DENG Hai-liang, ZHENG Jin-huang, YIN Zhong-yi, YAO Dong-mei, SU Hong, ZHANG Xiao-hu, SI Song-hua. Thermal conduction and tribological properties of carbon/carbon composites densified by xylene pyrolysis using La as a catalyst. New Carbon Mater., 2020, 35(1): 80-86.
Citation: DENG Hai-liang, ZHENG Jin-huang, YIN Zhong-yi, YAO Dong-mei, SU Hong, ZHANG Xiao-hu, SI Song-hua. Thermal conduction and tribological properties of carbon/carbon composites densified by xylene pyrolysis using La as a catalyst. New Carbon Mater., 2020, 35(1): 80-86.

Thermal conduction and tribological properties of carbon/carbon composites densified by xylene pyrolysis using La as a catalyst

Funds:  National Natural Science Foundation of China (51972002); Equipment Advanced Research Foundation of China (9140A12060514HT43190).
  • Received Date: 2019-11-10
  • Accepted Date: 2020-04-02
  • Rev Recd Date: 2020-02-01
  • Publish Date: 2020-02-29
  • Carbon/carbon composites with densities of 1.72-1.73 g/cm3 were fabricated by film boiling chemical vapor infiltration of a needle-pierced preform using xylene as a carbon precursor and LaCl3 as a catalyst, followed by resin impregnation and graphitization. The effects of the catalyst content on the thermal conduction and tribological properties of the composites were investigated by SEM, thermal tests with a laser flash instrument, and friction tests. Results showed that the thermal conductivities in the through thickness and in-plane directions, the friction coefficient, and the wear rate all had maxima at 6 wt% for LaCl3 contents from 0 to 15 wt%. The maximum thermal conductivities were about 58.5 and 75.6% higher than those of the composites without a catalyst in the through thickness and in-plane directions, respectively. A smooth friction film was most easily formed on the friction surface of the composite fabricated with a 6 wt% catalyst content, resulting in the lowest coefficient of friction and wear rate as well as the highest braking stability.
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