MENG Liang, SUN Yang, GONG Han, WANG Ping, QIAO Wei-chuan, GAN Lu, XU Li-jie. Research progress of the application of graphene-based materials in the treatment of water pollutants. New Carbon Mater., 2019, 34(3): 220-237.
Citation: MENG Liang, SUN Yang, GONG Han, WANG Ping, QIAO Wei-chuan, GAN Lu, XU Li-jie. Research progress of the application of graphene-based materials in the treatment of water pollutants. New Carbon Mater., 2019, 34(3): 220-237.

Research progress of the application of graphene-based materials in the treatment of water pollutants

Funds:  Natural Science Foundation of Jiangsu Province (BK20160936); National Natural Science Foundation of China (51708297); Natural Science Foundation of Jiangsu Province (BK20160938); Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).
  • Received Date: 2019-04-05
  • Accepted Date: 2019-06-27
  • Rev Recd Date: 2019-06-03
  • Publish Date: 2019-06-28
  • Graphene-based nanomaterials have attracted increasing attention in different areas, such as material science, chemical engineering and environmental science. In recent years, it and its derivatives (e.g. graphene oxide, reduced graphene oxide) have been considered promising functional materials in water pollution control because of their many unique properties. Recent intense research on the development of graphene-based composite materials has expanded their application to water treatment. Progress in the use of graphene, graphene oxide and graphene-based composite materials in water pollutant treatment is reviewed, including their use as adsorbents, photocatalysts, and the oxidant and oxidant (e.g. H2O2, peroxymonosulfate) activators in electrocatalysis. Water pollutants are heavy metal ions, dyestuffs, some inorganic nutrients and the emerging environmental pollutants. Not only are the mechanisms of the use of graphene and its derivatives in different treatment processes considered, but the effects of important factors on the removal efficiency of pollutants are analyzed, such as environmental factors (e.g. pH, pollutant concentration), the properties of the materials (e.g. particle size, surface charge) and the concentration and morphology of the material. Current problems of using graphene-based composite materials in water treatment are summarized and future research directions are proposed.
  • loading
  • Hanif S, Shahzad A. Removal of chromium(VI) and dye Alizarin Red S (ARS) using polymer-coated iron oxide (Fe3O4) magnetic nanoparticles by co-precipitation method[J]. Journal of Nanoparticle Research, 2014, 16(6).
    Novoselov K S, Geim A K, Morozov S V, et al. Electric field effect in atomically thin carbon films[J]. Science, 2004, 306(5696):666-669.
    Georgakilas V, Otyepka M, Bourlinos A B, et al. Functionalization of graphene:Covalent and non-covalent approaches, derivatives and applications[J]. Chemical Reviews, 2012, 112(11):6156-6214.
    Novoselov K S, Fal'ko V I, Colombo L, et al. A roadmap for graphene[J]. Nature, 2012, 490(7419):192-200.
    Li Y M, Ye H Q, Chen J H, et al. Flexible beta-Ni(OH)2/graphene electrode with high areal capacitance enhanced by conductive interconnection[J]. Journal of Alloys and Compounds, 2018, 737:731-739.
    Liu Y J, Xiao J J, Qiao L, et al. Amphiphilic mesoporous graphene mediated efficient photoionic cell[J]. Carbon, 2018, 128:134-137.
    Cho M J, Park H G, Jeong H C, et al. Superior fast switching of liquid crystal devices using graphene quantum dots[J]. Liquid Crystals, 2014, 41(6):761-767.
    Rashidiani J, Kamali M, Sedighian H, et al. Ultrahigh sensitive enhanced-electrochemiluminescence detection of cancer biomarkers using silica NPs/graphene oxide:A comparative study[J]. Biosensors & Bioelectronics, 2018, 102:226-233.
    Yang X Y, Mo Q J, Guo Y L, et al. Reduced-graphene-oxide supported tantalum-based electrocatalysts:Controlled nitrogen doping and oxygen reduction reaction[J]. Applied Surface Science, 2018, 434:243-250.
    唐朝春, 段先月, 叶鑫, 等. 石墨烯的制备及其在水处理中的应用研究进展[J]. 工业水处理, 2017, (03):10-15. (TANG Chao-Chun, DUAN Xian-yue, YE Xin, et al. Research progress in the preparation of graphene and its applicationto water treatment[J]. Industrial Water Treatment, 2017, 37(03):10-15.)
    Tang J, Huang Y, Gong Y, et al. Preparation of a novel graphene oxide/Fe-Mn composite and its application for aqueous Hg(Ⅱ) removal[J]. Journal of Hazardous Materials, 2016, 316:151-158.
    Shen Y, Chen B. Sulfonated graphene nanosheets as a superb adsorbent for various environmental pollutants in water[J]. Environmental Science & Technology, 2015, 49(12):7364-7372.
    Shen Y, Fang Q, Chen B. Environmental applications of three-dimensional graphene-based macrostructures:adsorption, transformation, and detection[J]. Environmental Science & Technology, 2015, 49(1):67-84.
    Zhang H, Lv X, Li Y, et al. P25-graphene composite as a high performance photocatalyst[J]. ACS Nano, 2010, 4(1):380-386.
    Huang C, Li C, Shi G. Graphene based catalysts[J]. Energy & Environmental Science, 2012, 5(10):8848.
    Yue Y, Wang X, Han J, et al. Effects of nanocellulose on sodium alginate/polyacrylamide hydrogel:Mechanical properties and adsorption-desorption capacities[J]. Carbohydrate Polymers, 2019, 206:289-301.
    Liu G, Lin S, Pile L S, et al. Effect of potassium permanganate and pyrolysis temperature on the biochar produced from rice straw and suitability of biochars for heavy metal (Cd & Pb) immobilization in paper sludge[J]. Fresenius Environmental Bulletin, 2018, 27(12A):9008-9018.
    Du Q, Sun J, Li Y, et al. Highly enhanced adsorption of congo red onto graphene oxide/chitosan fibers by wet-chemical etching off silica nanoparticles[J]. Chemical Engineering Journal, 2014, 245:99-106.
    Zhao D L, Zhang Q, Xuan H, et al. EDTA functionalized Fe3O4/graphene oxide for efficient removal of U(VI) from aqueous solutions[J]. Journal of Colloid and Interface Science, 2017, 506:300-307.
    Cheng W C, Ding C C, Nie X Q, et al. Fabrication of 3D macroscopic graphene oxide composites supported by montmorillonite for Efficient U(VI) wastewater purification[J]. Acs Sustainable Chemistry & Engineering, 2017, 5(6):5503-5511.
    Li X H, Wang Z, Li Q, et al. Preparation, characterization, and application of mesoporous silica-grafted graphene oxide for highly selective lead adsorption[J]. Chemical Engineering Journal, 2015, 273:630-637.
    Cui L, Wang Y, Gao L, et al. EDTA functionalized magnetic graphene oxide for removal of Pb(Ⅱ), Hg(Ⅱ) and Cu(Ⅱ) in water treatment:Adsorption mechanism and separation property[J]. Chemical Engineering Journal, 2015, 281:1-10.
    Nodeh H R, Ibrahim W a W, Ali I, et al. Development of magnetic graphene oxide adsorbent for the removal and preconcentration of As(Ⅲ) and As(V) species from environmental water samples[J]. Environmental Science and Pollution Research, 2016, 23(10):9759-9773.
    Zhou G Y, Liu C B, Tang Y H, et al. Sponge-like polysiloxane-graphene oxide gel as a highly efficient and renewable adsorbent for lead and cadmium metals removal from wastewater[J]. Chemical Engineering Journal, 2015, 280:275-282.
    Fei P, Wang Q, Zhong M, et al. Preparation and adsorption properties of enhanced magnetic zinc ferrite-reduced graphene oxide nanocomposites via a facile one-pot solvothermal method[J]. Journal of Alloys and Compounds, 2016, 685:411-417.
    Liu J, Wang L, Tang J, et al. Photocatalytic degradation of commercially sourced naphthenic acids by TiO2-graphene composite nanomaterial[J]. Chemosphere, 2016, 149:328-335.
    Wu Z, Zhang L, Guan Q, et al. Preparation of alpha-zirconium phosphate-pillared reduced graphene oxide with increased adsorption towards methylene blue[J]. Chemical Engineering Journal, 2014, 258:77-84.
    Yamaguchi N U, Bergamasco R, Hamoudi S. Magnetic MnFe2O4-graphene hybrid composite for efficient removal of glyphosate from water[J]. Chemical Engineering Journal, 2016, 295:391-402.
    Sun R, Zhang H B, Qu J, et al. Supercritical carbon dioxide fluid assisted synthesis of hierarchical AlOOH@reduced graphene oxide hybrids for efficient removal of fluoride ions[J]. Chemical Engineering Journal, 2016, 292:174-182.
    Dreyer D R, Todd A D, Bielawski C W. Harnessing the chemistry of graphene oxide[J]. Chemical Society Reviews, 2014, 43(15):5288-5301.
    Dong S, Sun Y, Wu J, et al. Graphene oxide as filter media to remove levofloxacin and lead from aqueous solution[J]. Chemosphere, 2016, 150:759-764.
    Tan P, Sun J, Hu Y Y, et al. Adsorption of Cu2+, Cd2+ and Ni2+ from aqueous single metal solutions on graphene oxide membranes[J]. Journal of Hazardous Materials, 2015, 297:251-260.
    Wang X, Fan Q, Yu S, et al. High sorption of U(VI) on graphene oxides studied by batch experimental and theoretical calculations[J]. Chemical Engineering Journal, 2016, 287:448-455.
    Madadrang C J, Kim H Y, Gao G, et al. Adsorption behavior of EDTA-graphene oxide for Pb (Ⅱ) Removal[J]. Acs Applied Materials & Interfaces, 2012, 4(3):1186-1193.
    Qin Q, Wang Q, Fu D, et al. An efficient approach for Pb(Ⅱ) and Cd(Ⅱ) removal using manganese dioxide formed in situ[J]. Chemical Engineering Journal, 2011, 172(1):68-74.
    Wan S, He F, Wu J, et al. Rapid and highly selective removal of lead from water using graphene oxide-hydrated manganese oxide nanocomposites[J]. Journal of Hazardous Materials, 2016, 314:32-40.
    Yang L, Hu J, Wu W, et al. In situ NH2-functionalized graphene oxide/SiO2 composites to improve Cu(Ⅱ) removal from ammoniacal solutions[J]. Chemical Engineering Journal, 2016, 306:77-85.
    Yoon Y, Park W K, Hwang T M, et al. Comparative evaluation of magnetite-graphene oxide and magnetite-reduced graphene oxide composite for As(Ⅲ) and As(V) removal[J]. Journal of Hazardous Materials, 2016, 304:196-204.
    Robati D, Mirza B, Rajabi M, et al. Removal of hazardous dyes-BR 12 and methyl orange using graphene oxide as an adsorbent from aqueous phase[J]. Chemical Engineering Journal, 2016, 284:687-697.
    Dutta D, Thiyagarajan S, Bahadur D. SnO2 quantum dots decorated reduced graphene oxide nanocomposites for efficient water remediation[J]. Chemical Engineering Journal, 2016, 297:55-65.
    Yan H, Yang H, Li A, et al. pH-tunable surface charge of chitosan/graphene oxide composite adsorbent for efficient removal of multiple pollutants from water[J]. Chemical Engineering Journal, 2016, 284:1397-1405.
    Ruan X, Chen Y, Chen H, et al. Sorption behavior of methyl orange from aqueous solution on organic matter and reduced graphene oxides modified Ni-Cr layered double hydroxides[J]. Chemical Engineering Journal, 2016, 297:295-303.
    Jauris I M, Matos C F, Saucier C, et al. Adsorption of sodium diclofenac on graphene:A combined experimental and theoretical study[J]. Physical Chemistry Chemical Physics, 2016, 18(3):1526-1536.
    Moussavi G, Hossaini Z, Pourakbar M. High-rate adsorption of acetaminophen from the contaminated water onto double-oxidized graphene oxide[J]. Chemical Engineering Journal, 2016, 287:665-673.
    Wang J, Chen B. Adsorption and coadsorption of organic pollutants and a heavy metal by graphene oxide and reduced graphene materials[J]. Chemical Engineering Journal, 2015, 281:379-388.
    Wang X, Qin Y, Zhu L, et al. Nitrogen-doped reduced graphene oxide as a bifunctional material for removing bisphenols:Synergistic effect between adsorption and catalysis[J]. Environmental Science & Technology, 2015, 49(11):6855-6864.
    Xia Y, Mokaya R, Walker G S, et al. Superior CO2 adsorption capacity on N-doped, high-surface-area, microporous carbons templated from zeolite[J]. Advanced Energy Materials, 2011, 1(4):678-683.
    Sun L, Wang L, Tian C, et al. Nitrogen-doped graphene with high nitrogen level via a one-step hydrothermal reaction of graphene oxide with urea for superior capacitive energy storage[J]. Rsc Advances, 2012, 2(10):4498-4506.
    Janowska I, Chizari K, Ersen O, et al. Microwave synthesis of large few-layer graphene sheets in aqueous solution of ammonia[J]. Nano Research, 2010, 3(2):126-137.
    Wang X, Huang S, Zhu L, et al. Correlation between the adsorption ability and reduction degree of graphene oxide and tuning of adsorption of phenolic compounds[J]. Carbon, 2014, 69:101-112.
    孙怡然, 杨明轩, 于飞, 等. 石墨烯气凝胶吸附剂的制备及其在水处理中的应用[J]. 化学进展, 2015, (08):1133-1146. (SUN Yi-Ran, YANG Ming-Xuan, YU Fei, et al. Synthesis of graphene aerogel adsorbents and their applications in water treatment[J]. Progress in Chemistry, 2015, 27(8):1133-1146.)
    Chi C, Xu H, Zhang K, et al. 3D hierarchical porous graphene aerogels for highly improved adsorption and recycled capacity[J]. Materials Science and Engineering B-Advanced Functional Solid-State Materials, 2015, 194:62-67.
    Hu X, Yu Y, Ren S, et al. Highly efficient removal of phenol from aqueous solutions using graphene oxide/Al2O3 composite membrane[J]. Journal of Porous Materials, 2017:1-8.
    Kochkodan V, Hilal N. A comprehensive review on surface modified polymer membranes for biofouling mitigation[J]. Desalination, 2015, 356:187-207.
    Zhang F, Zhang W, Yu Y, et al. Sol-gel preparation of PAA-g-PVDF/TiO2 nanocomposite hollow fiber membranes with extremely high water flux and improved antifouling property[J]. Journal of Membrane Science, 2013, 432(7):25-32.
    Ravishankar H, Roddick F, Navaratna D, et al. Preparation, characterisation and critical flux determination of graphene oxide blended polysulfone (PSf) membranes in an MBR system[J]. Journal of Environmental Management, 2018, 213:168.
    Liu Q, Li L, Jin X, et al. Influence of graphene oxide sheets on the pore structure and filtration performance of a novel graphene oxide/silica/polyacrylonitrile mixed matrix membrane[J]. Journal of Materials Science, 2018, 53(9):6505-6518.
    Zhang L, Chen B, Ghaffar A, et al. Nanocomposite membrane with polyethylenimine-grafted graphene oxide as a novel additive to enhance pollutant filtration performance[J]. Environmental Science & Technology, 2018.
    Wang C, Yang S, Ma Q, et al. Preparation of carbon nanotubes/graphene hybrid aerogel and its application for the adsorption of organic compounds[J]. Carbon, 2017, 118:765-771.
    Jiao C, Xiong P, Tao J, et al. Sodium alginate/graphene oxide aerogel with enhanced strength-toughness and its heavy metal adsorption study[J]. International Journal of Biological Macromolecules, 2016, 83:133-141.
    Liu S, Sun H, Liu S, et al. Graphene facilitated visible light photodegradation of methylene blue over titanium dioxide photocatalysts[J]. Chemical Engineering Journal, 2013, 214:298-303.
    Zhang L W, Fu H B, Zhu Y F. Efficient TiO2 photocatalysts from surface hybridization of TiO2 particles with graphite-like carbon[J]. Advanced Functional Materials, 2008, 18(15):2180-2189.
    Athanasekou C P, Morales-Torres S, Likodimos V, et al. Prototype composite membranes of partially reduced graphene oxide/TiO2 for photocatalytic ultrafiltration water treatment under visible light[J]. Applied Catalysis B-Environmental, 2014, 158:361-372.
    Muthirulan P, Devi C N, Sundaram M M. A green approach to the fabrication of titania-graphene nanocomposites:Insights relevant to efficient photodegradation of acid orange 7 dye under solar irradiation[J]. Materials Science in Semiconductor Processing, 2014, 25:219-230.
    Pastrana-Martinez L M, Morales-Torres S, Likodimos V, et al. Advanced nanostructured photocatalysts based on reduced graphene oxide-TiO2 composites for degradation of diphenhydramine pharmaceutical and methyl orange dye[J]. Applied Catalysis B-Environmental, 2012, 123:241-256.
    Tao H, Liang X, Zhang Q, et al. Enhanced photoactivity of graphene/titanium dioxide nanotubes for removal of Acetaminophen[J]. Applied Surface Science, 2015, 324:258-264.
    Prabhakarrao N, Chandra M R, Rao T S. Synthesis of Zr doped TiO2/reduced graphene oxide (rGO) nanocomposite material for efficient photocatalytic degradation of eosin blue dye under visible light irradiation[J]. Journal of Alloys and Compounds, 2017, 694:596-606.
    Rong X, Qiu F, Zhang C, et al. Preparation of Ag-AgBr/TiO2-graphene and its visible light photocatalytic activity enhancement for the degradation of polyacrylamide[J]. Journal of Alloys and Compounds, 2015, 639:153-161.
    Yu J, Low J, Xiao W, et al. Enhanced photocatalytic CO2-reduction activity of anatase TiO2 by coexposed {001} and {101} Facets[J]. Journal of the American Chemical Society, 2014, 136(25):8839-8842.
    Huang M, Yu J, Hu Q, et al. Preparation and enhanced photocatalytic activity of carbon nitride/titania(001 vs 101 facets)/reduced graphene oxide (g-C3N4/TiO2/rGO) hybrids under visible light[J]. Applied Surface Science, 2016, 389:1084-1093.
    Hou C, Zhang Q, Li Y, et al. P25-graphene hydrogels:Room-temperature synthesis and application for removal of methylene blue from aqueous solution[J]. Journal of Hazardous Materials, 2012, 205:229-235.
    Song J, Xu Z, Liu W, et al. KBrO3 and graphene as double and enhanced collaborative catalysts for the photocatalytic degradation of amoxicillin by UVA/TiO2 nanotube processes[J]. Materials Science in Semiconductor Processing, 2016, 52:32-37.
    Tang Y, Zhang G, Liu C, et al. Magnetic TiO2-graphene composite as a high-performance and recyclable platform for efficient photocatalytic removal of herbicides from water[J]. Journal of Hazardous Materials, 2013, 252:115-122.
    Wang C, Yin L, Zhang L, et al. Magnetic (gamma-Fe2O3@SiO2)(n)@TiO2 functional hybrid nanoparticles with actived photocatalytic ability[J]. Journal of Physical Chemistry C, 2009, 113(10):4008-4011.
    Lin L, Wang H, Xu P. Immobilized TiO2-reduced graphene oxide nanocomposites on optical fibers as high performance photocatalysts for degradation of pharmaceuticals[J]. Chemical Engineering Journal, 2017, 310:389-398.
    Appavoo I A, Hu J, Huang Y, et al. Response surface modeling of Carbamazepine (CBZ) removal by Graphene-P25 nanocomposites/UVA process using central composite design[J]. Water Research, 2014, 57:270-279.
    Hsieh S H, Chen W J, Wu C T. Pt-TiO2/graphene photocatalysts for degradation of AO7 dye under visible light[J]. Applied Surface Science, 2015, 340:9-17.
    Anirudhan T S, Shainy F, Christa J. Synthesis and characterization of polyacrylic acid-grafted-carboxylic graphene/titanium nanotube composite for the effective removal of enrofloxacin from aqueous solutions:Adsorption and photocatalytic degradation studies[J]. Journal of Hazardous Materials, 2017, 324:117-130.
    Low W, Boonamnuayvitaya V. Enhancing the photocatalytic activity of TiO2 co-doping of graphene-Fe3+ ions for formaldehyde removal[J]. Journal of Environmental Management, 2013, 127:142-149.
    Rao G, Zhang Q, Zhao H, et al. Novel titanium dioxide/iron (Ⅲ) oxide/graphene oxide photocatalytic membrane for enhanced humic acid removal from water[J]. Chemical Engineering Journal, 2016, 302:633-640.
    Chen G, Sun M, Wei Q, et al. Ag3PO4/graphene-oxide composite with remarkably enhanced visible-light-driven photocatalytic activity toward dyes in water[J]. Journal of Hazardous Materials, 2013, 244:86-93.
    Yang Z, Xu X, Liang X, et al. MIL-53(Fe)-graphene nanocomposites:Efficient visible-light photocatalysts for the selective oxidation of alcohols[J]. Applied Catalysis B-Environmental, 2016, 198:112-123.
    An J, Zhu L, Wang N, et al. Photo-fenton like degradation of tetrabromobisphenol A with graphene-BiFeO3 composite as a catalyst[J]. Chemical Engineering Journal, 2013, 219:225-237.
    Fu Y, Chen H, Sun X, et al. Combination of cobalt ferrite and graphene:High-performance and recyclable visible-light photocatalysis[J]. Applied Catalysis B-Environmental, 2012, 111:280-287.
    Bai X, Lyu L, Ma W, et al. Heterogeneous UV/Fenton degradation of bisphenol A catalyzed by synergistic effects of FeCo2O4/TiO2/GO[J]. Environmental Science and Pollution Research, 2016, 23(22):22734-22743.
    Benjwal P, Kumar M, Chamoli P, et al. Enhanced photocatalytic degradation of methylene blue and adsorption of arsenic(Ⅲ) by reduced graphene oxide (rGO)-metal oxide (TiO2/Fe3O4) based nanocomposites[J]. Rsc Advances, 2015, 5(89):73249-73260.
    Zhang P, Mo Z, Wang Y, et al. One-step hydrothermal synthesis of magnetic responsive TiO2 nanotubes/Fe3O4/graphene composites with desirable photocatalytic properties and reusability[J]. Rsc Advances, 2016, 6(45):39348-39355.
    Ran R, Meng X, Zhang Z. Facile preparation of novel graphene oxide-modified Ag2O/Ag3VO4/AgVO3 composites with high photocatalytic activities under visible light irradiation[J]. Applied Catalysis B-Environmental, 2016, 196:1-15.
    Chen M, Yao J, Huang Y, et al. Enhanced photocatalytic degradation of ciprofloxacin over Bi2O3/(BiO)2CO3 heterojunctions:Efficiency, kinetics, pathways, mechanisms and toxicity evaluation[J]. Chemical Engineering Journal, 2018, 334:453-461.
    Chen M, Chu W. H2O2 assisted degradation of antibiotic norfloxacin over simulated solar light mediated Bi2WO6:Kinetics and reaction pathway[J]. Chemical Engineering Journal, 2016, 296:310-318.
    Chen M, Huang Y, Yao J, et al. Visible-light-driven N-(BiO)2CO3/Graphene oxide composites with improved photocatalytic activity and selectivity for NOx removal[J]. Applied Surface Science, 2018, 430:137-144.
    赫荣安, 曹少文, 余家国. 铋系光催化剂的形貌调控与表面改性研究进展[J]. 物理化学学报, 2016, (12):2841-2870. (HE Rong-An, CAO Shao-Wen YU Jia-Guo. Recent advances in morphology control and surface modification of Bi-based photocatalysts[J]. Acta Physico-Chimica Sinica, 2016, 32(12):2841-2870.)
    Hu Z T, Liu J, Yan X, et al. Low-temperature synthesis of graphene/Bi2Fe4O9 composite for synergistic adsorption-photocatalytic degradation of hydrophobic pollutant under solar irradiation[J]. Chemical Engineering Journal, 2015, 262:1022-1032.
    Lin K, Liu W, Gan J. Oxidative removal of bisphenol A by manganese dioxide:Efficacy, products, and pathways[J]. Environmental Science & Technology, 2009, 43(10):3860-3864.
    Soltani T, Lee B K. Sono-synthesis of nanocrystallized BiFeO3/reduced graphene oxide composites for visible photocatalytic degradation improvement of bisphenol A[J]. Chemical Engineering Journal, 2016, 306:204-213.
    Yan M, Hua Y, Zhu F, et al. Fabrication of nitrogen doped graphene quantum dots-BiOI/MnNb2O6 p-n junction photocatalysts with enhanced visible light efficiency in photocatalytic degradation of antibiotics[J]. Applied Catalysis B-Environmental, 2017, 202:518-527.
    Tayyebi A, Outokesh M, Tayebi M, et al. ZnO quantum dots-graphene composites:Formation mechanism and enhanced photocatalytic activity for degradation of methyl orange dye[J]. Journal of Alloys and Compounds, 2016, 663:738-749.
    Yu M, Ma Y, Liu J, et al. Sub-coherent growth of ZnO nanorod arrays on three-dimensional graphene framework as one-bulk high-performance photocatalyst[J]. Applied Surface Science, 2016, 390:266-272.
    Xie H, Ye X, Duan K, et al. CuAu-ZnO-graphene nanocomposite:A novel graphene-based bimetallic alloy-semiconductor catalyst with its enhanced photocatalytic degradation performance[J]. Journal of Alloys and Compounds, 2015, 636:40-47.
    Khan M E, Khan M M, Cho M H. CdS-graphene Nanocomposite for efficient visible-light-driven photocatalytic and photoelectrochemical applications[J]. J Colloid Interface Sci, 2016, 482:221-232.
    Li H, Xia Z, Chen J, et al. Constructing ternary CdS/reduced graphene oxide/TiO2 nanotube arrays hybrids for enhanced visible-light-driven photoelectrochemical and photocatalytic activity[J]. Applied Catalysis B-Environmental, 2015, 168:105-113.
    Guo S, Zhang G, Yu J C. Enhanced photo-Fenton degradation of rhodamine B using graphene oxide-amorphous FePO4 as effective and stable heterogeneous catalyst[J]. Journal of Colloid and Interface Science, 2015, 448:460-466.
    欧晓霞, 张凤杰, 王崇. 光/Fenton体系氧化降解水中孔雀石绿的研究[J]. 大连民族学院学报, 2013, (01):8-11. (OU Xiao-xia, ZHANG Feng-jie, WANG Chong. Oxidation of malachite green in aqueous solution by Photo/Fenton' s reagent[J]. Journal of Dalian Nationalities University, 2013, 15(1):8-11.)
    Wang Q, Li H, Yang J-H, et al. Iron phthalocyanine-graphene donor-acceptor hybrids for visible-light-assisted degradation of phenol in the presence of H2O2[J]. Applied Catalysis B-Environmental, 2016, 192:182-192.
    Zhou Y, Xiao B, Liu S-Q, et al. Photo-Fenton degradation of ammonia via a manganese-iron double-active component catalyst of graphene-manganese ferrite under visible light[J]. Chemical Engineering Journal, 2016, 283:266-275.
    He D, Jiang Y, Lv H, et al. Nitrogen-doped reduced graphene oxide supports for noble metal catalysts with greatly enhanced activity and stability[J]. Applied Catalysis B-Environmental, 2013, 132:379-388.
    Yang L, Li Z, Jiang H, et al. Photoelectrocatalytic oxidation of bisphenol A over mesh of TiO2/graphene/Cu2O[J]. Applied Catalysis B-Environmental, 2016, 183:75-85.
    Rajput H, Sangal V K, Dhir A. Synthesis of highly stable and efficient Ag loaded GO/TiO2 nanotube electrodes for the photoelectrocatalytic degradation of pentachlorophenol[J]. Journal of Electroanalytical Chemistry, 2018, 814:118-126.
    Zhou M, Tan Q, Wang Q, et al. Degradation of organics in reverse osmosis concentrate by electro-Fenton process[J]. Journal of Hazardous Materials, 2012, 215-216(10):287.
    Bian Z Y, Bian Y, Wang H, et al. Synthesis of Pd nanoparticles decorated with graphene and their application in electrocatalytic degradation of 4-chlorophenol[J]. J Nanosci Nanotechnol, 2014, 14(9):7279-7285.
    Zhang Z, Meng H, Wang Y, et al. Fabrication of graphene@graphite-based gas diffusion electrode for improving H2O2 generation in Electro-Fenton process[J]. Electrochimica Acta, 2017, 260.
    Espinosa J C, Navalon S, Primo A, et al. Graphenes as efficient metal-free Fenton catalysts[J]. Chemistry-a European Journal, 2015, 21(34):11966-11971.
    Lyu L, Yu G, Zhang L, et al. 4-phenoxyphenol-functionalized reduced graphene oxide nanosheets:A metal-free Fenton-like catalyst for pollutant destruction[J]. Environmental Science & Technology, 2018, 52.
    81 Wan Z, Wang J. Ce-Fe-reduced graphene oxide nanocomposite as an efficient catalyst for sulfamethazine degradation in aqueous solution[J]. Environmental Science and Pollution Research, 2016, 23(18):18542-18551.
    Zhang J, Yao T, Guan C, et al. One-pot preparation of ternary reduced graphene oxide nanosheets/Fe2O3/polypyrrole hydrogels as efficient Fenton catalysts[J]. Journal of Colloid and Interface Science, 2017, 505:130-138.
    Zhao Y, Chen W F, Yuan C F, et al. Hydrogenated graphene as metal-free catalyst for Fenton-like reaction[J]. Chinese Journal of Chemical Physics, 2012, 25(3):335-338.
    Shi P, Su R, Zhu S, et al. Supported cobalt oxide on graphene oxide:Highly efficient catalysts for the removal of orange Ⅱ from water[J]. Journal of Hazardous Materials, 2012, 229:331-339.
    Xu L J, Chu W, Gan L. Environmental application of graphene-based CoFe2O4 as an activator of peroxymonosulfate for the degradation of a plasticizer[J]. Chemical Engineering Journal, 2015, 263:435-443.
    Du J, Bao J, Liu Y, et al. Efficient activation of peroxymonosulfate by magnetic Mn-MGO for degradation of bisphenol A[J]. Journal of Hazardous Materials, 2016, 320:150-159.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(1)

    Article Metrics

    Article Views(1891) PDF Downloads(724) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return