钠离子电池负极用高性能沥青基富硫炭材料

贺磊; 孙钰仁; 王春雷; 郭宏毅; 郭永强; 李晨; 周颖

doi:10.1016/S1872-5805(20)60499-1

钠离子电池负极用高性能沥青基富硫炭材料

doi: 10.1016/S1872-5805(20)60499-1

大连理工大学化工学院炭素材料研究室, 辽宁省能源材料化工重点实验室, 辽宁大连 116024

基金项目: 国家自然科学基金（21576047，U1510204，21776040）.

详细信息

作者简介:
贺磊,硕士研究生.E-mail:hl_helei@126.com

通讯作者:
周颖,教授.E-mail:zhouying.dlut@dlut.edu.cn

中图分类号: TQ127.1⁺1
计量
- 文章访问数: 830
- HTML全文浏览量: 204
- PDF下载量: 206
- 被引次数: 0
出版历程
- 收稿日期: 2020-04-20
- 修回日期: 2020-07-05
- 刊出日期: 2020-08-28

High performance sulphur-doped pitch-based carbon materials as anode materials for sodium-ion batteries

Liaoning Key Laboratory of Energy Materials and Chemical Engineering, Carbon Research Laboratory, College of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

Funds: National Natural Science Foundation of China (21576047, U1510204, 21776040).

摘要

摘要: 以中温煤沥青为碳源，升华硫为硫源，经低温和高温两步热处理，成功制备了具有较高硫含量的硫掺杂沥青基炭材料。探究了炭化温度对材料组成、结构及电化学性能的影响。结果表明，随着炭化温度的升高，材料中硫含量明显减少；硫流失的同时，带来炭结构的变化，材料的比表面积和层间距逐渐增大。其中800℃炭化的材料（SC-800）硫含量达到20.19 wt.%，层间距为0.368 nm，在0.1 A/g的电流密度下，储钠首次可逆容量高达482.8 mAh/g；在0.5 A/g和5 A/g的电流密度下，循环500圈和1 000圈后，仍然保持245.9和103.7 mAh/g的比容量。SC-800优异的电化学性能归因于高硫含量、较大的层间距和合适的孔道结构。
- 沥青 /
- 硫掺杂炭材料 /
- 钠离子电池负极炭
Abstract: Sulfur-doped pitch-based carbon materials with a high sulfur content were prepared by a two-step heat treatment method using medium-temperature coal tar pitch as the carbon source and sublimated sulfur as the sulfur source. The effect of the final carbonization temperature on the composition, microstructure and electrochemical properties of the materials suitability as anode materials for sodium ion batteries were investigated. Results show that by increasing the final carbonization temperature the sulfur content of the materials decreases significantly, and the specific surface area and interlayer spacing gradually increase. Among the carbons obtained at different final carbonization temperatures, the sulfur content of the carbon at 800℃ was 20.19 wt.% and its interlayer spacing 0.368 nm, and its reversible capacity was 482.8 mAh/g at 0.1 A/g for the first cycle and had values of 245.9 and 103.7 mAh/g at 0.5 and 5 A/g, respectively after 500 cycles. The excellent sodium storage performance of the carbon at 800℃ is attributed to its high sulfur content, large interlayer spacing and suitable pore structure.
- Asphalt /
- Sulphur-doped carbon materials /
- Anode carbon for sodium-ion batteries

HTML全文

下载: 全尺寸图片幻灯片

参考文献(31)

Yabuuchi N, Kubota K, Dahbi M, et al. Research development on sodium-ion batteries[J]. Chem Rev, 2014, 114(23):11636-11682.

Ren D Z, Huang H, Qi J G, et al. One-pot template-free cross-linking synthesis of SiO_x-SnO₂@C hollow spheres as a high volumetric capacity anode for lithium-ion batteries[J]. Energy Technology, 2020, 2000314, 10.1002/ente.202000314.

Bommier C, Surta T W, Dolgos M, et al. New mechanistic insights on Na-ion storage in nongraphitizable carbon[J]. Nano Lett, 2015, 15(9):5888-5892.

Ge P, Fouletier M. Electrochemical intercalation of sodium in graphite[J]. Solid State lonics, 1988, 28:1172-1175.

Doeff M M, Ma Y P, Visco S J, et al. Electrochemical insertion of sodium into carbon[J]. J Electrochem Soc, 1993, 140(12):169-170.

董伟,杨绍斌,沈丁,等. 石油沥青和葡萄糖热解炭的可逆储钠性能研究[J]. 新型炭材料, 2017, 32(3):227-233. (DONG Wei, YANG Shao-bin, SHEN Ding, et al. Performance of pitch and glucose pyrocarbons for reversible sodium storage[J]. New Carbon Materials, 2017, 32(3):227-233.)

Liu P, Li Y M, Hu Y S, et al. A waste biomass derived hard carbon as a high-performance anode material for sodium-ion batteries[J]. Journal of Materials Chemistry A, 2016, 4(34):13046-13052.

Wang Q Q, Zhu X S, Liu Y H, et al. Rice husk-derived hard carbons as high-performance anode materials for sodium-ion batteries[J]. Carbon, 2018, 127:658-666.

Wahid M, Puthusseri D, Gawli Y, et al. Hard carbons for sodium-ion battery anodes:Synthetic strategies, material properties, and storage mechanisms[J]. ChemSusChem, 2018, 11:506-526.

Qi Y R, Lu Y X, Ding F X, et al. Slope-dominated carbon anode with high specific capacity and superior rate capability for high safety Na-ion batteries[J]. Angew Chem Int Ed Engl, 2019, 58(13):4361-4365.

Wang H G, Wu Z, Meng F L, et al. Nitrogen-doped porous carbon nanosheets as low-cost, high-performance anode material for sodium-ion batteries[J]. ChemSusChem, 2013, 6(1):56-60.

Xu J T, Wang M, Wickramaratne N P, et al. High-performance sodium ion batteries based on a 3D anode from nitrogen-doped graphene foams[J]. Adv Mater, 2015, 27(12):2042-2048.

Yun Y S, Le V D, Kim H, et al. Effects of sulfur doping on graphene-based nanosheets for use as anode materials in lithium-ion batteries[J]. Journal of Power Sources, 2014, 262:79-85.

Yang J Q, Zhou X L, Wu D H, et al. S-Doped N-rich carbon nanosheets with expanded interlayer distance as anode materials for sodium-ion batteries[J]. Adv Mater, 2016, 29(6):1604108.

Qie L, Chen W M, Xiong X Q, et al. Sulfur-doped carbon with enlarged interlayer distance as a high-performance anode material for sodium-ion batteries[J]. Adv Sci, 2015, 2(12):1500195.

Wang Z H, Qie L, Yuan L X, et al. Functionalized N-doped interconnected carbon nanofibers as an anode material for sodium-ion storage with excellent performance[J]. Carbon, 2013, 55:328-334.

Hao M Y, Xiao N, Wang Y W, et al. Pitch-derived N-doped porous carbon nanosheets with expanded interlayer distance as high-performance sodium-ion battery anodes[J]. Fuel Processing Technology, 2018, 177:328-335.

Hou H S, Shao L D, Zhang Y, et al. Large-area carbon nanosheets doped with phosphorus:A high-performance anode material for sodium-ion batteries[J]. Adv Sci, 2017, 4(1):1600243.

Syroezhko A M, Begak O Y, Fedorov V V, et al. Modification of paving asphalts with sulfur[J]. Chemistry of Fossil Fuel, 2003, 76(3):491-496.

Zhao G G, Zou G Q, Hou H S, et al. Sulfur-doped carbon employing biomass-activated carbon as a carrier with enhanced sodium storage behavior[J]. Journal of Materials Chemistry A, 2017, 5(46):24353-24360.

ZHANG Hong-wei, LU Jia-min, YANG Le, et al. N,S co-doped porous carbon nanospheres with a high cycling stability for sodium ion batteries[J]. New Carbon Materials, 2017, 32(6):517-526.

Li W, Zhou M, Li H M, et al. A high performance sulfur-doped disordered carbon anode for sodium ion batteries[J]. Energy & Environmental Science, 2015, 8(10):2916-2921.

Brauman S K. Chemiluminescence studies of the low temperature thermooxidation of poly(phenylene sulfide)[J]. Journal of Polymer Science:Part A:Polymer Chemistry, 1989, 27:3285-3302.

Chen W Z, Shi J J, Zhu T S, et al. Preparation of nitrogen and sulfur dual-doped mesoporous carbon for supercapacitor electrodes with long cycle stability[J]. Electrochimica Acta, 2015, 177:327-334.

Hong Z S, Zhen Y C, Ruan Y R, et al. Rational design and general synthesis of S-doped hard carbon with tunable doping sites toward excellent Na-ion storage performance[J]. Adv Mater, 2018, 30(29):1802035.

Deng X, Xie K Y, Li L, et al. Scalable synthesis of self-standing sulfur-doped flexible graphene films as recyclable anode materials for low-cost sodium-ion batteries[J]. Carbon, 2016, 107:67-73.

Zou G Q, Hou H S, Zhao G G, et al. Preparation of S/N-codoped carbon nanosheets with tunable interlayer distance for high-rate sodium-ion batteries[J]. Green Chemistry, 2017, 19(19):4622-4632.

Zou G Q, Wang C, Hou H S, et al. Controllable interlayer spacing of sulfur-doped graphitic carbon nanosheets for fast sodium-ion batteries[J]. Small, 2017, 13(31):1700762.

Wang X L, Li G, Hassan F M, et al. Sulfur covalently bonded graphene with large capacity and high rate for high-performance sodium-ion batteries anodes[J]. Nano Energy, 2015, 15:746-754.

Xu D F, Chen C J, Xie J, et al. A hierarchical N/S-codoped carbon anode fabricated facilely from cellulose/polyaniline microspheres for high-performance sodium-ion batteries[J]. Advanced Energy Materials, 2016, 6(6):1501929.

Zhu Y J, Wang C S. Galvanostatic intermittent titration technique for phase-transformation Electrodes[J]. J Phys Chem C, 2010, 114:2830-2841.

施引文献

资源附件(0)

访问统计