ZHANG Zhi-yi, ZHANG Huang, SHOU Jin-quan, SUN You-yi, LIU Ya-qing. Preparation of reduced graphene oxide-reinforced epoxy resin composites and their shape memory properties. New Carbon Mater., 2015, 30(5): 404-411.
Citation: ZHANG Zhi-yi, ZHANG Huang, SHOU Jin-quan, SUN You-yi, LIU Ya-qing. Preparation of reduced graphene oxide-reinforced epoxy resin composites and their shape memory properties. New Carbon Mater., 2015, 30(5): 404-411.

Preparation of reduced graphene oxide-reinforced epoxy resin composites and their shape memory properties

Funds:  National Natural Science Foundation of China(11202006).
  • Received Date: 2015-04-21
  • Accepted Date: 2015-11-10
  • Rev Recd Date: 2015-08-03
  • Publish Date: 2015-10-28
  • Novel shape memory composites based on reduced graphene oxide (rGO)-reinforced epoxy resin (EP) composites were prepared by a solution mixing and solvothermal reduction method. The effect of rGO content on the mechanical and shape memory properties of the rGO/EP composites was investigated. Results showed that the GO uniformly dispersed in the EP matrix was reduced in-situ to rGO by the solvothermal reduction. The composite had the maximum tensile strength and modulus when the mass fraction of rGO was 0.2%. When the mass fraction of rGO was 0.6%, the glass transition temperature (Tg) of the composite was 102℃, 45℃ higher than that of pure EP, and the corresponding composite has a good shape memory property with its deformation fully recovered.
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  • Tang Z H , Sun D Q, Yang D, et al. Vapor grown carbon nanofiber reinforced bio-based polyester for electroactive shape memory performance[J]. Compos Sci Technol, 2013, 75:15-21.
    Qi G, Kristofer K Westbrook, Patrick T Mather, et al. Thermomechanical behavior of a two-way shape memory composite actuator[J]. Smart Mater Struct, 2013, 22:055009-055019.
    Marc Behl, Karl Kratz, Jorg Zotzmann, et al. Reversible bidirectional shape-memory polymers[J]. Adv Mater, 2013, 25:4466-4469.
    Pandini S, Baldi F, Paderni K, et al. One-way and two-way shape memory behaviour of semi-crystalline networks based on sole gel cross-linked poly(ε-caprolactone)[J]. Polymer, 2013, 54:4253-4265.
    Richard M Baker, James H Henderson, Patrick T Mather. Shape memory poly(3-caprolactone)-co-poly(ethylene glycol) foams with body temperature triggering and two-way actuation[J]. J Mater Chem B, 2013, 1:4916-4920.
    Chen S J, Hu J L, Zhuo H T. Properties and mechanism of two-way shape memory polyurethane composites[J]. Compos Sci Technol, 2010, 70:1437-1443.
    K S Santhosh Kumar, R Biju, C P Reghunadhan Nair. Progress in shape memory epoxy resins[J]. React Funct Polym, 2013, 73:421-430.
    Lu H B, Huang W M. Synergistic effect of self-assembled carboxylic acid-functionalized carbon nanotubes and carbon fiber for improved electro-activated polymeric shape-memory nanocomposite[J]. Appl Phys Lett, 2013, 102:231910.
    Lu H B, Liang F, Gou J H. Nanopaper enabled shape-memory nanocomposite with vertically aligned nickel nanostrand:controlled synthesis and electrical actuation[J]. Soft Matter, 2011, 7:7416-7423.
    Dorigato A, Giusti G, Bondioli F, et al. Electrically conductive epoxy nanocomposites containing carbonaceous fillers and in-situ generated silver nanoparticles[J]. Express Polym lett, 2013, 7:673-682.
    Kai Y, Amber J, Gyaneshwar P Tandon, et al. A thermomechanical constitutive model for an epoxy based shape memory polymer and its parameter identifications[J]. Mech Time-Depend Mat, 2014, 18:453-474.
    Liu K H, Chen S L, Luo Y F, et al. Edge-functionalized graphene as reinforcement of epoxy-based conductive composite for electrical interconnects[J]. Compos Sci and Technol, 2013, 88:84-91.
    Qian X D, Song L, Yu B, et al. Novel organic-inorganic flame retardants containing exfoliated graphene:Preparation and their performance on the flame retardancy of epoxy resins[J]. J Mater Chem A, 2013, 1:6822-6830.
    Chatterjee S, Wang J W,Kuo W S, et al. Mechanical reinforcement and thermal conductivity in expanded graphene nanoplatelets reinforced epoxy composites[J]. Chem Phys Lett, 2012, 531:6-10.
    Wang X,Xing W, Zhang P, et al. Covalent functionalization of graphene with organosilane and its use as a reinforcement in epoxy composites[J]. Compos Sci Technol, 2012, 72:737-743.
    Prolongo S G, Jimenez-Suarez A, Moriche R, et al. In situ processing of epoxy composites reinforced with graphene nanoplatelets[J]. Compos Sci Technol, 2013, 86:185-191.
    Shen X J , Liu Y , Xiao H M, et al. The reinforcing effect of graphene nanosheets on the cryogenic mechanical properties of epoxy resins[J]. Compos Sci Technol, 2012, 72:1581-1587.
    Li Z H. A program for SAXS data processing and analysis[J]. Chinese Physics C, 2013, 37(10):108002.
    Ahmed S Wajid, Tanvir Ahmed H S, Sriya Das, et al. High-performance pristine graphene/epoxy composites with enhanced mechanical and electrical properties[J]. Macromol Mater Eng, 2013, 298:339-347.
    Zhang Y G, Chi H J, Zhang W H, et al. Highly efficient adsorption of copper ions by a PVP-reduced graphene oxide based on a new adsorptions mechanism[J]. Nano-Micro Lett, 2014, 6:80-87.
    Zhou D, Cheng Q, Han B. Solvothermal synthesis of homogeneous graphene dispersion with high concentration[J]. Carbon, 2011, 49:3920-3927.
    He Y Q, Liu Y, Wu T, et al. An environmentally friendly method for the fabrication of reduced graphene oxide foam with a super oil absorption capacity[J]. J Hazard Mater, 2013, 260:796-805.
    Mohan Raja, A M Shanmugharaj, Sung Hun Ryu, et al. Influence of metal nanoparticle decorated CNTs on polyurethane based electro active shape memory nanocomposite actuators[J]. Mater Chem Phys, 2011, 129:925-931.
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