贺素姣, 张凯强, 邹雅珺, 田志红. 3D打印碳基微电池的技术、材料与应用进展[J]. 新型炭材料, 2022, 37(5): 898-917. DOI: 10.1016/S1872-5805(22)60634-6
引用本文: 贺素姣, 张凯强, 邹雅珺, 田志红. 3D打印碳基微电池的技术、材料与应用进展[J]. 新型炭材料, 2022, 37(5): 898-917. DOI: 10.1016/S1872-5805(22)60634-6
HE Su-jiao, ZHANG Kai-qiang, ZOU Ya-jun, TIAN Zhi-hong. Three-dimensional printed carbon-based microbatteries: progress on technologies, materials and applications[J]. New Carbon Mater., 2022, 37(5): 898-917. DOI: 10.1016/S1872-5805(22)60634-6
Citation: HE Su-jiao, ZHANG Kai-qiang, ZOU Ya-jun, TIAN Zhi-hong. Three-dimensional printed carbon-based microbatteries: progress on technologies, materials and applications[J]. New Carbon Mater., 2022, 37(5): 898-917. DOI: 10.1016/S1872-5805(22)60634-6

3D打印碳基微电池的技术、材料与应用进展

Three-dimensional printed carbon-based microbatteries: progress on technologies, materials and applications

  • 摘要: 可充电微型电池可以为下一代可穿戴便携设备提供储能装置。增材制造也称为三维(3D)打印技术,具有构建复杂3D构型的能力,为制备尺寸可调、形状一致性好、兼具高能量密度和高功率密度的微电池提供了新的机遇。与其他多孔金属电极材料相比,轻质炭材料具有比表面积大、导电性好、化学稳定性高等优点。近年来,基于碳基墨水的3D打印技术已被用于制备多种类型的可充电微电池。为了对碳基微电池的电化学性能进行优化,并充分发挥其潜力,亟需对3D打印技术、材料设计以及应用方向进行梳理,从而深入理解3D打印电池方法的设计优化策略。本文首先介绍了4种主要3D打印技术的最新进展,阐述了导电炭材料在解决3D打印微电池挑战中的研究方法,总结了其在一系列储能设备和可穿戴电子设备集成中的应用。最后,进一步讨论了3D打印技术制造碳基微电池面临的关键科学问题和未来的发展方向。

     

    Abstract: Next-generation wearable and portable devices require rechargeable microbatteries to provide energy storage. Three-dimensional (3D) printing, with its ability to build geometrically complex 3D structures, enables the manufacture of microbatteries of different sizes and shapes, and with high energy and power densities. Lightweight carbon materials have a great advantage over other porous metals as electrode materials for rechargeable batteries, because of their large specific surface area, superior electrical conductivity and high chemical stability. In recent years, a variety of rechargeable microbatteries of different types have been successfully printed using carbon-based inks. To optimize their electrochemical performance and extend their potential applications, it is important to analyze the design principles with respect to the 3D printing technique, printable carbon materials and promising applications. This paper provides a perspective on recent progress in the four major 3D printing techniques, elaborates on conductive carbon materials in addressing the challenging issues of 3D printed microbatteries, and summarizes their applications in a number of energy storage devices that integrate with wearable electronics. Current challenges and future opportunities for carbon-based microbattery fabrication by 3D printing techniques are discussed.

     

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