Electrochemical performance of a porous graphitic carbon-based supercapacitor in three different electrolytes

YE Ling; HUANG Zheng-hong; SHEN Wan-ci; LU Rui-tao; KANG Fei-yu; YANG Quan-hong

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Article Navigation > New Carbon Mater. > 2018 > 33(1): 53-60

YE Ling, HUANG Zheng-hong, SHEN Wan-ci, LU Rui-tao, KANG Fei-yu, YANG Quan-hong. Electrochemical performance of a porous graphitic carbon-based supercapacitor in three different electrolytes. New Carbon Mater., 2018, 33(1): 53-60.

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Electrochemical performance of a porous graphitic carbon-based supercapacitor in three different electrolytes

1.
State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University, Beijing 100084, China;
2.
Engineering Laboratory for Functionalized Carbon Materials, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China;
3.
Key Laboratory of Advanced Materials of Ministry of Education of China, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China;
4.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China

Funds: National Key Basic Research Program of China (2014CB932400);National Science Foundation of China (51672151);Shenzhen Basic Research Project (JCYJ20150529164918734, JCYJ20170412171630020).

Received Date: 2017-08-25
Accepted Date: 2018-02-11
Rev Recd Date: 2017-12-15
Publish Date: 2018-02-28

Abstract

Abstract

A porous graphitic carbon (PGC) was prepared by the one-step activation and graphitization of mesocarbon microbeads using NaOH and FeCl₃ as the activation reagent and graphitization catalyst, respectively. All supercapacitors constructed from the PGC using 1 M LiPF₆/EC:DEC (v/v=1), 1 M Et₄NBF₄/PC and 1 M[BMIM]BF₄/AN as the electrolytes show good electrochemical properties, with the optimum electrolyte being Et₄NBF₄/PC.
- Porous graphitic carbon,
- Supercapacitor,
- Catalytic graphitization,
- Electrolyte

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References(27)

References

刘希邈, 詹亮, 滕娜, 等. 超级电容器用沥青焦基活性炭的制备及其电化学性能[J]. 新型炭材料, 2006, 21(1):48-53. (Liu X, Zhan L, Ten N, et al. Preparation of electrochemical performance of petroleum coke based superactivated carbons for supercapacitors[J]. New Carbon Materials, 2006, 21(1):48-53.)

Li Z, Wu D, Huang X, et al. Fabrication of novel polymeric and carbonaceous nanoscale networks by the union of self-assembly and hypercrosslinking[J]. Energy & Environmental Science, 2014, 7:3006-3012.

Li Z, Wu D, Liang Y, et al. Synthesis of well-defined microporous carbons by molecular-scale templating with polyhedral oligomeric silsesquioxane moieties[J]. Journal of the American Chemical Society, 2014,136:4805-4808.

Xu F, Tang Z, Huang S, et al. Facile synthesis of ultrahigh-surface-area hollow carbon nanospheres for enhanced adsorption and energy storage[J]. Nature communications, 2015, 6.

Wu D, Li Z, Zhong M, et al. Templated synthesis of nitrogen-enriched nanoporous carbon materials from porogenic organic precursors prepared by aTRP[J]. Angewandte Chemie International Edition, 2014, 53(15):3957-3960.

Negre L, Daffos B, Turq V, et al. Ionogel-based solid-state supercapacitor operating over a wide range of temperature[J]. Electrochimica Acta, 2016.

Xu X, Liu Y, Wang M, et al. Hierarchical hybrids with microporous carbon spheres decorated three-dimensional graphene frameworks for capacitive applications in supercapacitor and deionization[J]. Electrochimica Acta, 2016, 193:88-95.

周鹏伟, 李宝华, 康飞宇, 等.椰壳活性炭基超级电容器的研制与开发[J]. 新型炭材料, 2006, 21(2):125-130. (Zhou P, Li B, Kang F, et al. The development of supercapacitors from coconut-shell activated carbon[J]. New Carbon Materials, 2016, 21(2):125-130.)

Zhang J, Lv W, Tao Y, et al. Ultrafast high-volumetric sodium storage of folded-graphene electrodes through surface-induced redox reactions[J]. Energy Storage Materials, 2015, 1:112-118.

曲江英, 李雨佳, 李传鹏, 等. 还原氧化石墨烯Mn₃O₄纳米复合材料的合成及其在超级电容器中的应用[J]. 新型炭材料, 2014, 29(3):186-192. (Qu J, Li Y, Li C, et al. Synthesis of reduced graphene oxide/Mn₃O₄ nanocomposites for supercapacitors[J]. New Carbon Materials, 2014, 29(3):186-192.)

Wang J, Kaskel S. KOH activation of carbon-based materials for energy storage[J]. Journal of Materials Chemistry, 2012, 22(45):23710-23725.

Yuan C, Gao B, Shen L, et al. Hierarchically structured carbon-based composites:design, synthesis and their application in electrochemical capacitors[J]. Nanoscale, 2011, 3(2):529-545.

Liang Q, Ye L, Huang Z, et al. A honeycomb-like porous carbon derived from pomelo peel for use in high-performance supercapacitors[J]. Nanoscale, 2014, 6:13831-13837.

Zhu Y, Hu H, Li W, et al. Resorcinol-formaldehyde based porous carbon as an electrode material for supercapacitors[J]. Carbon, 2007, 45(1):160-165.

Lv Y, Zhang F, Dou Y, et al. A comprehensive study on KOH activation of ordered mesoporous carbons and their supercapacitor application[J]. Journal of Materials Chemistry. 2012, 22(1):93-9

Franklin R E. Homogeneous and heterogeneous graphitization of carbon[J]. Nature, 1956, 177:238-239.

ōya A, Marsh H. Phenomena of catalytic graphitization[J]. Journal of Materials Science, 1982, 17(2):309-322.

Franklin R E. Crystallite growth in graphitizing and non-graphitizing carbons[J]. Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1951, 209(1097):196-218.

Qian W, Sun F, Xu Y, et al. Human hair-derived carbon flakes for electrochemical supercapacitors[J]. Energy & Environmental Science, 2014, 7(1):379-386.

Zhang J, Lv W, Zheng D, et al. The Interplay of oxygen functional groups and folded texture in densified graphene electrodes for compact sodium-Ion capacitors[J]. Advanced Energy Materials, 2018, 1702395.

Tao Y, Xie X, Lv W, et al. Towards ultrahigh volumetric capacitance:graphene derived highly dense but porous carbons for supercapacitors[J]. Scientific Reports, 2013, 3:2975.

Béguin F, Presser V, Balducci A, et al. Carbons and electrolytes for advanced supercapacitors[J]. Advanced Materials, 2014, 26(14):2219-2251.

Li H, Tao Y, Zheng X, et al. Ultra-thick graphene bulk supercapacitor electrodes for compact energy storage[J]. Energy & Environmental Science, 2016, 9(10):3135-3142.

Xu Y, Tao Y, Zheng X, et al. A metal-free supercapacitor electrode material with a record high volumetric capacitance over 800 F cm^-3[J]. Advanced Materials, 2015, 27(48):8082-8087.

Xu Y, Tao Y, Li H, et al. Dual electronic-ionic conductivity of pseudo-capacitive filler enables high volumetric capacitance from dense graphene micro-particles[J]. Nano Energy, 2017, 36:349-355.

Lei Y, Huang Z, Yang Y, et al. Porous mesocarbon microbeads with graphitic shells:constructing a high-rate, high-capacity cathode for hybrid supercapacitor[J]. Scientific Reports, 2013, 3.

Ye L, Liang Q, Huang Z H, et al. A supercapacitor constructed with a partially graphitized porous carbon and its performance over a wide working temperature range[J]. Journal of Materials Chemistry A, 2015, 3(37):18860-18866.

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