ZHAO Xue-fei, SUN Ye-xin, HAO Ce, SUN Tian-jun, CUI Ling-we, . Fabrication of carbon nanofibres and bambooshaped carbon nanotubes with open ends from anthracite coal by arc discharge. New Carbon Mater., 2009, 24(02): 109-113.
Citation:
ZHAO Xue-fei, SUN Ye-xin, HAO Ce, SUN Tian-jun, CUI Ling-we, . Fabrication of carbon nanofibres and bambooshaped carbon nanotubes with open ends from anthracite coal by arc discharge. New Carbon Mater., 2009, 24(02): 109-113.
ZHAO Xue-fei, SUN Ye-xin, HAO Ce, SUN Tian-jun, CUI Ling-we, . Fabrication of carbon nanofibres and bambooshaped carbon nanotubes with open ends from anthracite coal by arc discharge. New Carbon Mater., 2009, 24(02): 109-113.
Citation:
ZHAO Xue-fei, SUN Ye-xin, HAO Ce, SUN Tian-jun, CUI Ling-we, . Fabrication of carbon nanofibres and bambooshaped carbon nanotubes with open ends from anthracite coal by arc discharge. New Carbon Mater., 2009, 24(02): 109-113.
State Key Lab of Fine Chemicals, Carbon Research Laboratory, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China|
Funds:
The Natural Science Foundation of Liaoning Province of China (20022162), The Foundation of the Education Office of Liaoning Province of China (2004C024), The State Natural Science Foundation of China (20376011) and Program for New Century Excellent Talents in Universities of China Supported by the Education Ministry of China (NCET-04-0274).
Bamboolike carbon nanotube (BCNTs) with open ends, and carbon nanofibers (CNFs) were prepared from a coalbased carbon rod by a DC arc discharge. The coalbased carbon rod was made by carbonizing Chinese Bai-Yang-Shu anthracite with coal tar and pitch as binder . The BCNTs and CNFs were characterized by scanning and transmission electron microscopy, energy dispersive spectroscopy, and Xray diffraction. It is found that BCNTs and CNFs grow as a deposit on the anode at a low helium pressure of 0.020MPa with the coalbased carbon rod as anode. Most of the BCNTs have an open end and a diameter of 50nm. CNFs with a diameter of 30-50nm form fluffy balls on the surface of the remaining anode.