108(31):11375-11383.
|
Hu Y, Jensen J O, Zhang W, et al. Fe3C-based oxygen reduction catalysts:synthesis, hollow spherical structures and applications in fuel cells[J]. Journal of Material Chemical A, 2015, 3(4):1752-1760.
|
衣保廉.燃料电池:高效,环境友好的发电方式[M]:化学工业出版社, 2000. (Yi Baolian. Fuel Cell:An Efficient and Environmentally Friendly Power Generation Method[M]:Chemical Industry Press, 2000)
|
Liu M, Zhang R, Chen W, et al. Graphene-supported nanoelectrocatalysts for fuel cells:synthesis, properties, and applications[J]. Chemical Reviews, 2014, 114(10):5117-5160.
|
Wang Z B, Zhao C R, Shi P F, et al. Effect of a carbon support containing large mesopores on the performance of a Pt-Ru-Ni/C catalyst for direct methanol fuel cells[J]. Journal of Physics Chemical C, 2010, 114(1):672-677.
|
Fang B, Chaudhari N K, Kim M S, et al. Homogeneous deposition of platinum nanoparticles on carbon black for proton exchange membrane fuel Cell[J]. Journal of American Chemical Society, 2009, 131(42):15330-15338.
|
Hartnig C, Schmidt T J, Simulated start-stop as a rapid aging tool for polymer electrolyte fuel cell electrodes[J]. Journal of Power Sources, 2011, 196(13):5564-5572.
|
Kinoshita K, Lundquist J T, Stonehart P. Potential cycling effects on platinum electrocatalyst surfaces[J]. Jounal of Electroanalytical Chemical, 1973, 48(2):157-166.
|
Meier J C, Galeano C, Katsounaros I, et al. Degradation mechanisms of Pt/C fuel cell catalysts under simulated start-stop conditions[J]. ACS Catalysis, 2012, 2(5):832-843.
|
Schmidt T J, Baurmeister J. Properties of high-temperature PEFC Celtec®-P 1000 MEAs in start/stop operation mode[J]. Journal of Power Sources, 2008, 176(2):428-434.
|
Tang H, Qi Z, Ramani M, et al. PEM fuel cell cathode carbon corrosion due to the formation of air/fuel boundary at the anode[J]. Journal of Power Sources, 2006, 158(2):1306-1312.
|
Donthu S, Cai M, Ruthkosky M, et al. Carbon-titania composite substrates for fuel cell catalyst applications[J]. Chemical Communications, 2009, (28):4203-4205.
|
Liu Y, Mustain W E. Structural and electrochemical studies of Pt clusters supported on high-surface-area tungstencarbide for oxygen reduction[J]. ACS Catalysis, 2011, 1(3):212-220.
|
Chen W, Kim J, Sun S, et al. Composition effects of FePt alloy nanoparticles on the electro-oxidation of formic acid[J]. Langmuir, 2007, 23(22):11303-11310.
|
Wei W, Chen W, et al. "Naked" Pd nanoparticles supported on carbon nanodots as efficient anode catalysts for methanol oxidation in alkaline fuel cells[J]. Journal of Power Sources, 2012, 204:85-88.
|
Liu Z, Ling X Y, Su X, et al. Carbon-supported Pt and PtRu nanoparticles as catalysts for a direct methanol fuel Cell[J]. Journal of Physics Chemical B, 2004, 108(24):8234-8240.
|
Venkateswara Rao C, Cabrera C R, Ishikawa Y. Graphene-supported Pt-Au alloy nanoparticles:a highly efficient anode for direct formic acid fuel Cells[J]. Journal of Physics Chemical C, 2011, 115(44):21963-21970.
|
Li Y, Tang L, Li J. Preparation and electrochemical performance for methanol oxidation of Pt/graphene nanocomposites[J]. Electrochemical Communication, 2009, 11(4):846-849.
|
Guo S, Wen D, Zhai Y, et al. Platinum nanoparticle ensemble-on-graphene hybrid nanosheet:one-pot, rapid synthesis, and used as new electrode material for electrochemical sensing[J]. ACS Nano, 2010, 4(7):3959-3968.
|
Li Y, Li Y, Zhu E, et al. Stabilization of high-performance oxygen reduction reaction Pt electrocatalyst supported on reduced graphene oxide/carbon black composite[J]. Journal of American Chemical Society, 2012, 134(30):12326-12329.
|
Guo S, Sun S. FePt nanoparticles assembled on graphene as enhanced catalyst for oxygen reduction reaction[J]. Journal of American Chemical Society, 2012, 134(5):2492-2495.
|
Wei G, Zhang Y, Steckbeck S, et al. Biomimetic graphene-FePt nanohybrids with high solubility, ferromagnetism, fluorescence, and enhanced electrocatalytic activity[J]. Journal of Material Chemistry, 2012, 22(33):17190-17195.
|
Ji Z, Zhu G, Shen X, et al. Reduced graphene oxide supported FePt alloy nanoparticles with high electrocatalytic performance for methanol oxidation[J]. New Journal of Chemistry, 2012, 36(9):1774-1780.
|
Yang H, Kwon Y, Kwon T, et al. ‘Click’ preparation of CuPt nanorod-anchored graphene oxide as a catalyst in water[J]. Small, 2012, 8(20):3161-3168.
|
Liu Y, Huang Y, Xie Y, et al. Preparation of highly dispersed CuPt nanoparticles on ionic-liquid-assisted graphene sheets for direct methanol fuel cell[J]. Chemical Engineering Journal, 2012, 197:80-87.
|
Anandan S, Manivel A, Ashokkumar M. One-Step sonochemical synthesis of reduced graphene oxide/Pt/Sn hybrid materials and their electrochemical properties[J]. Fuel Cells, 2012, 12(6):956-962.
|
Han F, Wang X, Lian J, et al. The effect of Sn content on the electrocatalytic properties of Pt-Sn nanoparticles dispersed on graphene nanosheets for the methanol oxidation reaction[J]. Carbon, 2012, 50(15):5498-5504.
|
Rao C V, Reddy A L M, Ishikawa Y, et al. Synthesis and electrocatalytic oxygen reduction activity of graphene-supported Pt3Co and Pt3Cr alloy nanoparticles[J]. Carbon, 2011, 49(3):931-936.
|
Feng L, Gao G, Huang P, et al. Preparation of Pt Ag alloy nanoisland/graphene hybrid composites and its high stability and catalytic activity in methanol electro-oxidation[J]. Nanoscale Research Letters, 2011, 6(1):551.
|
Guo S, Dong S, Wang E. Three-dimensional Pt-on-Pd bimetallic nanodendrites supported on graphene nanosheet:facile synthesis and used as an advanced nanoelectrocatalyst for methanol oxidation[J]. ACS Nano, 2010, 4(1):547-555.
|
Hu C, Cheng H, Zhao Y, et al. Newly-designed complex ternary Pt/PdCu nanoboxes anchored on three-dimensional graphene framework for highly efficient ethanol oxidation[J]. Advanced Materials, 2012, 24(40):5493-5498.
|
Liu R, Zhou H, Liu J, et al. Preparation of Pd/MnO2-reduced graphene oxide nanocomposite for methanol electro-oxidation in alkaline media[J]. Electrochemistry Communications, 2013, 26:63-66.
|
Awasthi R, Singh R N. Synthesis and structural characterization of a ternary palladium-ruthenium-tin nanoalloy supported on graphene nanosheets for methanol electrooxidation in alkaline medium[J]. Catalysis Science Technology, 2012, 2(12):2428-2432.
|
Lefèvre M, Dodelet J P, Bertrand P. Molecular oxygen reduction in PEM fuel cells:evidence for the simultaneous presence of two active sites in Fe based catalysts[J]. Journal of Physics Chemical B, 2002, 106(34):8705-8713.
|
Lee J S, Park G S, Kim S T, et al. A highly efficient electrocatalyst for the oxygen reduction reaction:N-doped ketjenblack incorporated into Fe/Fe3C-functionalized melamine foam[J]. Angewandte Chemie International Edition, 2013, 125(3):1060-1064.
|
Wiesener K. N4-chelates as electrocatalyst for cathodic oxygen reduction[J]. Electrochim Acta, 1986, 31(8):1073-1078.
|
Schulenburg H, Stankov S, Schünemann V, et al. Catalysts for the oxygen reduction from heat-treated Iron(Ⅲ) tetramethoxyphenylporphyrin chloride:structure and stability of active sites[J]. Journal of Physics Chemical B, 2003, 107(34):9034-9041.
|
Gojkovi[SX(B-*2]'[] [JX-*5]c[SX)] S L, Gupta S, Savinell R F. Heat-treated iron(Ⅲ) tetramethoxyphenyl porphyrin chloride supported on high-area carbon as an electrocatalyst for oxygen reduction:Part Ⅱ. Kinetics of oxygen reduction[J]. Journal of Electroanalytical Chemical, 1999, 462(1):63-72.
|
Sawaguchi T, Itabashi T, Matsue T, et al. Electrochemical reduction of oxygen by metalloporphyrin ion-complexes with heat treatment[J]. Jounal of Electroanalytical Chemical International, 1990, 279(1):219-230.
|
Hung T F,Tu M H,Tsai C W, et al. Influence of pyrolysis temperature on oxygen reduction reaction activity of carbon-incorporating iron nitride/nitrogen-doped graphene nanosheets catalyst[J]. International Journal of Hydrogen Energy, 2013, 38(10):3956-3962.
|
Zhang Y, Mo G, Li X, et al. Iron tetrasulfophthalocyanine functionalized graphene as a platinum-free cathodic catalyst for efficient oxygen reduction in microbial fuel cells[J]. Journal of Power Sources, 2012, 197:93-96.
|
Kamiya K, Hashimoto K, Nakanishi S. Instantaneous one-pot synthesis of Fe-N-modified graphene as an efficient electrocatalyst for the oxygen reduction reaction in acidic solutions[J]. Chemical Communications, 2012, 48(82):10213-10215.
|
Liang Y, Li Y, Wang H, et al. Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction[J]. Nature Materials, 2011, 10(10):780-786.
|
Guo S, Zhang S, Wu L, et al. Co/CoO nanoparticles assembled on graphene for electrochemical reduction of oxygen[J]. Angewandte Chemie International Edition, 2012, 124(47):11940-11943.
|
Wu Z S,Yang S, Sun Y, et al. 3D nitrogen-doped graphene aerogel-supported Fe3O4 nanoparticles as efficient electrocatalysts for the oxygen reduction reaction[J]. Journal of American Chemical Society, 2012, 134(22):9082-9085.
|
Shen M, Ruan C, Chen Y, et al. Covalent entrapment of cobalt-iron sulfides in N-doped mesoporous carbon:extraordinary bifunctional electrocatalysts for oxygen reduction and evolution reactions[J]. ACS Applied Materials& Interfaces, 2015, 7:1207-1218.
|
Yuliang M, Jianmei Y, Jianxin Z. Density functional calculation of transition metal adatom adsorption on graphene. Journal of Physics Condensed Matter, 2008, 20(11):115209.
|
Wang J, Zhou J, Hu Y, et al. Chemical interaction and imaging of single Co3O4/graphene sheets studied by scanning transmission X-ray microscopy and X-ray absorption spectroscopy[J]. Energy &Environmental Science, 2013, 6(3):926-934.
|
Mahmood N, Zhang C, Jiang J, et al. Multifunctional Co3S4/graphene composites for lithium ion batteries and oxygen reduction reaction[J]. Chemistry-a European Journal, 2013, 19:5183-5190.
|
Zhang L R, Zhao J, Li M, et al. Preparation of graphene supported nickel nanoparticles and their application to methanol electrooxidation in alkaline medium[J]. New Journal of Chemistry, 2012, 36(4):1108-1113.
|
Zhang P, Lu X, Huang Y, et al. MoS2 nanosheets decorated with gold nanoparticles for rechargeable Li-O2 batteries[J]. Journal of Material Chemistry, 2015, 3:14562-14566.
|
Wang X, Ke Y, Pan H, et al. Cu-deficient plasmonic Cu2-xS nanoplate electrocatalysts for oxygen reduction[J]. ACS Catalysis, 2015, 5:2534-2540.
|
Yan X Y, Tong X L, Zhang Y F, et al. Cuprous oxide nanoparticles dispersed on reduced graphene oxide as an efficient electrocatalyst for oxygen reduction reaction[J]. Chemical Communications, 2012, 48(13):1892-1894.
|
Zhou Y, Cheng X, Yen C H, et al. Synthesis of an excellent electrocatalyst for oxygen reduction reaction with supercritical fluid:Graphene cellular monolith with ultrafine and highly dispersive multimetallic nanoparticles[J]. Journal of Power Sources, 2017, 347:69-78.
|
Zheng P, Zhou W, Wang Y B, et al. N-doped graphene-wrapped TiO2 nanotubes with stable surface Ti3+ for visible-light photocatalysis[J]. Applied Surface Science, 2020, 512:144549.
|
Sun L, Wang L, Tian C, et al. Nitrogen-doped graphene with high nitrogen level via a one-step hydrothermal reaction of graphene oxide with urea for superior capacitive energy storage[J]. RSC Advances, 2012, 2(10):4498-4506.
|
Jin Z, Yao J, Kittrell C, et al. Large-scale growth and characterizations of nitrogen-doped monolayer graphene sheets[J]. ACS Nano, 2011, 5(5):4112-4117.
|
Shao Y, Zhang S, Engelhard M H, et al. Nitrogen-doped graphene and its electrochemical applications[J]. Journal of Material Chemistry, 2010, 20(35):7491-7496.
|
Pan F, Jin J, Fu X, et al. Advanced oxygen reduction electrocatalyst based on nitrogen-doped graphene derived from edible sugar and urea[J]. ACS Applied Materials& Interfaces, 2013, 5(21):11108-11114.
|
Qu L, Liu Y, Baek J B, et al. Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells[J]. ACS Nano, 2010, 4(3):1321-1326.
|
Wei W, Liang H, Parvez K, et al. Nitrogen-doped carbon nanosheets with size-defined mesopores as highly efficient metal-free catalyst for the oxygen reduction reaction[J]. Angewandte Chemie International Edition, 2014, 126(6):1596-1600.
|
Joseph H, Ulises M, Kateryna A, et al. Nitrogen-doped graphene oxide electrocatalysts for the oxygen reduction reaction[J]. ACS Appl Nano Mater 2019, 2:1675-1682.
|
Tang Y B, Yin L C, Yang Y, et al.Tunable band gaps and p-type transport properties of boron-doped graphenes by controllable ion doping using reactive microwave plasma[J]. ACS Nano, 2012, 6(3):1970-1978.
|
Han J, Zhang L L, Lee S, et al. Generation of B-doped graphene nanoplatelets using a solution process and their supercapacitor applications[J]. ACS Nano, 2013, 7(1):19-26.
|
Li M, Liu C, Zhao H, et al. Tuning sulfur doping in graphene for highly sensitive dopamine biosensors[J]. Carbon, 2015, 86:197-206.
|
Jeon I Y, Zhang S, Zhang L, et al. Edge-selectively sulfurized graphene nanoplatelets as efficient metal-free electrocatalysts for oxygen reduction reaction:the electron spin effect[J]. Advanced Materials, 2013, 25(42):6138-6145.
|
Gong Y, Fei H, Zou X, et al. Boron- and nitrogen-substituted graphene nanoribbons as efficient catalysts for oxygen reduction reaction[J]. Chemical Materials, 2015, 27(4):1181-1186.
|
Zehtab Yazdi A, Roberts E P L, Sundararaj U. Nitrogen/sulfur co-doped helical graphene nanoribbons for efficient oxygen reduction in alkaline and acidic electrolytes[J]. Carbon, 2016, 100:99-108.
|
Li R, Wei Z, Gou X. Nitrogen and phosphorus dual-doped graphene/carbon nanosheets as functional electrocatalysts for oxygen reduction and evolution[J]. ACS Catalysis, 2015:4133-4142.
|
Li Y, Zhao Y, Cheng H, et al. Nitrogen-doped graphene quantum dots with oxygen-rich functional groups[J]. Journal of American Chemical Society, 2011, 134(1):15-18.
|
Li Q, Zhang S, Dai L, et al. Nitrogen-doped colloidal graphene quantum dots and their size-dependent electrocatalytic activity for the oxygen reduction reaction[J]. Journal of American Chemical Society, 2012, 134(46):18932-18935.
|
Zhou X, Tian Z, Li J, et al. Synergistically enhanced activity of graphene quantum dot/multi-walled carbon nanotube composites as metal-free catalysts for oxygen reduction reaction[J]. Nanoscale 2014, 6:2603-2607.
|
Jin H, Huang H, He Y, et al. Graphene quantum dots supported by graphene nanoribbons with ultrahigh electrocatalytic performance for oxygen reduction[J]. Journal of American Chemical Society, 2015, 137(24):7588-7591.
|
Palaniselvam T, Valappil M O, Illathvalappil R, et al. Nanoporous graphene by quantum dots removal from graphene and its conversion to a potential oxygen reduction electrocatalyst via nitrogen doping[J]. Energy & Environmental Science, 2014, 7(3):1059-1067.
|
Wang C, Zhang H, Wang J, et al. Atomic Fe embedded in carbon nanoshells-graphene nanomeshes with enhanced oxygen reduction reaction performance[J]. Chem Mater, 2017, 29, 9915-9922.
|
Men B, Sun Y, Li M, et al. Hierarchical metal-free nitrogen-doped porous graphene/carbon composites as an efficient oxygen reduction reaction catalyst[J]. ACS Applied Materials& Interfaces, 2016, 8(2):1415-1423.
|
Wang C, Zhao H, Wang J, et al. Atomic Fe hetero-layered coordination between g-C3N4 and graphene nanomeshes enhances the ORR electrocatalytic performance of zinc-air batteries[J]. J Mater Chem A, 2019, 7, 1451-1458.
|
Chen Y, Wang Q, Bai X, et al. Unexpected catalytic performance of Fe-M-C (M=N, P and S) electrocatalysts towards oxygen reduction reaction:surface heteroatoms boost the activity of Fe2M/graphene nanocomposites[J]. Dalton Trans 2017, DOI: 10.1039/C7DT03903D.
|
Thomas M, Illathvalappil R, Kurungot S, et al. Graphene oxide sheathed zif-8 microcrystals:engineered precursors of nitrogen-doped porous carbon for efficient oxygen reduction reaction (ORR) electrocatalysis[J]. ACS Applied Materials& Interfaces, 2016, 8:29373-29382.
|
Tao L, Wang Q, Dou S, et al. Edge-rich and dopant-free graphene as a highly efficient metal-free electrocatalyst for the oxygen reduction reaction[J]. Chemical Communications, 2016, 52(13):2764-2767.
|
Guo D, Shibuya R, Akiba C, et al. Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts[J]. Science, 2016, 351(6271):361-365.
|
Ito Y, Qiu H J, Fujita T, et al. Bicontinuous nanoporous N-doped graphene for the oxygen reduction reaction[J]. Advanced Materials, 2014, 26(24):4145-4150.
|
Vineesh T V, Kumar M P, Takahashi C, et al. Bifunctional electrocatalytic activity of Boron-doped graphene derived from Boron carbide[J]. Advanced Energy Materials, 2015, 5:1500658.
|
Ma Z, Dou S, Shen A, et al. Sulfur-doped graphene derived from cycled lithium-sulfur batteries as a metal-free electrocatalyst for the oxygen reduction reaction[J]. Angewandte Chemie International Edition, 2015, 54(6):1888-1892.
|
Zhang H H, Liu X Q, He G L, et al. Bioinspired synthesis of nitrogen/sulfur co-doped graphene as an efficient electrocatalyst for oxygen reduction reaction[J]. Journal of Power Sources, 2015, 279:252-258.
|
Wang L, Sofer Z, Zboril R, et al. Phosphorus and halogen Co-doped graphene materials and their electrochemistry[J]. Chemistry a European Journal, 2016, 22(43):15444-15450.
|
Dong Q, Zhuang X, Li Z, et al. Efficient approach to iron/nitrogen co-doped graphene materials as efficient electrochemical catalysts for the oxygen reduction reaction[J]. Journal of Material Chemistry A, 2015, 3(15):7767-7772.
|
Chen C, Yang X D, Zhou Z Y, et al. Aminothiazole-derived N,S,Fe-doped graphene nanosheets as high performance electrocatalysts for oxygen reduction[J]. Chemical Communications, 2015, 51(96):17092-17095.
|
Wang L, Ambrosi A, Pumera M. "Metal-free" catalytic oxygen reduction reaction on heteroatom-doped graphene is caused by trace metal impurities[J]. Angewandte Chemie International Edition, 2013, 125(51):14063-14066.
|
Liang Y, Li Y, Wang H, et al. Co3O4 nanocrystals on graphene as a synergistic catalyst for oxygen reduction reaction[J]. Nature Materials, 2011, 10:780.
|
Tian G L, Zhao M Q, Yu D, et al. Nitrogen-doped graphene/carbon nanotube hybrids:In situ formation on bifunctional catalysts and their superior electrocatalytic activity for oxygen evolution/reduction reaction[J]. Small, 2014, 10(11):2251-2259.
|
Wan H, Anders W, María E, et al. Insights in the oxygen reduction reaction:From metallic electrocatalysts to diporphyrins[J].ACS Catal, 2020, 10, 11, 5979-5989.
|