张伟财, 杨朝炜, 胡书宇, 方亚伟, 林晓敏, 谢卓豪, 郑明涛, 刘应亮, 梁业如. 一锅法合成多金属硫化物/碳复合材料及其储锂性能[J]. 新型炭材料, 2023, 38(6): 1080-1091. DOI: 10.1016/S1872-5805(23)60781-4
引用本文: 张伟财, 杨朝炜, 胡书宇, 方亚伟, 林晓敏, 谢卓豪, 郑明涛, 刘应亮, 梁业如. 一锅法合成多金属硫化物/碳复合材料及其储锂性能[J]. 新型炭材料, 2023, 38(6): 1080-1091. DOI: 10.1016/S1872-5805(23)60781-4
ZHANG Wei-cai, YANG Chao-wei, HU Shu-yu, FANG Ya-wei, LIN Xiao-min, XIE Zhuo-hao, ZHENG Ming-tao, LIU Ying-liang, LIANG Ye-ru. A one-pot method to prepare a multi-metal sulfide/carbon composite with a high lithium-ion storage capability[J]. New Carbon Mater., 2023, 38(6): 1080-1091. DOI: 10.1016/S1872-5805(23)60781-4
Citation: ZHANG Wei-cai, YANG Chao-wei, HU Shu-yu, FANG Ya-wei, LIN Xiao-min, XIE Zhuo-hao, ZHENG Ming-tao, LIU Ying-liang, LIANG Ye-ru. A one-pot method to prepare a multi-metal sulfide/carbon composite with a high lithium-ion storage capability[J]. New Carbon Mater., 2023, 38(6): 1080-1091. DOI: 10.1016/S1872-5805(23)60781-4

一锅法合成多金属硫化物/碳复合材料及其储锂性能

A one-pot method to prepare a multi-metal sulfide/carbon composite with a high lithium-ion storage capability

  • 摘要: 多金属硫化物/碳(MMS/C)复合材料因其良好的结构稳定性、充足的活性位点和有益的协同效应,在能源、催化、传感、环境科学等领域具有良好的应用潜力。然而,MMS/C复合材料繁琐、低效和对环境有害的制备方法制约了其发展。本文报道了一种简易、通用的制备策略合成了系列MMS/C复合材料。该策略的关键是采用了碳源−非碳前驱体一体化的离子交换树脂−金属离子杂化组装体作为构筑单元,可实现均匀的多相有机/无机界面,在高温条件下原位生成封装于碳骨架中的金属硫化物。通过改变金属离子的种类,实现了14 种 MMS/C 复合材料的合成。基于其组分和结构优势,所制MMS/C复合材料表现出高效、快速和持久的锂离子存储性能。其中,ZnS-Co9S8/C复合材料在0.1 A·g−1电流密度下循环600次后仍具有651 mAh·g−1的可逆储锂容量;当电流密度提高20倍时,容量保持率超过54%,展现出优异的倍率性能。本文提出的均一、多相有机/无机界面合成策略有望扩展用于制备其他金属化合物(如金属磷化物、金属硒化物等)/碳复合材料,为多金属化合物/碳复合材料的合成提供有效的途径。

     

    Abstract: Because of their high electrochemical activity, good structural stability, and abundant active sites, multi-metal sulfide/carbon (MMS/C) composites are of tremendous interest in diverse fields, including catalysis, energy, sensing, and environmental science. However, their cumbersome, inefficient, and environmentally unfriendly synthesis is hindering their practical application. We report a straightforward and universal method for their production which is based on homogeneous multi-phase interface engineering. The method has enabled the production of 14 different MMS/C composites, as examples, with well-organized composite structures, different components, and dense heterointerfaces. Because of their composition and structure, a typical composite has efficient, fast, and persistent lithium-ion storage. A ZnS-Co9S8/C composite anode showed a remarkable rate performance and an excellent capacity of 651 mAh·g−1 at 0.1 A·g−1 after 600 cycles. This work is expected to pave the way for the easy fabrication of MMS/C composites.

     

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