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3D porous NiCo2(CO3)3/reduced graphene oxide aerogel with heterogeneous interfaces for high-efficiency microwave absorption

WU Dan-dan ZHANG Han-xiao WANG Zheng-yan ZHANG Yan-lan WANG Yong-zhen

武丹丹, 张含笑, 王政炎, 张妍兰, 王永祯. 用于高效微波吸收的3D多孔异质界面型NiCo2(CO3)3/RGO气凝胶. 新型炭材料(中英文), 2023, 38(6): 1035-1049. doi: 10.1016/S1872-5805(23)60780-2
引用本文: 武丹丹, 张含笑, 王政炎, 张妍兰, 王永祯. 用于高效微波吸收的3D多孔异质界面型NiCo2(CO3)3/RGO气凝胶. 新型炭材料(中英文), 2023, 38(6): 1035-1049. doi: 10.1016/S1872-5805(23)60780-2
WU Dan-dan, ZHANG Han-xiao, WANG Zheng-yan, ZHANG Yan-lan, WANG Yong-zhen. 3D porous NiCo2(CO3)3/reduced graphene oxide aerogel with heterogeneous interfaces for high-efficiency microwave absorption. New Carbon Mater., 2023, 38(6): 1035-1049. doi: 10.1016/S1872-5805(23)60780-2
Citation: WU Dan-dan, ZHANG Han-xiao, WANG Zheng-yan, ZHANG Yan-lan, WANG Yong-zhen. 3D porous NiCo2(CO3)3/reduced graphene oxide aerogel with heterogeneous interfaces for high-efficiency microwave absorption. New Carbon Mater., 2023, 38(6): 1035-1049. doi: 10.1016/S1872-5805(23)60780-2

用于高效微波吸收的3D多孔异质界面型NiCo2(CO3)3/RGO气凝胶

doi: 10.1016/S1872-5805(23)60780-2
基金项目: 中央引导地方科技发展资金项目 (YDZJSX2022B003);山西省科技重大专项计划项目 (202101120401008);山西省重点研发计划项目(202102030201006);山西省自然科学基金项目 (202203021212205);山西省高等学校科技创新项目 (2022L074)
详细信息
    通讯作者:

    张妍兰,讲师. E-mail:zhangyanlan@tyut.edu.cn

    王永祯,教授. E-mail:wangyongzhen@tyut.edu.cn

  • 中图分类号: TB33

3D porous NiCo2(CO3)3/reduced graphene oxide aerogel with heterogeneous interfaces for high-efficiency microwave absorption

More Information
  • 摘要: 创新的微观结构设计和合适的多组分策略对于具有强吸收和宽有效吸收频带(EAB)的先进电磁吸波材料(EAM)仍然具有挑战性。本文采用简单的水热还原法制备了自组装的3D网络结构NiCo2(CO3)3/RGO(NCR)气凝胶。独特的微观结构和多组分不仅解决了NiCo2(CO3)3颗粒的物理团聚,而且可以调整电磁参数以提高阻抗匹配和衰减能力。界面基体和宏观3D互联网格结构的协同效应可以实现高电磁波吸收(EMA)性能,在2.3 mm处最小反射损耗(RLmin)值为−58.5 dB,EAB为6.5 GHz。NiCo2(CO3)3/RGO气凝胶优异的EMA性能可归因于3D多孔结构的多重反射、散射和弛豫过程以及界面基体的强界面极化。
  • FIG. 2776.  FIG. 2776.

    FIG. 2776..  FIG. 2776.

    Figure  1.  Synthetic procedure of NCR aerogel

    Figure  2.  (a) XRD patterns of NC, NCR-1, NCR-2 and RGO. (b) Digital photograph of NCR-1 aerogel. (c) SEM image of NC. (d-f) SEM images of NCR-1 with different resolutions. (g-i) SEM images of NCR-2 with different resolutions. (j-m) EDS elemental mapping images of the NCR-1 (dashed area in Fig. e). (j) Co, (k) Ni, (l) O, (m) C

    Figure  3.  (a) XPS spectra of NC, NCR-1 and NCR-2. XPS spectra of (b) C 1s, (c) O 1s, (d) Ni 2p, and (e) Co 2p of NC, NCR-1 and NCR-2. (f) Raman spectra of NC, NCR-1 and NCR-2

    Figure  4.  (a, b) The real part (ε') and the imaginary part (ε") of complex permittivity, (c, d) the real part (μ') and the imaginary part (μ") of complex permeability of NC, NCR-1, NCR-2

    Figure  5.  (a, b) Dielectric and magnetic loss tangents (ε″/ε′, μ"/μ'), (c) C0–f curves and (d) attenuation constant of NC, NCR-1, NCR-2

    Figure  6.  (a, b, c) RLmin, 1/4 λ curve, and impedance matching of NC, NCR-1 and NCR-2 at frequency and different thicknesses

    Figure  7.  (a-c) Cole-Cole plots of NC, NCR-1 and NCR-2. (d) EIS spectra

    Figure  8.  Calculated theoretical RL value of NC, NCR-1, NCR-2: (a) three-dimensional images and (b) two-dimensional projection images

    Figure  9.  (a) Comprehensive comparison of the EMA performance based on RLmin and EAB of NC, NCR-1, NCR-2 and RGO. (b) Comprehensive comparison of the EMA performance given RLmin, and EAB with reported EMA materials

    Figure  10.  Schematic illustration of EM wave absorption for NCR

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  • 收稿日期:  2023-05-14
  • 录用日期:  2023-09-21
  • 修回日期:  2023-09-16
  • 网络出版日期:  2023-10-21
  • 刊出日期:  2023-11-23

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