CVI处理对浸渍裂解法制备C/C-SiC复合材料弯曲性能的影响

JIA Lin-tao; WANG Meng-qian; GUO Xiao-feng; ZHU Jie; LI Ai-jun; PENG Yu-qing

doi:10.1016/S1872-5805(23)60732-2

CVI处理对浸渍裂解法制备C/C-SiC复合材料弯曲性能的影响

doi: 10.1016/S1872-5805(23)60732-2

上海大学材料科学与工程学院材料研究所，上海 200444

基金项目: 国家自然科学基金项目(21676163，51602189)；航空科学基金(2016ZFS6001，2017ZFS6001)；上海市自然科学基金(18ZR1417700)

详细信息

通讯作者:
李爱军，教授. E-mail：aijun.li@shu.edu.cn

中图分类号: TQ174
计量
- 文章访问数: 144
- HTML全文浏览量: 99
- PDF下载量: 46
- 被引次数: 0
出版历程
- 收稿日期: 2020-02-20
- 修回日期: 2020-08-24
- 网络出版日期: 2023-03-13
- 刊出日期: 2023-11-23

Effect of chemical vapor infiltration on the flexural properties of C/C-SiC composites prepared by the precursor infiltration pyrolysis method

Institute of Materials, School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China

Funds: National Natural Science Foundation of China (21676163, 51602189)，Aeronautical Science Foundation of China (2016ZFS6001，2017ZFS6001) and The Shanghai Natural Science Fund (No. 18ZR1417700)

More Information

Author Bio:
贾林涛，博士研究生. E-mail：jia0721@shu.edu.cn

Corresponding author: LI Ai-jun, Professor. E-mail: aijun.li@shu.edu.cn

摘要

摘要: 以2D叠层炭布为增强体，以掺加硅粉、炭粉和碳化硅粉3种无机粉体的糠酮树脂为前驱体，经浸渍、热压固化、炭化裂解和高温热处理过程制备出炭/炭-碳化硅（C/C-SiC）复合材料。采用多功能密度测试仪、扫描电子显微镜（SEM）、X射线衍射仪（XRD）和力学万能试验机，研究了硅粉、炭粉和碳化硅粉的掺加量以及后续化学气相渗透（CVI）处理对C/C-SiC复合材料致密度、微观结构及抗弯强度的影响。结果表明：硅粉、炭粉和碳化硅粉掺加后所形成的碳化硅颗粒对复合材料起到颗粒弥散增强的作用。具体而言，粉体掺加量越多，C/C-SiC复合材料越致密，抗弯强度越大；在三点弯曲载荷作用下，C/C-SiC复合材料呈假塑性断裂模式，并且出现层间开裂现象。对C/C-SiC复合材料进行10 h CVI处理后发现，形成的热解炭可以作为炭纤维与树脂炭基体之间的界面，弥补了树脂炭的微孔，相比于未进行CVI处理的C/C-SiC复合材料，密度最大提高了4.98%，抗弯强度最大提高了38.86%。
- 糠酮树脂 /
- C/C-SiC复合材料 /
- 无机粉体 /
- 化学气相渗透 /
- 抗弯强度
Abstract: Carbon/carbon-silicon carbide (C/C-SiC) composites were prepared by impregnation, hot-pressing with curing, carbonization at 800 ^oC and high-temperature heat treatment (800-1600 ^oC) using a 2D laminated carbon cloth as the reinforcing filler, and furfurone resin mixed with silicon, carbon from furfurone resin and SiC powders as the matrix. The effects of the addition of the three powders as well as subsequent chemical vapor infiltration (CVI) by methane on the density, microstructure and bend strength of the composites were investigated by scanning electron microscopy, density measurements, X-ray diffraction and mechanical testing. Both the SiC powders formed by the reaction at 1600 ^oC between the added Si and C particles and the added SiC powder, play a role in the reinforcement of the materials. In three-point bending, the composites had a pseudoplastic fracture mode and showed interlaminar cracking. After 10 h CVI with methane, pyrolytic carbon was formed at the interface between some of the carbon fibers and the resin carbon matrix, which produced maximum increases in the density and flexural strength of the composites of 4.98% and 38.86%, respectively.
- Furfurone resin /
- C/C-SiC composites /
- Inorganic powder /
- CVI /
- Flexural strength

HTML全文

FIG. 2784. FIG. 2784.

FIG. 2784.. FIG. 2784.

下载: 全尺寸图片幻灯片

Figure 1. TGA curve of furfurone resin

下载: 全尺寸图片幻灯片

Figure 2. Preparation flow chart of C/C-SiC composites

下载: 全尺寸图片幻灯片

Figure 3. (a) Bulk density and (b) open porosity of C/C-SiC composites with different powder content

下载: 全尺寸图片幻灯片

Figure 4. SEM images of C/C-SiC with different powder contents

下载: 全尺寸图片幻灯片

Figure 5. XRD patterns of C/C-SiC composites with different powder contents

下载: 全尺寸图片幻灯片

Figure 6. Flexural strength of C/C-SiC composites with different powder contents

下载: 全尺寸图片幻灯片

Figure 7. Flexural stress-strain curves of C/C-SiC composites with different powder contents

下载: 全尺寸图片幻灯片

Figure 8. (a) Bulk density and (b) open porosity of C/C-SiC composites after CVI enhancement process

下载: 全尺寸图片幻灯片

Figure 9. Flexural strength of C/C-SiC composites after CVI enhancement process

下载: 全尺寸图片幻灯片

Figure 10. Flexural stress-strain curves of C/C-SiC composites after CVI enhancement process

下载: 全尺寸图片幻灯片

Figure 11. Flexural modulus of C/C-SiC composites before and after CVI

下载: 全尺寸图片幻灯片

Figure 12. PLM image of PyC deposition between resin carbon and fiber of S5 sample

下载: 全尺寸图片幻灯片

Figure 13. Porosity distribution of S5 sample before and after CVI

下载: 全尺寸图片幻灯片

Table 1. Powder formula of 5 groups of samples

Specimen C powders
/wt% Si powders /wt% SiC powders /wt%

S1 0 0 0
S2 0 5 0
S3 5 5 0
S4 10 10 0
S5 5 5 10

下载: 导出CSV

参考文献(26)

[1]	Qiu M, Hang Y, Liu Z, et al. A review of the fabrication methods for solar silicon wafer[J]. Mechanical Science and Technology for Aerospace Engineering,2008(08):43-46.6.
[2]	Quan C. Preparation and Passivation of Silicon Nitride Thin Films for Solar Cells[M]. University of Electronic Science and Technology of China, 2012.
[3]	Gorin A, Jaouad A, Grondin E, et al. Fabrication of silicon nitride waveguides for visible-light using PECVD: A study of the effect of plasma frequency on optical properties[J]. Optics Express,2008,16(18):13509-16. doi: 10.1364/OE.16.013509
[4]	Zhou Z, Cai X, Liu W. Preparation of silicon nitride thin films for solar cells by PECVD[J]. Solar Energy,2017,8:43-47.
[5]	Zhang B, Dang J. Graphite boat pin and coating device[P]. CN 207130336 U. 2018.
[6]	Bai X, Guo W, Jia Y, et al. Study on the uniformity of polycrystalline PECVD coating[J]. Technological Development of Enterprise,2013,32(Z2):51-52+54.54.
[7]	Fu Q, Li H, Shen X, et al. Domestic research process of matrix modification for carbon/carbon composites[J]. Materials China,2011,30(11):6-12.
[8]	Su J, Li Y, Xiao Z, et al. Preparation and properties of the U-shaped carbon-carbon composite radiator[J]. Carbon,2011,1:21-24.
[9]	Li T, Yang Z, Zheng X, et al. The relationship between the surface state of carbon fiber and the ILSS of C/C composites[J]. Ordnance Material Science and Engineering,1993,04:8-11.
[10]	Li C, Zheng J, Su H, et al. Mechanical and thermophysical properties of two dimensional carbon/carbon composites at elevated temperatures[J]. Aerospace Materials & Technology,2004,34(1):33-37.
[11]	Jian K, Hu H, Chen Z. Fabrication of low-cost C/SiC composite from silicon powder and phenolic resins[J]. Development and Application of Materials,2002,17(6):12-14.
[12]	Yan L, Li H, Cui H, et al. C/SiC composites prepared by inner siliconizing process[J]. Journal of Materials Engineering,2005(09):41-44+52.
[13]	Wang M. Application of carbon fiber composites in aerospace field[J]. Modern Business Trade Industry,2019,40(08):195-197.
[14]	Hu L, Li C, Zhang Y. Influence of C/C thermal treatment temperature on microstructure and thermal properties of C/C-SiC composites[J]. Carbon,2018(1):18-23.
[15]	Xia L, Zhang H, Xiong X, et al. Curing reaction of furfural acetone resin used for new carbon materials[J]. The Chinese Journal of Nonferrous Metals,2008(06):7-12.
[16]	Wang J, Guo L, Li H, et al. Curing, characteristics and kinetic analysis of furfural acetone resin used as carbon /carbon composites precursor[J]. Journal of Solid Rocket Technology,2012,35(01):127-130+136.
[17]	Donh L, Zhang B, Tian J, et al. Study on the oxidation resistance of carbon ceramic composites[J]. Journal of Tsinghua University (Science and Technology),1997,37(05):108-111.
[18]	Chollion G, Siron O, Takahashi J, et al. Microstructure and mechanical properties of coal tar pitch-based 2D-C/C composites with a filler addition[J]. Carbon,2001,39(13):2065-2075. doi: 10.1016/S0008-6223(01)00021-5
[19]	Peng X, Zhuan L, Xiang X. Manufacture and tribological properties of C/C-SiC brake composites fabricated by warm compacted in situ reaction[J]. Tribology,2012(04):332-337.
[20]	Mikociak D, Rudawski A, Blazewicz S. Mechanical and thermal properties of C/C composites modified with SiC nanofiller[J]. Materials Science and Engineering:A,2018,716:220-227. doi: 10.1016/j.msea.2018.01.048
[21]	Qin M, Xiao P, Xiong X, et al. Mechanical properties of C/C-SiC composites prepared with different phenolic resin[J]. Materials Science and Engineering of Powder Metallurgy,2008,13(06):346-351.
[22]	Zhou S, Wu X, Cui H, et al. Influence of graphite filler on the performance of C/C-SiC composites based on LSI[J]. Journal of Solid Rocket Technology,2015,38(02):281-285.
[23]	Zhao W, Zhu B, Shi Z, et al. Study on moulding process and properties of C/C-SiC composites[J]. Journal of Functional Materials,2015,46(S1):152-155.
[24]	Schulte-Fischedick J, Frieß M, Krenkel W, et al. The interlaminar shear strength of C/C-SiC[J]. High Temperature Ceramic Matrix Composites,2001:181-186.
[25]	Chen Z, Zhang L, Cheng L, et al. Preparation of C fiber reinforced alumina-mullite composite by PIP and CVI[J]. Journal of Inorganic Materials,2003,18(3):638-644.
[26]	Li C, Ma B, Jin Z. The fracture toughness of 2D carbon-carbon composite[J]. Journal of Solid Rocket Technology,2003,26(1):67-70.