碳基锌离子电容器研究进展

Research progress on carbon-based zinc-ion capacitors

  • 摘要: 锌离子电容器(ZICs)由电容器型电极和电池型电极组成,不仅具备与超级电容器相当的高功率密度和电池级的高能量密度,而且还具有资源丰富、安全性高、环境友好等优点,因此被视为最具发展前景的能量储存与转换装置。然而,ZICs仍面临比容量不足、循环寿命短以及工作电压低和工作温度范围窄等问题,这些缺点阻碍了其实际应用。为应对这些挑战,本文对碳基ZICs的基础理论进行了全面概述,并从碳阴极、电解质和锌阳极三个方面总结了ZICs的近期研究进展。特别地,本文重点阐述了炭材料结构和表面化学性质调控对ZICs电化学性能的影响,为推动下一代高性能ZICs的开发与实际应用提供了理论指导。

     

    Abstract: Zinc-ion capacitors (ZICs), which consist of a capacitor-type electrode and a battery-type electrode, not only possess the high power density of supercapacitors and the high energy density of batteries, but also have other advantages such as abundant resources, high safety and environmental friendliness. However, they still face problems such as insufficient specific capacitance, a short cycling life, and narrow operating voltage and temperature ranges, which are hindering their practical use. We provide a comprehensive overview of the fundamental theory of carbon-based ZICs and summarize recent research progress from three perspectives: the carbon cathode, electrolyte and zinc anode. The influence of the structure and surface chemical properties of the carbon materials on the capacitive performance of ZICs is considered together with theoretical guidance for advancing their development and practical use.

     

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