SHEN Kai-quan, LI Hua-yi, WANG Yao. Properties of carbon nanotube/ethylene-propylene rubber composites prepared by an in-situ gas phase polymerization method. New Carbon Mater., 2020, 35(1): 73-79.
Citation: SHEN Kai-quan, LI Hua-yi, WANG Yao. Properties of carbon nanotube/ethylene-propylene rubber composites prepared by an in-situ gas phase polymerization method. New Carbon Mater., 2020, 35(1): 73-79.

Properties of carbon nanotube/ethylene-propylene rubber composites prepared by an in-situ gas phase polymerization method

Funds:  National Basic Research Program of China(973 program, 2011CB932602).
  • Received Date: 2019-10-25
  • Accepted Date: 2020-04-02
  • Rev Recd Date: 2020-01-15
  • Publish Date: 2020-02-29
  • Carbon nanotube/ethylene-propylene rubber composites were prepared by gas-phase polymerization of the monomers in an autoclave loaded with carbon nanotubes under agitation. The aggregation of rubber particles during polymerization was effectively prevented by adding more than 6.76 wt% carbon nanotubes that were well dispersed in the composites. The addition of carbon nanotubes had no effect on the melting and thermal decomposition temperatures of the rubber. The composites with carbon nanotubes had a significantly better conductivity and tensile strength than those with conductive carbon black or those obtained with the same formulations using a mechanical blending method.
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  • 蔡小平, 陈文启, 关颖. 乙丙橡胶及聚烯烃类热塑性弹性体[M]. 北京:中国石化出版社, 2011. 1-13. (CAI Xiao-ping, CHEN Wen-qi, GUAN Ying, et al. EPDM and Polyolefin-Based Thermoplastic Elastomer[M]. Beijing:China Petrochemical Press, 2011. 1-13.)
    朱景芬. 乙丙橡胶生产工艺及其技术经济分析[J]. 化工技术经济, 2000, 18(5):25-27. (ZHU J F. The production process of EPDM and its technical and economic analysis[J]. Chemical Techno Economics, 2000, 18(5):25-27.)
    李涛. 乙丙橡胶生产工艺的比较分析[J]. 化工科技市场, 2006, 29(9):32-35. (LI T. Comparative analysis of the production process of EPDM[J]. Chemical Technology Market, 2006, 29(9):32-35.)
    白东明. 乙丙橡胶工艺进展[J]. 化学工程师, 2010, 177(6):46-48. (BAI D M. The process progress of EPDM[J]. Chemical Engineer, 2010, 177(6):46-48.)
    M Hamba, G C Han-Adebekun, W H Ray. Kinetic study of gas phase olefin polymerization with a TiCl4/MgCl2 catalyst. II. kinetic parameter estimation[J]. Journal Of Polymer Science Part A-Polymer Chemistry, 1997, 35(10):2075-2096.
    R l Posen, L S Shikaluola, C R Moore, et al. Method for producing sticky polymers[P]. CN1079234. 1993-12-08.
    Li Chengjun, Edgar Chapman Baker, David Nicholas Edwards, et al. Producing sticky polymers[P]. CN1051737. 1991-05-29.
    E C Baker, J F Qiewa Morelos-Canton, F D Hussein, et al. Producing sticky polymers[P]. CN1099396. 1995-03-01.
    魏飞, 张强, 骞伟中, 等. 碳纳米管阵列研究进展[J]. 新型炭材料, 2007, 22(3):271-281. (WEI Fei, ZHANG Qiang, QIAN Wei zhong, et al. Progress on aligned carbon nanotube arrays[J]. New Carbon Materials, 2007, 22(3):271-281.)
    Iijima S. Helical microtubes of graphitic carbon[J]. Nature, 1991, 354(6348):56-58.
    余颖, 曾艳, 张丽莎, 等. 碳纳米管增强EPDM橡胶的性能与结构[Z]. 中国北京:中国材料研究学会, 2002:1160-1164. (YU Y, ZENG Y, ZHANG L S, et al. The properties and structure of carbon nanotube reinforced EPDM[Z]. Beijing, China:China Materials Research Society, 2002:1160-1164.)
    范壮军, 王垚, 罗国华, 等. 碳纳米管和炭黑在橡胶体系增强的协同效应[J]. 新型炭材料, 2008, 23(2):149-153. (FAN Zhuang-jun, WANG Yao, LUO Guo-hua, et al. The enhanced synergy of carbon nanotubes and carbon black in in rubber system[J]. New Carbon Materials, 2008, 23(2):149-153.)
    隋刚, 杨小平, 梁吉, 等. 碳纳米管/天然橡胶复合材料的制备及性能[J]. 复合材料学报, 2005, 22(5):72-77. (SUI G, Yang X P, LIANG J, et al. Preparation and properties of CNT/natural rubber composites[J]. Acta Materiae Compositae Sinica, 2005, 22(5):72-77.)
    李国喜, 周建庆, 王润霞, 等. 碳纳米管/丙烯酸酯橡胶复合材料的制备及性能研究[J]. 炭素技术, 2011, 30(5):6-9. (LI G X, ZHOU J Q, WANG R X, et al. Preparation and properties of Acrylate/carbon nanotubes composites[J]. Carbon Techniques 2011, 30(5):6-9.)
    陈晓红, 宋怀河. 多壁碳纳米管填充丁苯橡胶复合材料的研究[J]. 新型炭材料, 2004, 19(3):214-218. (CHEN Xiao-hong, SONG Huai-he. The research of Multi-walled carbon nanotubes filled SBR composites[J]. New Carbon Materials, 2004, 19(3):214-218.)
    Kang I, Khaleque M A, Yoo Y. Preparation and properties of ethylene propylene diene rubber/multi walled carbon nanotube composites for strain sensitive materials[J]. COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2011, 42(623-630).
    殷志刚, 盛芬玲, 刘煜. 乙丙橡胶的组成及分子序列的红外光谱研究[J]. 兰化科技. 1984, 2(4):222-229. (YIN Z G, SHENG F L, LIU Y. The study of the composition and infrared spectra of molecular sequence of EPR[J]. Science and Technology of Lcic, 1984, 2(4):222-229.)
    郝凤岭, 田春光, 尹香玉. 红外光谱法测定二元乙丙橡胶中乙烯/丙烯组成[J]. 弹性体, 2000, 10(4):17-20. (HAO F L, TIAN C G, YIN X Y. Determination of EPM rubber compositions by infrared method[J]. China Elastomerics, 2000, 10(4):17-20.)
    赵霞, 徐广通, 刘红梅, 等. 红外光谱结合偏最小二乘法快速测定二元乙丙橡胶中的结合乙烯量[J]. 石油炼制与化工, 2011, 42(12):78-81. (ZHAO X, XU G T, LIU H M, et al. Fast determination of bound ethylene content of ethylene-propylene rubber by FTIR combined with partial least square regression. Petroleum Processing and Petrochemicals, 2011, 42(12):78-81.)
    龚文化, 曾黎明. 聚合物基导电复合材料研究进展[J]. 化工新型材料, 2002, 30(4):38-40. (GONG W H, ZENG L M. The progress of conductive polymer matrix composites[J]. New Chemical Materials, 2002, 30(4):38-40.)
    万梅香. 导电高分子[J]. 高分子通报. 1999(3):47-53. (WANG M X. Conductive polymer[J]. Polymer Bulletin, 1999(3):47-53.)
    Yao F W, Wang G L. The large-scale production of carbon nanotubes in a nano-agglomerate fluidized-bed reactor[J]. Chemical Physics Letters, 2002, 364(5):568-572.
    Wei F, Qiang Z, Wei Z Q, et al. The mass production of carbon nanotubes using a nano-agglomerate fluidized bed reactor:A multiscale space-time analysis[J]. Powder Technology, 2008, 183:10-20.
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