废旧动力锂离子电池全组分回收技术研究进展

Research progress on recovering the components of spent Li-ion batteries

  • 摘要: 随着近年来电动汽车的蓬勃发展,锂离子电池的使用量以及退役量都在逐年增长,随之而来的是废旧锂离子电池带来的环境污染以及资源浪费问题。目前商用锂离子电池多由过渡金属氧化物或磷酸盐基正极、石墨基负极、含有害锂盐的有机电解质、聚合物隔膜以及塑料或金属外壳组成,在电池退役后,其中的诸多贵金属以及石墨等都具有较高的回收价值。本文对锂离子电池工作原理及组成结构、废旧锂离子电池全组分回收等研究现状进行了综述,着重介绍废旧锂离子电池中正极材料、负极材料以及电解液回收的研究进展,从回收成本和二次污染等方面概述了不同方法所遇到的问题,最后对未来的发展提供了一些思路。

     

    Abstract: With the recent rapid development of electric vehicles, the use and decommissioning of Li-ion batteries have increased, causing environmental pollution and the waste of valuable materials in spent batteries. Commercial Li-ion batteries are mostly composed of transition metal oxide or phosphate-based cathodes, graphite-based anodes, organic electrolytes containing harmful lithium salts, polymer separators, and plastic or metal shells. After the battery is retired, many precious metals and graphite have a high recycling value. We review the current status of research on recovering these components with an emphasis on the leaching and separation of cathode and anode materials, and electrolytes in these batteries. The problems encountered in the different methods are outlined in terms of recycling cost and secondary pollution. Future research trends are outlined for the commercial full recovery of spent Li-ion batteries.

     

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