Preparation and microwave absorption properties of magnetic carbon nano-onion matrix composites

DENG Chuan; ZHANG Wei-ke; YANG Yan-qing; GAO Ze-yu; Wang Jia-wei; WEI Xian-xian

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Article Navigation > New Carbon Mater. > 2019 > 34(2): 170-180

DENG Chuan, ZHANG Wei-ke, YANG Yan-qing, GAO Ze-yu, Wang Jia-wei, WEI Xian-xian. Preparation and microwave absorption properties of magnetic carbon nano-onion matrix composites. New Carbon Mater., 2019, 34(2): 170-180.

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Preparation and microwave absorption properties of magnetic carbon nano-onion matrix composites

1.
College of Environmental Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China;
2.
College of Environmental Science and Safety, Taiyuan University of Science and Technology, Taiyuan 030024, China

Funds: The 59th batch of Open Category China Postdoctoral Funds (2016M592654); Scientific Research Foundation for Young Scientists of Shanxi Province (201601D021134); The Key Research and Development Projects of Shanxi Province(201803D31049).

Received Date: 2019-01-30
Accepted Date: 2019-04-30
Rev Recd Date: 2019-04-02
Publish Date: 2019-04-28

Abstract

Abstract

Magnetic carbon nano-onions (MCNOs) and multi-wall carbon nanotubes (MWCNTs) were prepared by chemical vapor deposition using a stainless steel mesh as the substrate and a sol-gel derived LaFeO₃ as the catalyst. They were dispersed in water with a mass ratio of 1:1, and spray-dried with the assistance of ultrasonication to form hybrid granules. The morphology and magnetic permeability of the granules were investigated by XRD, SEM, TEM, Raman spectroscopy and a vibrating sample magnetometer. The granules were coated on a glass plate to evaluate their microwave absorption properties with a microwave vector network analyzer. Results showed that the absorption ability of the hybrid granule coatings was significantly improved in the frequency range 2-18 GHz compared with MCNOs or MWCNTs alone under the same conditions. With an increase of the coating thickness, the maximum absorption peak shifts to a lower frequency. The coating shows the best absorption properties when the thickness is 3.5 mm, where the maximum peak value reaches -25.6 dB and the effective bandwidth of less than -10 dB reaches 2.2 GHz.
- Carbon nano-onions,
- Multiwalled carbon nanotubes,
- Carbon-carbon composite absorbing materials,
- Absorption properties,
- Electromagnetic parameters

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