炭纤维增强环氧树脂复合材料的化学回收与再利用研究进展

Review of chemical recycling and reuse of carbon fiber reinforced epoxy resin composites

  • 摘要: 炭纤维增强环氧树脂复合材料以其优异的力学性能被广泛应用于交通运输、航空航天等领域。近年来,炭纤维增强环氧树脂复合材料的回收利用引起了全世界的关注。化学回收是一种有前景的方法,它可以选择性地破坏环氧树脂的特定化学键,实现环氧树脂的可控化学降解。复合材料中的环氧树脂被降解为单体或低聚物,高价值炭纤维可回收利用。首先,本文综述了炭纤维增强环氧树脂复合材料化学回收方法的研究进展,主要包括超临界和亚临界流体、氧化降解、醇解、电化学回收等。然后,简要介绍了可回收热固性树脂的合成及解聚机理,其应用有利于炭纤维增强环氧树脂复合材料中各组分的回收和再利用。最后,提出了化学回收炭纤维增强环氧树脂复合材料和制备高性能可回收环氧树脂材料可能的发展方向。

     

    Abstract: Carbon fiber-reinforced epoxy resin composites (CFRCs) have been used in the transportation and aerospace fields because of their excellent mechanical properties. The recycling of CFRCs has attracted attention worldwide in recent years. Chemical recycling is a promising method, which can selectively destroy specific resin bonds to achieve controllable degradation. Matrix epoxy resins are degraded into monomers or oligomers, and the high-value carbon fibers can be recycled. First, we summarize progress on chemical recovery methods, mainly super- and subcritical fluids, oxidation, alcoholysis and electrochemical recycling etc. Then, we briefly introduce the synthesis and depolymerization mechanism of recyclable thermosetting resins by the insertion of reversible chemical bonds into the resin to prepare recyclable resins, which is beneficial for the recycling and reuse of components in CFRCs. Finally, possible developments in the chemical recycling of CFRCs and the preparation of high-performance recyclable epoxy resins are proposed.

     

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