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Recent advances in the electroreduction of carbon dioxide to formic acid over carbon-based materials

LI Wen-bin YU Chang TAN Xin-yi CUI Song ZHANG Ya-fang QIU Jie-shan

李文斌, 于畅, 谭新义, 崔崧, 张亚方, 邱介山. 碳基材料在电还原二氧化碳制甲酸中的研究进展. 新型炭材料(中英文), 2022, 37(2): 277-289. doi: 10.1016/S1872-5805(22)60592-4
引用本文: 李文斌, 于畅, 谭新义, 崔崧, 张亚方, 邱介山. 碳基材料在电还原二氧化碳制甲酸中的研究进展. 新型炭材料(中英文), 2022, 37(2): 277-289. doi: 10.1016/S1872-5805(22)60592-4
LI Wen-bin, YU Chang, TAN Xin-yi, CUI Song, ZHANG Ya-fang, QIU Jie-shan. Recent advances in the electroreduction of carbon dioxide to formic acid over carbon-based materials. New Carbon Mater., 2022, 37(2): 277-289. doi: 10.1016/S1872-5805(22)60592-4
Citation: LI Wen-bin, YU Chang, TAN Xin-yi, CUI Song, ZHANG Ya-fang, QIU Jie-shan. Recent advances in the electroreduction of carbon dioxide to formic acid over carbon-based materials. New Carbon Mater., 2022, 37(2): 277-289. doi: 10.1016/S1872-5805(22)60592-4

碳基材料在电还原二氧化碳制甲酸中的研究进展

doi: 10.1016/S1872-5805(22)60592-4
基金项目: 国家自然科学基金项目(51872035,22078052);辽宁省大连市高层次人才创新计划(2019RJ03)
详细信息
    通讯作者:

    于 畅,教授. E-mail:chang.yu@dlut.edu.cn

    邱介山,教授. E-mail:jqiu@dlut.edu.cn

  • 中图分类号: TQ127.1+1

Recent advances in the electroreduction of carbon dioxide to formic acid over carbon-based materials

Funds: This work was partly supported by the National Natural Science Foundation of China (51872035, 22078052) and Innovation Program of Dalian City of Liaoning Province (2019RJ03)
More Information
  • 摘要: 基于可再生、间歇性的能源驱动的二氧化碳(CO2)电还原制甲酸(HCOOH)技术是二氧化碳转化利用的重要途径。本文详细介绍了CO2的物理化学性质及其电还原生成HCOOH的反应机理;综述了近年来碳基材料在电还原CO2制HCOOH中的研究进展,包括无金属的碳催化剂和碳负载型催化剂。在此基础上,总结和评述了电化学反应器的设计和优化策略。以CO2电还原耦合甲醇电氧化反应为例,分析了CO2杂化电解技术的优势。最后,提出了目前电还原CO2制HCOOH的关键科学技术问题和未来的发展方向,以期为该技术的进一步发展提供新的思路和指导。
  • FIG. 1395.  FIG. 1395.

    FIG. 1395.. 

    Figure  1.  Two possible mechanisms for electroreduction of CO2 to HCOO, where the C, O, H atoms and catalyst are represented by red, gray, blue, yellow colors.

    Figure  2.  (a) Linear sweep voltammetry curves over different GNDs catalysts for CO2RR. (b) FEHCOO over different GNDs catalysts for CO2RR. (c) Models of carbon catalysts with different configurations containing oxygen functional groups. (d) Gibbs free energy of CO2RR and HER over carbon catalysts with different configurations of oxygen-containing functional groups[31]. Reprinted with permission by American Chemical Society.

    Figure  3.  (a) Fabrication of DEA-SnOx/C catalyst. (b) Mechanism diagram of electrochemical CO2RR to HCOO-[33]. Reprinted with permission by American Chemical Society. (c) Schematic illustration of the preparation of VO-SnOx/CF catalyst. (d, e) SEM images of VO-SnOx/CF[34]. Reprinted with permission by Royal Society of Chemistry. (f) Schematic diagram of electrochemical CO2RR on Cu@C catalyst. (g) Electrochemical performance over the Cu@C catalyst covering FEHCOOH and HCOOH formation rate[35]. Reprinted with permission by Elsevier.

    Figure  4.  (a) Schematic fabrication process for S-doped Bi2O3-CNT. (b) FEHCOOH over a series of catalysts at different applied voltages. (c) Schematic diagram of the S species-promoted effects on CO2RR to HCOOH[36]. Reprinted with permission by American Chemical Society. (d) Mechanism diagram for CO2RR to HCOOH over N, S-doped SnO2/NSC[37]. Reprinted with permission by American Chemical Society. (e) Schematic fabrication process for In-N-C[38]. Reprinted with permission by American Chemical Society.

    Figure  5.  (a) Preparation diagram of carbon nanorods-encapsulated Bi2O3 (Bi2O3@C). (b) TEM image of Bi2O3@C. (c) FEHCOOH over catalyst at different potentials vs. RHE[40]. Reprinted with permission by WILEY-VCH. (d) Schematic fabrication process for CuBi-C. (e) FEHCOOH over different catalysts under various voltages[41]. Reprinted with permission by Elsevier.

    Figure  6.  Scheme and comparison of four different reactors for producing HCOOH via CO2RR.

    Figure  7.  (a) Schematic of CO2RR and MOR. (b) LSV curves of CO2RR and MOR. (c) FEformate of CO2RR and MOR[16]. Reprinted with permission by WILEY-VCH.

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  • 收稿日期:  2021-10-28
  • 修回日期:  2021-12-06
  • 网络出版日期:  2021-12-17
  • 刊出日期:  2022-03-30

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