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A one-pot method to prepare a multi-metal sulfide/carbon composite with a high lithium-ion storage capability

ZHANG Wei-cai YANG Chao-wei HU Shu-yu FANG Ya-wei LIN Xiao-min XIE Zhuo-hao ZHENG Ming-tao LIU Ying-liang LIANG Ye-ru

张伟财, 杨朝炜, 胡书宇, 方亚伟, 林晓敏, 谢卓豪, 郑明涛, 刘应亮, 梁业如. 一锅法合成多金属硫化物/碳复合材料及其储锂性能. 新型炭材料(中英文), 2023, 38(6): 1080-1091. doi: 10.1016/S1872-5805(23)60781-4
引用本文: 张伟财, 杨朝炜, 胡书宇, 方亚伟, 林晓敏, 谢卓豪, 郑明涛, 刘应亮, 梁业如. 一锅法合成多金属硫化物/碳复合材料及其储锂性能. 新型炭材料(中英文), 2023, 38(6): 1080-1091. doi: 10.1016/S1872-5805(23)60781-4
ZHANG Wei-cai, YANG Chao-wei, HU Shu-yu, FANG Ya-wei, LIN Xiao-min, XIE Zhuo-hao, ZHENG Ming-tao, LIU Ying-liang, LIANG Ye-ru. A one-pot method to prepare a multi-metal sulfide/carbon composite with a high lithium-ion storage capability. New Carbon Mater., 2023, 38(6): 1080-1091. doi: 10.1016/S1872-5805(23)60781-4
Citation: ZHANG Wei-cai, YANG Chao-wei, HU Shu-yu, FANG Ya-wei, LIN Xiao-min, XIE Zhuo-hao, ZHENG Ming-tao, LIU Ying-liang, LIANG Ye-ru. A one-pot method to prepare a multi-metal sulfide/carbon composite with a high lithium-ion storage capability. New Carbon Mater., 2023, 38(6): 1080-1091. doi: 10.1016/S1872-5805(23)60781-4

一锅法合成多金属硫化物/碳复合材料及其储锂性能

doi: 10.1016/S1872-5805(23)60781-4
基金项目: 茂名实验室自主科研项目(2022ZD002);国家自然科学基金项目(51972121,52373074)
详细信息
    通讯作者:

    刘应亮,教授. E-mail:tliuyl@scau.edu.cn

    梁业如,教授. E-mail:liangyr@scau.edu.cn

  • 中图分类号: TQ127.1+1

A one-pot method to prepare a multi-metal sulfide/carbon composite with a high lithium-ion storage capability

Funds: This work was financially supported by Independent Research Project of Maoming Laboratory (2022ZD002) and National Natural Science Foundation of China (51972121 and 52373074)
More Information
  • 摘要: 多金属硫化物/碳(MMS/C)复合材料因其良好的结构稳定性、充足的活性位点和有益的协同效应,在能源、催化、传感、环境科学等领域具有良好的应用潜力。然而,MMS/C复合材料繁琐、低效和对环境有害的制备方法制约了其发展。本文报道了一种简易、通用的制备策略合成了系列MMS/C复合材料。该策略的关键是采用了碳源−非碳前驱体一体化的离子交换树脂−金属离子杂化组装体作为构筑单元,可实现均匀的多相有机/无机界面,在高温条件下原位生成封装于碳骨架中的金属硫化物。通过改变金属离子的种类,实现了14 种 MMS/C 复合材料的合成。基于其组分和结构优势,所制MMS/C复合材料表现出高效、快速和持久的锂离子存储性能。其中,ZnS-Co9S8/C复合材料在0.1 A·g−1电流密度下循环600次后仍具有651 mAh·g−1的可逆储锂容量;当电流密度提高20倍时,容量保持率超过54%,展现出优异的倍率性能。本文提出的均一、多相有机/无机界面合成策略有望扩展用于制备其他金属化合物(如金属磷化物、金属硒化物等)/碳复合材料,为多金属化合物/碳复合材料的合成提供有效的途径。
  • FIG. 2780.  FIG. 2780.

    FIG. 2780..  FIG. 2780.

    Figure  1.  Synthetic scheme for preparing MMS/C composites by taking BMS/C composites as example. (a) Traditional post-synthesis strategy and (b) simplified post-synthesis strategy. (c) One-pot synthetic route by using a homogeneous multi-phase interfacial engineering

    Figure  2.  (a) Digital photos of IER-S before and after coordination. (b) Schematic illustration of Zn2+ and Co2+ combined with IER-S. (c) EDS images, (d) FTIR spectra of IER-S before and after coordination. (e) S 2p and (f) O 1s spectra of IER-S-Zn/Co. The inset in (f) shows a schematic diagram of the structure of 2 benzenesulfonates coupling to a divalent metal ion

    Figure  3.  (a) Mass content and relative amount of substance of Zn, Co, and S elements in IER-S-Zn/Co. (b) XRD patterns of distinct samples obtained by heating IER-S-Zn/Co under different temperatures. (c) TGA curve obtained by heat treatment IER-S-Zn/Co under N2 flow. (d) Schematic of the evolution for IER-S-Zn/Co during the heating process. (e) SEM image, (f) EDS mapping images, (g) HRTEM image, (h) TGA curve, (i) XRD pattern and (j) S 2p spectrum of ZnS-Co9S8/C

    Figure  4.  (a) Digital photos of different IER-S-M1/M2 hybrid assemblies. (b) Synthesis schematic of BMS/C composites. (c) XRD patterns and (d–g) SEM images of BMS/C composites

    Figure  5.  (a) Schematic illustration for fabrication of TMS/C composites. (b) Digital photos of different IER-S-M1/M2/M3 hybrid assemblies. (c-e) EDS mapping images, (f-h) SEM images, and (i) XRD patterns of TMS/C composites

    Figure  6.  Cycling performances of ZnS-Co9S8/C, Co9S8/C, and ZnS/C anodes at (a) 0.1 A·g−1 and (b) 1 A·g−1, (c) Rate performances of the ZnS-Co9S8/C, Co9S8/C and ZnS/C anodes, (d) Nyquist plots, (e) resistance, and (f) DLi of ZnS-Co9S8/C, Co9S8/C and ZnS/C anodes in LIB

    Figure  7.  Schematic illustration of fast electron and ion transportation of ZnS-Co9S8/C anode

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出版历程
  • 收稿日期:  2023-04-19
  • 录用日期:  2023-08-29
  • 修回日期:  2023-08-28
  • 网络出版日期:  2023-10-16
  • 刊出日期:  2023-11-23

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