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The use of in-situ Raman spectroscopy in investigating carbon materials as anodes of alkali metal-ion batteries

CHENG Xiao-qin LI Hui-jun ZHAO Zhen-xin WANG Yong-zhen WANG Xiao-min

程晓琴, 李慧君, 赵振新, 王永祯, 王晓敏. 原位拉曼光谱在碱金属离子电池炭负极材料研究中的应用. 新型炭材料, 2021, 36(1): 93-105. doi: 10.1016/S1872-5805(21)60007-0
引用本文: 程晓琴, 李慧君, 赵振新, 王永祯, 王晓敏. 原位拉曼光谱在碱金属离子电池炭负极材料研究中的应用. 新型炭材料, 2021, 36(1): 93-105. doi: 10.1016/S1872-5805(21)60007-0
CHENG Xiao-qin, LI Hui-jun, ZHAO Zhen-xin, WANG Yong-zhen, WANG Xiao-min. The use of in-situ Raman spectroscopy in investigating carbon materials as anodes of alkali metal-ion batteries. New Carbon Mater., 2021, 36(1): 93-105. doi: 10.1016/S1872-5805(21)60007-0
Citation: CHENG Xiao-qin, LI Hui-jun, ZHAO Zhen-xin, WANG Yong-zhen, WANG Xiao-min. The use of in-situ Raman spectroscopy in investigating carbon materials as anodes of alkali metal-ion batteries. New Carbon Mater., 2021, 36(1): 93-105. doi: 10.1016/S1872-5805(21)60007-0

原位拉曼光谱在碱金属离子电池炭负极材料研究中的应用

doi: 10.1016/S1872-5805(21)60007-0
详细信息
  • 中图分类号: TQ127.1+1

The use of in-situ Raman spectroscopy in investigating carbon materials as anodes of alkali metal-ion batteries

Funds: The authors would like to offer special thanks to Naticnal Natural Science Foundation of China (U1810115, U1710256, 52072256)
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  • 摘要: 拉曼散射仪是一种基于激光物理学的快速、无损、高分辨率的通用表征工具,已被证明是研究温度、应力、电化学反应等诱导的结构相变的一种有力工具。碱金属电池的原位拉曼表征可以追踪充放电过程中的电极材料变化和界面反应。炭材料因其良好的可逆性、优异的稳定性、低电化学平台和低成本,成为应用最广泛的锂离子电池负极材料。本文详细总结了原位拉曼谱图在碱金属离子电池炭负极材料研究中的应用,着重整理归纳了原位拉曼谱图在分析Li+/Na+/K+在石墨、硬碳等炭材料储能机理中的应用,分析了尺寸效应、应力、掺杂、溶剂化共插层等对碱金属离子电池炭负极材料储能的影响。原位拉曼与原子力显微镜(AFM),X射线衍射(XRD)等高分辨率的原位表征联用以达到分析储能机理的目的,将会在储能领域中表现出广阔的应用前景。
  • Figure  1.  Schematic representation of lithium-graphite intercalation compounds (Li-GICs).

    Figure  2.  Schematic representation of in operando system for Raman measurements[47]. Reproduced with permission.

    Figure  3.  Comparison of the Raman peak shift of the split G band for graphite flakes with different thicknesses[48]. Reproduced with permission.

    Figure  4.  (a) Raman spectra of NG-7 and GCNSs with various sizes and heat-treatment temperatures and (b) representative fitting results with three Lorentzians[49]. Reproduced with permission.

    Figure  5.  (a) Scheme illustration of the electrochemical coin cell assembly with a visible Kapton window and (b) Raman spectra of the graphene electrode during lithiation/delithiation[50]. Reproduced with permission.

    Figure  6.  (a) Sodium insertion model and (b) experimentally observed discharge curve[51]. Reproduced with permission.

    Figure  7.  In-situ Raman spectra of NMCSs-800 for SIBs at (a) the first cycle and (b) the second cycle [52]. Reproduced with permission.

    Figure  8.  In-situ Raman spectra and the corresponding discharge-charge profiles at the first cycle of N-GCNs for (a,b) LIBs (c,d) and SIBs, respectively[54]. Reproduced with permission.

    Figure  9.  Proposed sodium storage mechanism of the graphite electrode with linear ether-based electrolyte [55]. Reproduced with permission.

    Figure  10.  (a) In-situ Raman spectra (normalized) of FLG, (b) selected spectra and Lorentzian fits and (c) tracking the positions of the Raman G peak components[56]. Reproduced with permission.

    Figure  11.  (a) Schematic representing the staging mechanism revealed by the in-situ Raman experiments, (b) Selective Raman spectra taken at different states of charge and (c) waterfall plot of all Raman spectra[62]. Reproduced with permission.

    Figure  12.  (a,b) CVs for N-FLG and FLG, (c,d) Raman spectra at selected voltages for N-FLG and FLG and (e,f) schematic of the staging and defect storage mechanism in N-FLG and FLG[64]. Reproduced with permission.

    Figure  13.  Schematic illustration of the potassium storage behavior occurring in the NP-CNPs/electrolyte/K metal battery system[66]. Reproduced with permission.

    Figure  14.  (a) In-situ Raman spectra (normalized) with corresponding cell voltages and (b) analysis of the evolving G peak doublet with the component peak areas plotted with respect to the cell potential.[68]. Reproduced with permission.

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  • 收稿日期:  2020-10-09
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