Preparation and characterization of spinnable mesophase pitches: A review

SHI Jing-li; MA Chang

Article Contents

Article Navigation > New Carbon Mater. > 2019 > 34(3): 211-219

SHI Jing-li, MA Chang. Preparation and characterization of spinnable mesophase pitches: A review. New Carbon Mater., 2019, 34(3): 211-219.

Citation:

SHI Jing-li, MA Chang. Preparation and characterization of spinnable mesophase pitches: A review. New Carbon Mater., 2019, 34(3): 211-219.

SHI Jing-li, MA Chang. Preparation and characterization of spinnable mesophase pitches: A review. New Carbon Mater., 2019, 34(3): 211-219.

Citation:

SHI Jing-li, MA Chang. Preparation and characterization of spinnable mesophase pitches: A review. New Carbon Mater., 2019, 34(3): 211-219.

PDF( 2298 KB)

Preparation and characterization of spinnable mesophase pitches: A review

Tianjin Municipal Key Lab of Advanced Fiber and Energy Storage Technology, Tianjin Polytechnic University, Tianjin 300387, China

Received Date: 2019-03-06
Accepted Date: 2019-06-27
Rev Recd Date: 2019-05-30
Publish Date: 2019-06-28

Abstract

Abstract

Mesophase pitch-based carbon fibers have a higher modulus and thermal conductivity than other carbon fibers. A good spinnable mesophase pitch is key to prepare high performance carbon fibers. In this paper, the preparation and characterization of mesophase pitches are reviewed. Spinnable mesophase pitches have been prepared from petroleum pitch or coal tar pitch by heat and catalytic polycondensation. Sometimes, hydrogenation, catalytic polymerization and co-carbonization were used to modify the chemical structure of the pitch before polycondensation. Traditional characterization of mesophase pitch include the softening point, rheology properties, optical anisotropy, average molecule weight and chemical structure. With the rapid progress of characterization techniques, other characterization of the microstructure is possible, such as high resolution MALDI ToF MS which gives the elemental formula of thousands of molecular constituents, which helps improve our understanding of the molecular structure of spinnable mesophase pitches.
- Preparation,
- Spinning mesophase pitch,
- Characterization

FullText(HTML)

References(48)

References

Otani S. On the carbon fiber from the molten pyrolysis products[J]. Carbon, 1965, 3(1):31-38.

Tailor G H. Development of optical properties of coke during carbonization[J]. Fuel, 1961, 40:465-472.

Brooks J D, Tailor G H. The formation of graphitizing carbons from the liquid phase[J]. Carbon, 1965, 3(2):185-193.

White J L. In Petroleum-Derived Carbons[C]. Bacha J, et al. ACS Symposium Series, 1986, 303:62-65.

Otani S, Okubo K, Koitabashi T. The preparation of highly-oriented carbon fiber from pitch material[J]. Bulletin of the Chemical Society of Japan, 1970, 43:3291-3291.

角田三尚. 沥青基炭纤维的最近动向[J]. 新型炭材料, 1988, 12(2):23-29. (Tunoda Mi. Recent tendency of pitch based carbon fiber[J]. New Carbon Materials. 1988, 12(2):23-29.)

Singer L. High modulus high strength fibers produced from mesophase pitch[P]. US4005183, 1977.

Singer L. The mesophase and high modulus carbon fibers from pitch[J]. Carbon, 1978, 16(6):409-415.

Chwastiak S. Low molecular weight mesophase pitch[P]. GB2005298A, 1978.

Lewis I, Mchenry R, Singer L. Process for produce mesophase pitch[P]. US4017327, 1977.

Rhee B, Ryu S, Jung D, et al. Preparation of spinnable mesophase pitch by two stage-heat treatment from coal tar pitch[C]. Extended abstracts of the 19th biennial conference on Carbon, 1989:212-213.

Park Y, Korai Y, Mochida I. Preparation of anisotropic mesophase pitch by carbonization under vacuum[J]. Journal of Materials Science, 1986, 21(2):424-428.

Park Y D, Mochida I. A two-stage preparation of mesophase pitch from the vacuum residue of FCC decant oil[J]. Carbon, 1989, 27(6):925929.

Summer M B. Thermal properties of heavy isotropic petroleum pitches[C]. Preceedings of the International Carbon Conference, 1988, 52-54.

Diefendorf R J, Park C, Riggs M, et al. Forming optically anisotropic pitches[P]. US4208267, 1980.

Hutchenson K W, Roebers J R, Thies M C. Fractionation of petroleum pitch by supercritical fluid extraction[J]. Carbon, 1991, 29(2):215-233.

Mochida I, Korai Y, Ku C H, et al. Chemistry of synthesis, structure, preparation and application of aromatic-derived mesophase pitch[J]. Carbon, 2000, 38(2):305-328.

Otani S. Dormant mesophase pitch[P]. US4472265A, 1984.

Yamada Y, Matsumoto S, Fukuda K, et al. Optically anisotropic texture in, tetrhydroquinoline soluble matter of carbonaceous mesophase[J]. Tanso, 1981,107:144-146.

Otani S,Oya A, Bacha J, et al. In petroleum-derived carbons[C]. ACS Symposium Series, 1986, 303:323-334.

Honda H. Advanced coal liquefaction and pitch-based carbon fiber[J]. Tanso, 1983, 113:66-78.

Mochida I, Sone Y, Korai Y. Preparation and properties of carbonaceous mesophaseⅡ:Highly soluble mesophase from ethylene tar modified using aluminum chloride as a catalyst[J]. Carbon, 1985, 23(2):175-178.

魏锋,刘朗,王茂章,等. 轻柴油重组分AlCl₃催化改性产物的中间相转化行为[J]. 石油学报(石油加工), 1989, 4:1-8. (WEI F, LIU L,WANG M. et al. Mesophase formation for aluminium chloride-modified pitches from heavy fraction of light diesel fuel oil[J]. Acta Petrolei Sinica (Petroleum Processing Section), 1989, 4:1-8.)

王成扬,郭崇涛. 纺丝用中间相沥青的有效制备途径[J]. 碳素,1987, 1:10-17. (WANG C, GUO C. Effective ways to prepare spinning mesophase pitches[J]. Carbon, 1987, 1:10-17.)

Mochida I, Kudo K, Fukuda N, et al. Carbonization of pitches-IV:Carbonization of polycyclic aromatic hydrocarbons under the presence of aluminum chloride catalyst[J]. Carbon, 1975, 13(2):135-139.

Mochida I, Shimizu K, Korai Y, et al. Structure and carbonization properties of pitches produced catalytically from aromatic hydrocarbons with HF/BF₃[J]. Carbon, 1988, 26(6):843-852.

Mochida I, Shimizu K, Korai Y, et al. Preparation of mesophase pitch from aromatic hydrocarbons by the aid of HF/BF₃[J]. Carbon, 1990, 28(2-3):311-319.

胡子君,凌立成,刘朗. 固体超强酸对萘的低温齐聚反应的催化效应的研究[J]. 炭素技术, 1995, 3:5-9. (HU Z, LING L, LIU L. Study on catalytical effect of solid for naphthalene oligomerization reaction[J]. Carbon Techniques, 1995, 3:5-9.)

宋怀河,刘朗. 沥青-重油共炭化反应机理的研究Ⅰ:原料沥青和共炭化沥青的结构[J]. 燃料化学学报, 1994, 2:157-163. (SONG H, LIU L. Study on the mechanism of co-carbonization of pitch-heavy oil blend Ⅰ. Structure analysis of raw pitch and co-carbonization pitch[J]. Journal of Fuel Chemistry and Technology, 1994, 2:157-163.)

Mochida I, Korai Y, Fujitsu H, et al. Modifying ability of QI-free coat-tar pitch to develop optical anisotropy in co-carbonizations[J]. Fuel, 1981, 60(5):405-412.

Li M, Liu D, Men Z, et al. Effects of different extracted components from petroleum pitch on mesophase development[J]. Fuel, 2018, 222(15):617-626.

Chen L, Fei Y, Fan X, et al. Coalescence of mesophase spheres and microstructures of graphitic carbon revealed by scanning electron microscopy[J]. Journal Materials Science, 2017, 52:12663-12676.

刘银全,王秀娥,李安邦,等. 针入法沥青软化点和可纺性的简单测定[J]. 新型炭材料, 1994, 9(3):30-31. (LIU Y, WANG X, LI A, et al. Simple test of soft point and spinnability of pitch by needling method[J]. New Carbon Materials, 1994, 9(3):30-31.

Boenigk W, Haenel M, Zander M. Structural features and mesophase formation of coal-tar pitch fractions obtained by preparative size exclusion chromatography[J]. Fuel, 1990, 69(10):1226-1232.

Reggle L, Friedel R, Wender I. Lithium in ethylenediamine:A new reducing system for organic compounds[J]. Journal of Organic Chemistry, 1957, 22(8):891-894.

Qian S, Xiao Y, Gu Y. Study on chemical composition and formation mechanism of some typical pitch feedstocks using field desorption mass spectrometry[J]. Fuel, 1987, 66(2):242-249.

Zhang W, Andersson J, Räder H, Müllena K. Molecular characterization of large polycyclic aromatic hydrocarbons in solid petroleum pitch and coal tar pitch by high resolution MALDI ToF MS and insights from ion mobility separation[J]. Carbon, 2015, 95:672-680.

Zimmer J, White J. Disclination Structures in the Carbonaceous Mesophase[M]. Advances in Liquid Crystals, Elsevier 1982, 157-213.

White J, Guthrie G, Gardner J. Mesophase microstructures in carbonized coal tar pitch[J]. Carbon, 1967, 5(5):517-518.

Fitzer E, Kompalik D, Yudatet K. Rheological characteristics of coal-tar pitches[J]. Fuel, 1987, 66(11):1504-1510.

Nazem F. Flow of molten mesophase pitch[J]. Carbon, 1982, 20(4):345-354.

Cheung T, Turpin M, Rand B. Controlled stress, oscillatory rheometry of mesophase-pitches[J]. Carbon, 1995, 33(12):1673-1679.

Edie D. Pitch and Mesophase Fibers[M]. Dordrecht:Kluwer Academic Publisher, 1990:43-72.

Endo M. Structures of mesophase pitch-based carbon fibers[J]. Journal of materials Science, 1988, 23(2):598-605.

刘均庆. 中间相沥青炭纤维径向结构研究及其应用[D]. 山西煤炭化学研究所,2012. (Liu J. Study of cross-section structures of mesophase pitch based carbon fiber and its application[D]. Shanxi Institute of Coal Chemistry, 2012.)

史景利, 刘朗, 查庆芳. 沥青流变性质的研究方法[J]. 炭素技术, 1996, 3:18-23. (Shi J, Liu L, Zha Q. methods of rheological measurement of pitch[J]. Carbon Techniques, 1996, 3:18-23.)

王成扬,郑嘉明,阮湘泉,等. 中间相沥青质量的综合评判分析[J]. 炭素, 1997, 1:14-16. (Wang C, Zheng J, Ruan X, et al. Synthetic evalution and analyzing to the quality of mesophase pitch[J]. Carbon, 1997, 1:14-16.

刘均庆,宫晓颐,郑冬芳,等. 煤直接液化残渣制备中间相沥青炭纤维[J]. 功能材料, 2015增刊Ⅱ, (46):176-180. (Liu J, Gong X, Zheng D, et al. Mesophase pitch based carbon fiber prepared from direct coal liquefaction residue[J]. Journal of Functional Materials, Supplement Ⅱ, 2015, (46):176-180.

Relative Articles

Supplements(0)

Cited By

Proportional views